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Spectroscopic investigation and density functional theory calculations of mercaptobenzothiazole and mercaptobenzimidazole ligands and their rhenium complexes

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DOI: 10.4236/ojic.2011.12004    4,462 Downloads   10,454 Views   Citations

ABSTRACT

Four complexes containing the [Re(V)O]3+ core have been prepared by substitution on the precursors RO(citrate)2- and ReO(gluconate)2-. The complex [ReO(MBT)2OH] was obtained by reaction of the direct reduction of ReO4- using sodium borohydride as a reducing agent. Four complexes were character-ized by UV-Vis and IR spectrophotometer, elemental analyses, 1H-and 13C NMR spectroscopy, TG and DFT calculations.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

AlHokbany, N. and AlJammaz, I. (2011) Spectroscopic investigation and density functional theory calculations of mercaptobenzothiazole and mercaptobenzimidazole ligands and their rhenium complexes. Open Journal of Inorganic Chemistry, 1, 23-32. doi: 10.4236/ojic.2011.12004.

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