Green and Efficient Oxidation of Octanol by Iron Oxide Nanoparticles Supported on Activated Carbon

Mohammad Sadiq; Razia Aman; Saddam Hussain; Muhammad Abid Zia; Najeeb Ur Rahman; Mohammad Saeed

doi:10.4236/mrc.2015.41004

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Modern Research in Catalysis > Vol.4 No.1, January 2015

Green and Efficient Oxidation of Octanol by Iron Oxide Nanoparticles Supported on Activated Carbon ()

Mohammad Sadiq^1*, Razia Aman¹, Saddam Hussain¹, Muhammad Abid Zia², Najeeb Ur Rahman¹, Mohammad Saeed³

¹Department of Chemistry, University of Malakand, Khyber Pakhtunkhwa, Pakistan.
²Department of Chemistry, University of Education, Attock Campus, Attock, Pakistan.
³Department of Chemistry, GC University, Faisalabad, Pakistan.

DOI: 10.4236/mrc.2015.41004 PDF HTML XML 4,599 Downloads 5,327 Views Citations

Abstract

Iron oxide nanoparticles were synthesized by precipitation method and supported on activated carbon. The catalyst thus obtained was characterized by various physicochemical techniques, and used for the liquid phase dehydrogenation/oxidation of octanol in a batch reactor at various temperatures in the range 30 °C - 60 °C. Maximum conversion of octanol to octanal was attained at 60°;C in 30 min. However, with longer reaction time, the selectivity of the catalyst was found to change in favor of octene as a product. The catalyst could be recovered and reused multiple times without any decline in its catalytic performance.

Keywords

Liquid Phase, Oxidation, Dehydration, Octanol

Share and Cite:

Sadiq, M. , Aman, R. , Hussain, S. , Zia, M. , Rahman, N. and Saeed, M. (2015) Green and Efficient Oxidation of Octanol by Iron Oxide Nanoparticles Supported on Activated Carbon. Modern Research in Catalysis, 4, 28-35. doi: 10.4236/mrc.2015.41004.

Conflicts of Interest

The authors declare no conflicts of interest.

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