Conductivity Studies in Proton Irradiated AgI-Ag2O-V2O5-TeO2 Super-Ionic Glass System
Poonam Sharma, Dinesh Kumar Kanchan, Meenakshi Pant, Karan Pal Singh
DOI: 10.4236/msa.2010.12011   PDF    HTML     5,400 Downloads   9,770 Views   Citations


The electrical properties of proton ion beam irradiated glass samples are carried out by impedance spectroscopy in the frequency range from 10 Hz to 32 MHz. The ion beam of energy 3 MeV and fluence of of 1014 particles cm-2 was chosen for irradiation. The conductivity of the super ionic glass samples increases after irradiation and other electrical parameters like dielectric constant, dielectric loss and modulus of the proton irradiated glass samples as a function of glass composition and temperature are observed to change. The dielectric constant and the dielectric losses are increased after irradiation and the modulus parameters confirm the non-Debye nature for irradiated samples also.

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Sharma, P. , Kanchan, D. , Pant, M. and Singh, K. (2010) Conductivity Studies in Proton Irradiated AgI-Ag2O-V2O5-TeO2 Super-Ionic Glass System. Materials Sciences and Applications, 1, 59-65. doi: 10.4236/msa.2010.12011.

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The authors declare no conflicts of interest.


[1] S. Bhattacharya and A. Ghosh, “Relaxation Dynamics in AgI-Doped Silver Vanadate Superionic Glasses,” Journal of Chemical Physics, Vol. 123, No. 12, 2005, pp. 1-5.
[2] K. P. Padmsree, D. K. Kanchan, H. R. Panchal, A. M. Awasthi and S. Bharadwaj, “Structural and Transport Properties of CdI2 Doped Silver Ion Conducting System,” Solid State Commun, Vol. 136, No. 2, October 2005, pp. 102-107.
[3] A. K. Arof, “Internal Resistance and Cathode Content in Silver Borovanadate Batteries,” Journl of Power Sources, Vol. 52, No. 1, November 1994, pp. 129-133.
[4] A. Singh, “Irradiation of Polymer Blends Containing a Polyolefin,” Radiation Physics and Chemistry, Vol. 60, No. 4-5, 2001, pp. 453-459.
[5] O. Puglisi, M. E. Fragala, K. G. Lynn, M. Petkov, et al., “Study of Ion Beam Induced Depolymerization Using Positron Annihilation Techniques,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 175-177, April 2001, pp. 605-609.
[6] J. C. Pivin, M. Sendova-Vassileva, M. Nikolaeva, D. Dimova-Malinovska and A. Martucci, “Optical Extinction Resonance of Au and Ag Clusters Formed by Ion Irradiation in SiO2 and Al2O3,” Applied Physics A: Materials Science and Processing, Vol. 75, No. 3, pp. 401-410.
[7] J. C. Pivin, “Mixing of Noble Metals in Oxides and Formation of Colloids by Ion Irradiation,” Materials Science and Engineering A, Vol. 293, No. 1-2, November 2000, pp. 30-38.
[8] J. C. Pivin, M. A. Garcia, J. Llopis, and H. Hofmeister, “Interaction between Clusters in Ion Implanted and Ion Beam Mixed SiO2: Ag Films,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 191, No. 1-4, May 2002, pp. 794-799.
[9] H. Hofmeister, S. Thiel, M. Dubiel and F. Schurig, “Synthesis of Nanosized Silver Particles in Ion-Exchanged Glass by Electron Beam Irradiation,” Applied Physics Letter, Vol. 70, No. 13, 1997, pp. 1694-1696.
[10] S. Chen, T. Akai, K. Kadono and T. Yazawa, (2001) “Reversible Control of Silver Nanoparticle Generation and Dissolution in Soda-Lime Silicate Glass through X-Ray Irradiation and Heat Treatment,” Applied Physic Letters, Vol. 79, No. 22, 2001, pp. 3687-3689.
[11] D. L. Griscom, “E.S.R. Studies of Radiation Damage and Structure in Oxide Glasses not Containing Transition Group Ions: A Contemporary Overview with Illustrations from the Alkali Borate System,” Journal of Non-Crystalline Solids, Vol. 13, No. 2, January 1974, pp. 251-285.
[12] R. A. B. Devine, “Macroscopic and Microscopic Effects of Radiation in Amorphous SiO2,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 91, No. 1-4, June 1994, pp. 378-390.
[13] V. N. Sandalov, M. I. Muminov and E. M. Ibragimova, “Radiation-Induced Enhancement of Proton-Conductivity in Porous Glass,” Materials Science and Engineering B, Vol. 108, No. 1-2, April 2004, pp. 171-173.
[14] E. J. Friebele, “Optical Properties of Glasses,” American Ceramic Society, Westerville, 1991.
[15] B. Boizot, G. Petite, D. Ghaleb and G. Calas, “Dose, Dose Rate and Irradiation Temperature Effects in β-Irradiated Simplified Nuclear Waste Glasses by EPR Spectroscopy,” Journal of Non-Crystalline Solids, Vol. 283, No. 1-3, May 2001, pp. 179-185.
[16] H. Hofmeister, M. Dubiel, H. Graener and J. C. Pivin, “Structural Characteristics of Metal Nanoparticles in Glass upon Irradiation-Assisted Processing,” Radiation Effects and Defects in Solids, Vol. 158, No. 1-6, 2003, pp. 49-54.
[17] B. Boizot, G. Petite, D. Ghaleb, B. Reynard and G. Calas, “Radiation Induced Paramagnetic Centres in Nuclear Glasses by EPR Spectroscopy,” Nuclear Instruments and Methods in Physics Research Section B, Vol. 141, No. 1-4, 1998, pp. 580-585.
[18] B. Boizot, G. Petite, D. Ghaleb, B. Reynard and G. Calas, “Raman study of β-irradiated glasses,” Journal of Non-Crystalline Solids, Vol. 243, No. 2-3, February 1999, pp. 268-272.
[19] B. Boizot, G. Petite, D. Ghaleb, N. Pellerin, et al., “Migration and Segregation of Sodium under β-Irradiation in Nuclear Glasses,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 166-167, May 2000, pp. 500-504.
[20] B. Constantinescu, R. Bugoi, E. R. Hodgson, R. Vila and P. Ioan, “Studies on Proton Irradiation-Induced Modifications of KU1 and KS-4V Quartz Glasses Ultraviolet Transmission Properties, Journal of Nuclear Materials, Vol. 367-370, August 2007, pp. 1048-1051.
[21] V. T. Kuanyshev, T. A. Belykh, et al., “Fundamental Processes of Radiation Energy Storage in KDP (KH2PO4) and ADP (NH4H2PO4) Crystals,” Radiation Measurements, Vol. 33, No. 5, October 2001, pp. 503-507.
[22] A. K. Arof and S. Radhakrishna, “Electrical Properties of Silver Vanadate Electrochemical Cells,” Journal of Alloys and Compounds, Vol. 200, No. 1-2, October 1993, pp. 129-134.
[23] P. Sharma, D. K. Kanchan, M. Pant and K. P. Padmashree, “Transport Properties of Super Ionic AgI-Ag2O-V2O5-TeO2 Glasses,” Indian Journal of Pure and Applied Physics, Vol. 48, No. 1, 2010, pp. 39-46.
[24] A. A. Baghat, I. I. Shaltout and A. M. Abu-Elazm, “Structural and thermal Properties of some Tellurite Glasses,” Journal of Non-Crystalline Solids, Vol. 150, No. 1-3, November 1992, pp. 179-184.
[25] Y. Dimitriev, V. Dimitrov and M. Arnaudov, “IR Spectra and Structures of Tellurite Glasses,” Journal of Materials Science, Vol. 18, No. 5, May 1983, pp. 1353-1358.
[26] M. Pant, D. K. Kanchan and P. Sharma, “Characterization and Transport Properties of 10BaO-xAg2O-(85-x)V2O5- 5TeO2 Glass System,” Communicated in Ionics, in Press.
[27] S. Sen and A. Ghosh, “Structure and Other Physical Properties of Magnesium Vanadate Glasses,” Journal of Non-Crystalline Solids, Vol. 258, No. 1-3, November 1999, pp. 29-33.
[28] E. F. Lambson, G. A. Saunders, B. Bridge and R. A. El- Mallawany, “The Elastic Behaviour of TeO2 Glass under Uniaxial and Hydrostatic Pressure,” Journal of NonCrystalline Solids, Vol. 69, No. 1, December 1984, pp. 117-133.
[29] A. K. Jonscher, “The ‘Universal’ Dielectric Response,” Nature, Vol. 267, June 1977, pp. 673-679.
[30] D. K. Kanchan, K. P. Padmashree, H. R. Panchal and A. R. Kulkarni, “Electrical Transport Studies on CdI2 Doped Silver Oxysalt System,” Cermics International, Vol. 30, No. 7, 2004, pp. 1655-1660.
[31] M. Pant, D. K. Kanchan, P. Sharma and M. S. Jayswal, “Mixed Conductivity Studies in Silver Oxide Based Barium Vanado—Tellurite Glasses, Materials Science and Engineering B, Vol. 149, No. 1, March 2008, pp. 18-25.
[32] H. M. Abdel-Hamid, R. M. Radwan and A. H. Ashour, “Ion Beam Induced Changes in Electrical Resistivity of Polymer Films: The Case of Unplasticized Poly (Vinyl Chloride),” Journal of Physics D: Applied Physics, Vol. 35, No. 11, 2002, pp. 1183-1187.
[33] T. Minami, “Fast Ion Conducting Glasses,” Journal of Non-Crystalline Solids, Vol. 73, No. 1-3, July 1984, pp. 273-284.
[34] A. Ghosh and A. Pan, “Scaling of the Conductivity Spectra in Ionic Glasses: Dependence on the Structure,” Physics Review Letters, Vol. 84, No. 10, March 2000, pp. 2188-2190.
[35] B. Roling, A. Happe, K. Funke and M. D. Ingram, “Carrier Concentrations and Relaxation Spectroscopy: New Information from Scaling Properties of Conductivity Spectra in Ionically Conducting Glasses,” Physics Review Letters, Vol. 78, No. 11, 1997, pp. 2160-2163.
[36] K. P. Padmashree and D. K. Kanchan, “Dielectric Studies on CdI2 Doped Ag2O-V2O5-B2O3 System,” Materials Chemistry Physics, Vol. 91, No. 2-3, June 2005, pp. 551- 557.
[37] D. L. Sidebottom, B. Roling and K. Funke, “Ionic Conduction in Solids: Comparing Conductivity and Modulus Representations with Regard to Scaling Properties,” Physical Review B, Vol. 63, No. 2, pp. 1-7.
[38] S. H. Kim, K. W. Lee and C. E. Lee, “Dielectric Properties of Proton-Irradiated TlH2PO4,” Journal of Korean Physical Society, Vol. 48, No. 3, March 2006, pp. 433-436.
[39] P. B. Macedo, C. T. Moynihan and R. Bose, “The Role of Ionic Diffusion in Polarization in Vitreous Ionic Conductors,” Physics and Chemistry Glasses, Vol. 13, 1972, pp. 171-179.

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