Ablation Properties of C Fibers and SiC Fibers Reinforced Glass Ceramic Matrix Composites Upon Oxyacetylene Torch Exposure

DOI: 10.4236/msa.2011.210189   PDF   HTML     5,864 Downloads   9,484 Views   Citations


The ablation properties of two laminated composites, having both a glass ceramic matrix and different kinds of fibers (C or SiC) with the same architecture, are evaluated and compared. Ablation tests are performed using an oxyacetylene torch on samples having two different thicknesses. Mass loss and ablation depth are measured after flame exposure. The results obtained show that the decomposition of SiC fibers during thermal exposure has a significant impact on ablation behavior. Oxidation of SiC produces a liquid SiO2 film at the top of the material during ablation. This leads to an improved ablation resistance compared to the glass ceramic matrix/C composite, especially in case of successive flame exposures where the SiO2 film consumes a substantial fraction of the heat flow during its liquefaction upon re-heating.

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J. Beaudet, J. Cormier, A. Dragon, M. Rollin and G. Benoit, "Ablation Properties of C Fibers and SiC Fibers Reinforced Glass Ceramic Matrix Composites Upon Oxyacetylene Torch Exposure," Materials Sciences and Applications, Vol. 2 No. 10, 2011, pp. 1399-1406. doi: 10.4236/msa.2011.210189.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] D. E. Glass, “Ceramic Matrix Composite (CMC) Thermal Protection Systems (TPS) and Hot Structures for Hypersonic Vehicles,” 15th AIAA Space Planes and Hypersonic Systems and Technologies Conference, Dayton, 28 April- 1 May 2008, pp. 1-36.
[2] B. Chen, L. T. Zhang, L. F. Cheng and X. G. Luan, “Ablation of Pierced C/C Composite Nozzles in an Oxygen/Ethanol Combustion Gas Generator,” Carbon, Vol. 47, No. 3, 2009, pp. 291-293. doi:10.1016/j.carbon.2008.10.009
[3] Y. J. Lee and H. J. Joo,” Ablation Characteristics of Carbon Fiber Reinforced Carbon (CFRC) Composites in the Presence of Silicon Carbide (SiC) Coating,” Surface & Coatings Technology,Vol. 180-181, 2004, pp. 289-289. doi:10.1016/j.surfcoat.2003.10.071
[4] S. Biamino, V. Liedtke, C. Badini, G. Euchberger, I. H. Olivares, M. Pavese and P. Fino, “Multilayer SiC for Thermal Protection System of Space Vehicles: Manufacturing and Testing under Simulated Re-Entry Conditions.,” Journal of the European Ceramic Society, Vol. 28, No. 14, 2008, pp. 2791-2800. doi:10.1016/j.jeurceramsoc.2008.04.006
[5] A. R. Bahramian, M. Kokabi, M. H. N. Famili and M. H. Beheshty, “Ablation and Thermal Degradation Behaviour of a Composite Based on Resol Type Phenolic Resin: Process Modeling and Experimental,” Polymer, Vol. 47, No. 10, 2006, pp. 3661-3673. doi:10.1016/j.polymer.2006.03.049
[6] M. P. Bacos, “Carbon-Carbon Composites―Oxidation Be- havior and Coatings Protection,” Journal de Physique Archives, Vol. 3, No. C7, 1993, pp. 1895-1903. doi:10.1051/jp4:19937303
[7] S. F. Tang, J. Y. Deng, S. J. Wang and W. C. Liu, “Comparison of Thermal and Ablation Behaviors of C/SiC Composites and C/ZrB2-SiC Composites,” Corrosion Science, Vol. 51, No. 1, 2009, pp. 54-61. doi:10.1016/j.corsci.2008.09.037
[8] B. Yan, Z. F. Chen, J. X. Zhu, J. Z. Zhang and Y. Jiang, “Effects of Ablation at Different Regions in Three-Dimen- sional Orthogonal C/SiC Composites Ablated by Oxyacetylene Torch at 1800?C,” Journal of Materials Processing Technology, Vol. 209, No. 7, 2009, pp 3438-3443.
[9] Z. Chen, D. Fang and B. Yan, “Comparison of Morphology and Microstructure of Ablation Centre of C/SiC Composites by Oxy-Acetylene Torch at 2900?C and 3550?C,” Corrosion Science, Vol. 50, No. 12, 2008, pp. 3378-3381. doi:10.1016/j.corsci.2008.07.019
[10] D. Fang, Z. Chen , Y. Song and Z. Sun, “Morphology and Microstructure of 2.5 Dimension C/SiC Composites Ablated by Oxyacetylene Torch,” Ceramic International, Vol. 35, No. 3, 2009, pp. 1249-1253. doi:10.1016/j.ceramint.2008.06.008
[11] M. Hussain, R. J. Varley, Y. B. Cheng and G. P. Simon, “Investigation of Thermal and Fire Performance of Novel Hybrid Geopolymer Composites,” Journal of Material Science, Vol. 39, No. 14, 2004, pp. 4721-4726. doi:10.1023/B:JMSC.0000034180.35216.ba
[12] A. C. J. Flowerday, P. N. H. Wright, R. O. Ledger and A. G. Gibson, “Investigation into the Use of Geopolymers for Fire Resistant Marine Composites,” Advanced Marine Materials and Coatings International Conference, London, 22-23 February 2006, pp. 37-44.
[13] C. Buchler and M. Rollin, “User-Friendly Composites That Take the Heat,” JEC Composites Magazine, Vol. 53, 2009, pp. 33-35.
[14] G. Pulci, J. Tirillo, F. Marra, F. Fossati, C. Bartuli and T. Valente, “Carbon-Phenolic Ablative Materials for Re-En- try Space Vehicles: Manufacturing and Properties,” Com- posites Part A: Applied Science and Manufacturing, Vol. 41, No. 10, 2010, pp. 1483-1490.
[15] Y. I. Dimitrienko, “Thermomechanical Behaviour of Composite Materials and Structures under High Temperatures: 1,” Composites Part A: Applied Science and Manufacturing, Vol. 28, No. 5, 1997, pp. 453-461.
[16] J. E. J. Staggs, “A Discussion of Modelling Idealised Ablative Materials with Particular Reference to Fire Testing,” Fire Safety Journal, Vol. 28, No. 1, 1997, pp. 44-66. doi:10.1016/S0379-7112(96)00062-8
[17] C. Argirusis, T. Damjanovic and G. Borchardt, “Yttrium Silicate Coating System for Oxidation Protection of C/C-Si-SiC Composites: Electrophoretic Deposition and Oxygen Self-Diffusion Measurements,” Fire Safety Jour- nal, Vol. 27, No. 2-3, 2007, pp. 1303-1306.
[18] W. L. Vaughn and H. G. Maahs, “Active-to-Passive Transition in the Oxidation of Silicon-Carbide and Silicon-Nitride in Air,” Journal of the American Ceramic Society, Vol. 73, No. 6, 1993, pp. 1540-1543. doi:10.1111/j.1151-2916.1990.tb09793.x

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