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Visible Light Photocatalytic Degradation of Methylene Blue and Malachite Green Dyes with CuWO4-GO Nano Composite

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DOI: 10.4236/mrc.2018.72002    579 Downloads   1,119 Views  

ABSTRACT

Copper Tungstate-Graphene Oxide nano composites have been successfully applied as excellent catalysts for the photocatalytic degradation with Methylene blue and Malachite green dyes under visible light irradiation. A facile solid state metathesis synthesis of copper tungstate (CuWO4) followed by ball milling and subsequent preparation of copper tungstate-graphene oxide (CuWO4-GO) nano composite using a colloidal blending process and its application as a visible light photocatalyst for the degradation of Malachite green and Methylene blue dyes. The morphology and composition of copper tungstate (CuWO4) nano composite have been characterized using X-Ray Diffraction (XRD), UV-Visible Diffuse Reflectance Spectra (UV-DRS), Raman Spectra, Field Emission Scanning Electron Microscopy (FESEM)-EDS and UV Visible Spectroscopy. It shows a band gap value of 2.13 eV, an increase in range and intensity of light absorption and the reduction of electron-hole pair recombination in CuWO4 with the introducing of GO on to it.

1. Introduction

Many efforts have been made in the past, and in recent years semiconductor based photocatalysts with high photocatalytic activity for environmental protection have been developed. Procedures such as water disinfection, air purification, polluted waste water remediation, etc. are taken. It has been a promising technique owing to its strong oxidizing nature, chemical inertness, economic viability and non-toxicity [1] [2] [3] . The unique arrangement of electronic structure, light absorption properties and charge transport characteristics in most of the metal oxides and tungstates have proven them to be superior photocatalysts.

Transition metal tungstates are considerable inorganic materials that have a significant application in various fields. Some of the divalent transition metal tungstates have also gained commercial interest in fluorescent lamps and lasers lights, due to its excellent electrical conductivity. In addition to this, these are also used as humidity sensors and catalysts. Copper tungstate is a well-known semiconductor with potential technological applications in scintillates, detectors, photon-odes, laser hosts, optical fibers etc. [4] [5] .

Solid-state metathetic approach has been successfully applied for the synthesis of many oxide materials. For example, Gopalakrishnan et al. have synthesized oxides of K2La2Ti3O10, Ca2La2CuTi2O10 belonging to Ruddleson-Popper type of materials, ABO3 perovskite type of materials like LaMO3 (M = Co, Mn), ATiO3 (A = Ca, Sr and Ba) and double perovskites like Ba3MM-2O9 (M = Mg, Ni, Zn; M_ = Nb, Ta) by this approach [6] [7] [8] [9] . In addition, Kaner et al. have synthesized oxides of Zr, Hf and Cu using this approach [10] [11] . Coppertungstate (CuWO4) crystals exhibit only wolframite-type monoclinic structure at high pressure [12] . Many metal tungstates like CuWO4 are also used for water splitting and photocatalysis [13] [14] .

Generally, the oxidized graphene sheets, namely, GO, acquire multiple defects and the degree of the defects is subject to the additive amount of oxidant and the oxidizing time [15] . Graphene oxide consists of water-dispersible, soft carbon sheets that can be easily converted to a conductive form and this 2D material continues to inspire many interesting applications and discoveries in a wide variety of fields including liquid-crystal display technology, bioscience, and materials science [16] - [21] .

Graphene oxide (GO) is a two-dimensional material derived from graphite by introducing covalent C-O bonds [22] . A large number of oxygen-containing functional groups have been implanted on both sides of a single graphite sheet overcomes the inter sheet Vander Waals force and enlarges the interlayer spacing. The sheets in such an expanded structure are easily pulled up using an external force by ultrasonication. Now the copper tungstate nano particles are directly grown on graphene oxide which appears to exhibit strong interactions with the underlying graphene oxide sheets. Since ultrasonication would not lead to any dissociation of the sheets ,due to its strong coupling leading to an advanced hybrid materials for various applications including photocatalysis. The photo catalytic activity of the obtained copper tungstate-graphene oxide hetero-architecture was evaluated by the degradation of Malachite green (MG) and Methylene blue (MB) under visible-light, and the results are shown in Figure 1.

Figure 1. Photo degradation plots of Malachite green and methylene blue with copper tungstate, nano copper tungstate and nano copper tungstate-graphene oxide composite.

The reasons for these improvements are attributed to the fact that copper tungstate has a direct band gap positioned near the optical value of the solar spectrum and high energy of CB (Conduction Band), giving the photo electrons to a strong reducing ability and graphene oxide possesses a remarkable electrical transport property [23] . By this, the CuWO4-GO composite also possesses a remarkable electrical transport property. Now, in the CuWO4-GO composites, a possible reaction mechanism can be proposed based on the observed enhanced photo catalytic activity. Here, a portion of graphene oxide acts as a photo carrier in conducting electrons to the surface of the graphene oxide ,which improves the separation of the electron-hole pairs and photo catalytic efficiency. It plays a conventional role as an elector acceptor and transporter, which is reported in most of the graphene oxide-semiconductor composites.

In the present study, a facile metathesis synthesis of CuWO4 and CuWO4-GO nano composite has been reported. The morphology and composition have been characterized using XRD, SEM and EDAX. The photo catalysis has been performed to study degradation of Methylene blue and Malachite green dyes by the prepared materials.

2. Experimental

2.1. Materials and Methods

All the chemicals were purchased of analytical grade which can be used as directly without any further purification. All the reactions were carried out using deionized water. The dyes used for this study are Malachite green and Methylene blue whose chemical formulae are C23H25ClN2 and C16H18ClN3S respectively, and the stock solutions of the dyes were prepared in 10 ppm concentrations in distilled water.

2.2. General Procedure

2.2.1. Synthesis of CuWO4

CuWO4 is prepared by solid-state metathesis synthesis followed by ball milling. Stoichiometric amounts of CuCl2 (LobaChemie Pvt. Ltd.) and NaWO4 (98% HIMEDIA) in the molar ratio of 1:1 are mixed in an agate mortar and grinded for about 4 hrs in ethanol. With progressive grinding, the mixture exhibits a bright blue colour and the powder is calcinated at 400˚C for 4hours in a muffle furnace. After calcination, the compound is washed with distilled water several times to remove excess NaCl which is formed as a by-product and the residue is dried at 80˚C in hot air oven and finally a greenish yellow copper tungstate powder is obtained which is then subjected to phase identification, micro-structural investigation and photocatalytic studies.

CuCl 2 n H 2 O + Na 2 WO 4 CuWO 4 + 2 NaCl + n H 2 O

The resultant compound CuWO4 obtained from the solid-state method was taken and grinded mechanically in low energy ball mill to obtain nano sized copper tungstate. The balls to powder weight ratio was maintained at 10:1 and the mixture is ground at 350 rpm for 4 hrs in methanol medium to obtain homogeneous compound. The residue after ball milling was dried in a hot air oven at 80˚C.

2.2.2. Synthesis of Graphene Oxide

Graphene oxide (GO) was prepared by the well-known modified Hummers method [15] from an expanded acid washed graphite flakes (Sigma Aldrich). In this, 5 g of graphite was added into a mixture of 108 mL of sulphuric acid (Molychem-AR) and 12 mL of orthophosphoric acid (Molychem-AR) and stirred for 10 min. To it, 2.5 g of sodium nitrate (Molychem-AR) was added. Subsequently, the beaker with reagents was put in an ice bath in order to keep it below 5˚C. Now, 15 g of potassium permanganate (Molychem-AR) was added in portions into the mixture, which was vigorously stirred. After addition of the oxidant, the beaker was heated and kept at 35˚C to 40˚C with continuous stirring. In the next step, 280 mL of deionized water was added to the beaker and heated to 95˚C and maintained the same conditions for about 60 min. To complete the reaction 5 ml of 30% hydrogen peroxide (Molychem-AR) is added, now the color of the solution changes to bright yellow .The mixture is then washed with 5% hydrochloric acid (Molychem-AR) solution to remove sulfate ions and with deionized water in order to remove the chloride ions to maintain neutral pH. After centrifugation the gel like substance is vacuum dried at 60˚C for more than 6 hrs to get GO as powder.

2.2.3. Synthesis of CuWO4-GO Nano Composites

CuWO4-GO nano composites were synthesized using a colloidal blending process with GO and CuWO4. For the preparation of CuWO4-10% GO nano composites, 1 ml of 10% GO was dispersed in 20 mL of deionized water and sonicated using ultrasonic cleaner for 30 minutes and 1gm of copper tungstate is dispersed in the prepared GO solution using sonicator for another 30 minutes. The above mixture is under constant stirring for about 4 hours. The bluish yellow product was collected and dried in hot air oven at 80˚C for 2 hours [24] . Similarly 1%, 2%, 3%, 5% and 20% GO nano composites are prepared and used.

The obtained GO-CuWO4 composite was characterized by X-Ray Diffraction (XRD), FT-IR, Scanning Electron Microscopy (SEM) and EDS, UV-Diffused Reflectance spectroscopy, Raman Spectroscopy.

2.2.4. PhotoCatalytic Experiments

Photo catalytic activity of the synthesized CuWO4-GO nano composite was evaluated by de-colorization of Methylene blue and Malachite green dye solutions. The experiments were carried out under the visible light irradiation in presences of CuWO4-GO photocatalyst. The photocatalysis process is carried out in a visible light photo reactor constructed with an outer wooden cabinet equipped with a magnetic stirrer, a Metal Halide Lamp, an exhaust fan and electric power supply cable. The reaction was carried out by adding 0.05 g of the as-synthesized nano composite into 100 mL of dye solution (10 ppm) in a 1000 mL Borosil glass beaker. The suspension was magnetically stirred in dark for 30 minutes to obtain desorption/absorption equilibrium before irradiating the solution to the light. A 400 W metal halide lamp is used as light source for the photo catalytic studies. The solution was irradiated and aliquots were drawn at regular time intervals, centrifuged and the transparent dye solution analyzed for absorbance using Visible Spectrophotometer (340 nm to 960 nm).

Percentage degradation of the dye was calculated using the following formula.

%Degradation = ( A o A t ) / A o (1)

where Ao is absorbance of dye at initial stage At is absorbance of dye at time t.

2.2.5. Instrumentation

Retsch® Planetary Ball Mill PM 100 bench top grinding station has been used for ball milling. The resulting powder was characterized using X-Ray Diffractometer (PANalytical-X’ Pert PRO, Japan) at room temperature, using Nickel Filter Cu-Kα radiation (λ = 1.54059 Å), over a wide range of 10˚ ≤ 2θ ≤ 80˚ with a scanning speed of 2˚ min1. The morphology of the as-synthesized samples was investigated by field emission scanning electron microscopy (FESEM, LEO1550). Band gaps were calculated using Single Monochromator UV-2600 (optional ISR-2600 Plus, λ up to 1400 nm).

3. Results and Discussion

3.1. X-Ray Diffraction

Figure 2 shows the X-Ray Diffraction plot of nanographene oxide and the peaks are in good agreement with the characteristic peaks of graphene oxide. Figure 3 shows the X-Ray Diffraction plot of CuWO4-GO nano composite. The peaks of the composite are in good agreement with the characteristic peaks of CuWO4. While a distinct peak for pure graphene oxide was observed at 2 = 10.2˚ (Figure 2), this GO related peak is not observed in CuWO4-GO plot due to the low amounts of GO and the resultant low diffraction intensity that would be

Figure 2. XRD-Spectrum of graphene oxide.

Figure 3. XRD-Spectrum of CuWO4-GO nano composite.

below the limit of detection of the instrument [23] . The phase purity of the as-synthesized materials was confirmed by representative XRD analysis. As shown in Figure 3 as-prepared powder samples have similar narrow characteristic peaks locating at 15.1˚, 19.2˚, 23.8˚, 24.9˚, 29.2˚, 31.6˚, 36.7˚ and 43.8˚, which match well with the (010), (001), (110), (0 11), (111), (111), (200) and (121) planes, respectively. All the mentioned crystal planes are in good agreement with the standard patterns for triclinic phase CuWO4 (JCPDS No 80-1918) [25] .

3.2. FT-IR

The FTIR spectrum of CuWO4 is shown in Figure 4 The spectrum exhibits a broad band near 3446 cm−1 due to the OH-stretching vibrations of free and hydrogen-bonded hydroxyl groups .The band at 614 cm−1 and the peak at 476 cm−1 can be assigned to the Cu-O stretching vibration along the direction and the peak at 1028 cm−1 is due the presence of W-OH bond [26] .

3.3. Composition and Morphology Study

Figure 5 shows the FE-SEM of CuWO4-GO nano composite. The nano structures and morphologies of samples are examined by SEM characterization. It shows the morphology of CuWO4-GO and it obviously reveals that micro structured

Figure 4. FTIR spectrum of CuWO4.

Figure 5. SEM-micrographs of CuWO4-GO nano composite and EDS spectra.

CuWO4 particles have a rough surface, with various irregular particles anchored on the surface of CuWO4. From this, it can be clearly observed that the prepared sample consists of nano particles in the size of <50 nm in diameter. Further, the EDS spectrum and elemental composition demonstrates the presence of Cu, W, O and C which confirms the proper formation of CuWO4-GO nano composite. EDS analysis shows a composition of 46.9% W, 18.8% O, 18.5% Cu and 15.8% C (wt.%) as evidence of successful inter-diffusion and the formation of CuWO4-GO nano composite.

3.4. UV Diffuse Reflectance Spectral Studies

The optical properties of pure copper tungstate, nano copper tungstate and CuWO4-GO nano composite was evaluated by UV-Diffuse Reflectance Spectroscopy as shown Figures 6-9. Micro sized copper tungstate shows the λmax at 290 nm and the calculated band gap was found to be 4.5 eV (Figure 6). The nano sized copper tungstate shows a λmax at 580 nm and the band gap has been reduced to 2.1 eV (Figure 7). A steep decrease in the band gap of nanocopper tungstate indicates that the absorption in the visible light region is possible from a band gap transition from macro size to nano size. Specifically, electrons on the valence band were activated by photon energy and jumped to the conduction band [27] . By introducing graphene oxide on the surface of nano copper tungstate, a similar absorption edge was observed indicating that the graphene oxide was not incorporated into the lattice of copper tungstate and just got adsorbed on its surface. From the absorbance spectra for CuWO4-GO nano composite

Figure 6. Band gap spectrum of CuWO4 (prepared by metathesis).

Figure 7. Band gap spectrum of CuWO4 (after low energy ball milling).

Figure 8. Band gap spectrum of CuWO4-GO composite.

Figure 9. Band gap overlay spectrum of CuWO4, CuWO4-GO.

the λmax is observed at 580 nm and the band gap is found to be 2.1 eV in Figure 8 and Figure 9.

The band gap of a solid and the wavelength of light that is reflected by it are related to one another via the Planck-Einstein Relation, which is stated below. E is the gap energy of the band gap in joules, h is Planck’s constant (6.63 × 10−34 J s), ν is frequency in hertz.

E g = h v = h c λ (2)

From the plot of absorbance vs wavelength (λ), wavelength of the material is measured and band gap is calculated from the equation. Where λ is the wavelength of the material from the graph. Eg is the bandwidth to be calculated

E g = 1240 / λ ( nm ) (3)

3.5. Raman Spectral Analysis

Figure 10 shows Raman spectra of CuWO4-GO nano composite. In terms of group theoretical analysis, Wolframite structure belonging to P2/c (z = 2) monoclinic structure is expected to give 18 (8 Ag + 10 Bg) Raman-active bands out of 36 possible lattice modes. As our interest is limited to show the phase formation of tungstates, the Raman modes CuWO4-GO is shows the vibrations at 910 cm−1 which is an evidence for wolframite structure.

3.6. UV-Visible Spectroscopy

Figure 11 and Figure 12 show that high intensity peak at 667 nm for Methylene blue and 617 nm for a Malachite green dyes. The absorption wavelength of Methylene blue was recorded at 667 nm and Malachite green was recorded at 617 nm throughout the study and the percentage of degradation of Methylene blue and Malachite green was carefully monitored at various time intervals.

Figure 10. Raman spectra of CuWO4-GO nano composite.

Figure 11. Absorption spectrum of methylene blue (λmax at 667 nm).

Figure 12. Absorption spectrum of malachite green (λmax 617 nm).

3.7. The Photo Catalytic Activity

The photo catalytic activity of the nanoCuWO4-GO composite was investigated towards the degradation of organic dyes Methylene blue (MB) and Malachite green (MG) under visible light irradiation is represented in Figure 13 shown in comparison with micro and nanoCuWO4.

Aiming at eliminating the effect of adsorption on the dye degradation efficiency, before each photocatalytic process, the adsorption-desorption equilibria between the dye and the photocatalysts were first obtained at 30 min and it is sufficient time to reach equilibrium. After 30 min the reaction mixture is exposed to visible light under constant magnetic stirring, and aliquot of the reaction mixture is collected for every 10 min and subjected to UV-Vis analysis. It can be seen that the intensity of the absorption peaks decreased as the reaction progressed with CuWO4-GO as the catalyst. We observed that the MG dye solution is completely degraded in 60 min and MB dye degraded in 80 min.

3.8. Effect of Graphene Oxide % Composition on the Photocatalytic Activity

Malachite green and Methylene blue dye can be more easily adsorbed by GO (MG&MB degradation efficiency ~75%) rather than the CuWO4 (MG & MB degradation efficiency ~3%) catalyst. Its adsorption capacity was enhanced when GO was introduced on CuWO4. The performances of the prepared samples, including pure CuWO4 and modified CuWO4 by graphene oxide with different percent compositions, were investigated with regard to the degradation of MG&MB under visible light irradiation. There is almost no photodegradation in the absence of the catalyst. This suggested that, negligible amount of degradation by light can be ignored. In the presence of nano CuWO4, Malachite green and Methylene blue dyes were degraded in 80 to100 min under visible light irradiation. The CuWO4-GO nano composite has enhanced the photocatalytic degradation of Malachite green and Methylene blue dyes. The efficiencies of dye degradation were significantly improved from 80% to 100% in a time interval of 60 to 80 min by improving the amount of graphene oxide from 5% to 10% in the CuWO4-GO composite. Even though by adding upto 20% of graphene oxide in the composite, degradation efficiency remained the same. This suggests that graphene oxide with an amount of 10% in the CuWO4-GO composite performs the best in removing the organic pollutants in wastewater under visible light irradiation (Figure 14).

3.9. Effect of Amount of CuWO4-GO Nano Composite

The effect of photocatalysts (10% CuWO4-GO nano composite) dosage on the photocatalytic degradation of Malachite green and Methylene blue was studied and shown in Figure 15. The dosage amount was varied from 10 mg to 100 mg/100mL and all the observations are carried out at room temperature. It can be concluded that, with the increase of catalyst dosage from 10 mg to 50 mg/100ml, the degradation efficiencies were significantly improved. Further increase

Figure 13. Comparative degradation of CuWO4-GO composite with micro and nano CuWO4.

Figure 14. % of GO composition on catalyst.

Figure 15. Effect of amount of CuWO4-GO nano composite.

of the catalysts dosage quantity from 4 to 6 g/L will slightly decrease the efficiency of the degradation of Malachite Green and Methylene blue. This phenomena, maybe because of the increase in the amount of catalysts dosage, which would increase the reactive sites that can correspondingly produce more reactive oxidative species. However, too much catalyst dispersed in the system will possibly increase light scattering and decrease light penetration [28] , resulting in the reduction of degradation efficiency of MG & MB in a system with excessive photocatalysts. CuWO4-10% and CuWO4-20% GO nano are having similar percentage of degradation so the experiment was carriedout with CuWO4-10% GO composite

3.10. Effect of pH of Initial Dye Solution

Considering that the pH of wastewater is possibly different, its effect on the photocatalytically degrading dye (MG/MB) in the presence of CuWO4-GO under visible light irradiation was explored. It has been reported in Figure 16 that, with an increase of pH of the dye (MG/MB) solution, it may reduce the adsorption of dye (MG/MB) on the photocatalyst. This resulted in the improvement of degradation efficiencies when pH of the MG solution increased from 5 to 7 and for MB solution increased from 3 to 5 [27] . And the transformation of CuWO4 damages the CuWO4-GO structure and eventually reduces the photocatalytic activity.

3.11. Effect of Temperature

As shown in Figure 17, temperature of the photocatalytic reacting system was also varied from 0˚C to 80˚C to explore its effect on the photocatalytic performances of the prepared samples under visible light irradiation. When the temperature of the reacting system is in the range of 20˚C - 60˚C, the photocatalytic performances in degrading dye (MG/MB) were similar and only a slight increase is found with the increase in temperature. However, when the temperature was fixed at 0˚C, the photocatalytic activity was significantly reduced. This might be because the mass transfer of pollutants to the surface of photocatalysts was decreased and the generation rate of oxidative species was also reduced. When the temperature was as high as 80˚C, the photocatalytic activity was greatly decreased. High temperature favors the recombination of charge carriers and desorption of adsorbed organics on the photocatalysts. The results can be regarded as evidence of temperature controller needed for solar devices.

3.12. Reusability of the Catalyst

The reusability of the prepared sample was assessed by recycling CuWO4-GO composite three times and the profiles of MG/MB concentrations is shown in Figure 18. The removal efficiency of dye (MG/MB) was 95% in the first run 60% in second run and 33% in third run over 80 - 160 min under visible light irradiation. The slight decrease can be attributed to the loss of photocatalysts between two runs and some refractory intermediates adsorbed on their surface which are

Figure 16. pH range of CuWO4-GO Nano composite on Malachite Green and Methylene Blue.

Figure 17. Temperature effect on CuWO4-GO Nano composite.

Figure 18. Reusable capacity of CuWO4-GO nano composite.

difficult to be destroyed [28] . Despite of this slight reduction in degradation efficiency, the stability of the reused CuWO4-GO photocatalysts after degradation of dye (MG/MB) is still significant.

3.13. Plausible Photocatalytic Mechanism

The plausible mechanism for the photocatalytic activity of the catalyst can be attributed to the presence of π-conjugation and 2D planar structures of graphene oxide in the CuWO4-GO composite which can adsorb organic molecules easily on its surface via strong π-π interactions [29] . Additionally, graphene oxide possesses high charge carrier mobility and can be regarded as an electron acceptor. It can greatly decrease the recombination rate of photogenerated electrons and holes. Upon visible light excitation, the electron-hole pairs (h+, e) are generated on the copper tungstate-graphene oxide surface followed by the instant transfer of photogenerated electrons onto graphene oxide via a percolation mechanism and then the negatively charged graphene oxide can activate the dissolved oxygen to produce superoxide anion radical, while the holes can react with the adsorbed water to form hydroxyl radical. Finally, the active species, holes, superoxide anion radical and hydroxyl radical oxidize the Methylene blue and Malachite green dye molecules adsorbed on the active sites of the copper tungstate-graphene oxide system through the π-π stacking and electrostatic attraction.

CuWO 4 -GO + h υ e + h + + CuWO 4 -GO

h + + H 2 O O H + H +

h + + O O H

h + + C 16 H 18 N 3 S + Cl ( C 16 H 18 N 3 S + Cl ) +

h + + C 23 H 25 ClN 2 ( C 23 H 25 ClN 2 ) +

e + O 2 O 2

O 2 + H + O OH

O OH O 2 + H 2 O 2

H 2 O 2 + O 2 O H + OH + O 2

H 2 O 2 + h υ 2 O H

C 16 H 18 N 3 S + Cl + ( O H , H + O OH or O 2 ) CO 2 + H 2 O + SO 4 2 + NO 3

C 23 H 25 ClN 2 + ( O H , H + O OH or O 2 ) CO 2 + H 2 O + SO 4 2 + NO 3

4. Conclusion

In summary, we have demonstrated the synthesis of CuWO4-GO nano composite by metathesis and colloidal blending processes. The results demonstrated that CuWO4-10% GO nano composite acts as an excellent photocatalyst for degradation of Methylene blue and Malachite green dyes under visible light irradiation. This catalyst causes complete degradation of Methylene blue dye in 60 min and Malachite green dye in 80 min of irradiation of visible light. The effect of pH and temperature on degradation and the reusability of the catalyst are also studied. As a result, this work provides a new method of developing a promising photo catalyst for the degradation of dyes.

Acknowledgements

Authors thank the UGC, SERO, Hyderabad for providing UGC-FDP Teacher Fellowship to M. Sunitha and UGC, MHRD, New Delhi for providing financial assistance through UGC-MRP No. 41-371/2012 (SR) to S. Paul Douglas. Authors thank Prof. M. Uma Bala, HOD, Dept. of Inorganic and Analytical Chemistry, Andhra University for UV-DRS studies, IICT Hyderabad for SEM, FT-IR and XRD, Centre for Nanotechnology, AUCE (A), AU for ball milling and JNTUK, Kakinada for Raman spectral studies.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Medidi, S. , Markapurapu, S. , Kotupalli, M. , Chinnam, R. , Susarla, V. , Gandham, H. and Sanasi, P. (2018) Visible Light Photocatalytic Degradation of Methylene Blue and Malachite Green Dyes with CuWO4-GO Nano Composite. Modern Research in Catalysis, 7, 17-34. doi: 10.4236/mrc.2018.72002.

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