Synthesis and Characterization of Liquid Crystal Elastomer

Abstract

The thermal and mechanical properties of Liquid Crystal Elastomers (LCEs) were characterized using various techniques for understanding of their physical behavior. The material used for investigation was synthesized by us, using Finklemann procedure, with proper cross linking density in nematic phase. The material is found to have unique coupling between anisotropicorder of liquid crystal component and elasticity of polymer network. The chemical structures were confirmed by Fourier Transform Infrared (FTIR) Spectroscopy and Scanning Electron Microscopy (SEM). Fabry Perot Scattering Studies (FPSS), Thermo gravimetric Analysis (TGA) and Differential Scanning Calorimatory (DSC) were used to study thermal properties. The mechanical properties were studied using force sensor. Our investigation shows that this synthesized Liquid Crystal Elastomer has ability of spontaneous change as a function of temperature and mechanical force, which shows it as a unique class of soft material.

Share and Cite:

Gharde, R. , Mani, S. , Lal, S. , Khosla, S. and Tripathi, S. (2015) Synthesis and Characterization of Liquid Crystal Elastomer. Materials Sciences and Applications, 6, 527-532. doi: 10.4236/msa.2015.66056.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] De Gennes, P.G. (1975) The Physics of Liquid Crystals. Oxford University Press, Oxford.
[2] Zental, R. and Reckert, G. (1986) Liquid Crystalline Elastomers Based on Liquid Crystalline Side Group, Main Chain and Combined Polymers. Die Makromolekulare Chemie, 187, 1915-1926.
http://dx.doi.org/10.1002/macp.1986.021870811
[3] Terentjev, E.M. (1999) Liquid-Crystalline Elastomers. Journal of Physics: Condensed Matter, 11, 239-257.
http://dx.doi.org/10.1088/0953-8984/11/24/201
[4] Legge, C.H., Davis, J. and Mitchell, G.R. (1991) Memory Effects in Liquid Crystal Elastomers. Journal de Physique, 21, 1253-1261.
http://dx.doi.org/10.1051/jp2:1991131
[5] Finkelman, H. and Kupfer, J. (1991) Nematic Liquid Single Crystal Elastomers. Die Makromolekulare Chemie, Rapid Communications, 12, 717-726.
http://dx.doi.org/10.1002/marc.1991.030121211
[6] Fridrikh, S.V. and Terentjev, E.M. (1999) Polydomain-Monodomain Transition in Nematic Elastomers. Physical Review E, 60, 1847.
http://dx.doi.org/10.1103/PhysRevE.60.1847
[7] Tajbakhsh, A.R. and Terentjev, E.M. (2001) Spontaneous Thermal Expansion of Nematic Elastomers. The European Physical Journal E, 6, 181-188.
http://dx.doi.org/10.1007/s101890170020
[8] Finkelmann, H., Koch, H.J. and Rehange, G. (1981) Investigation of Liquid Crystalline Polysiloxanes 3. Liquid Crystalline Elastomers—A New Type of Liquid Crystalline Materials. Die Makromolekulare Chemie, Rapid Communications, 2, 317-322.
[9] Bispo, M., Guillon, D., Donnio, B. and Finkelmann, H. (2008) Main-Chain Liquid Crystalline Elastomers: Monomer and Cross-Linker Molecular Control of the Thermotropic and Elastic Properties. Macromolecules, 41, 3098-3108.
http://dx.doi.org/10.1021/ma7026929
[10] Hogan, P.M., Tajbakhsh, A.R. and Terentjev, E.M. (2001) UV-Manipulation of Order and Macroscopic Shape in Nematic Elastomers. Cond. Mat.
[11] Perline, R., Kornbluh, R., Pei, Q. and Joseph, J. (2000) High-Speed Electrically Actuated Elastomers with Strain Greater Than 100%. Science, 287, 836-839.
[12] Warner, M. and Terentjev, E.M. (2003) Liquid Crystal Elastomers. Clarendon Press, Oxford.
[13] David, P.K. and Fritz, V. (2002) Biological Liquid Crystal Elastomers. Philosophical Transactions of the Royal Society B, 357, 155-163.
[14] Dukes, D., Li, Y., Lewis, S., Benicewicz, B., Schadler, L. and Kumar, S.K. (2010) Conformational Transitions of Spherical Polymer Brushes: Synthesis, Characterization, and Theory. Macromolecules, 43, 1564-1570.
http://dx.doi.org/10.1021/ma901228t
[15] Biggins, J.S., Warner, M. and Bhattacharya, K. (2012) Elasticity of Polydomain Liquid Crystal Elastomers. Journal of the Mechanics and Physics of Solids, 60, 573-590.
http://dx.doi.org/10.1016/j.jmps.2012.01.008
[16] Jayaraman, A.J. (2013) Polymer Grafted Nanoparticles: Effect of Chemical and Physical Heterogeneity in Polymer Grafts on Particle Assembly and Dispersion. Journal of Polymer Science Part B: Polymer Physics, 51, 524-534.
http://dx.doi.org/10.1002/polb.23260

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.