A Chiral Three Dimensional Potassium(I)/Strontium(II)/Chromium(III) Oxalato-Bridged Coordination Polymer: Synthesis, Characterization and Thermal Analysis

DOI: 10.4236/csta.2014.34008   PDF   HTML   XML   3,916 Downloads   4,716 Views   Citations


A new compound of general formula {[(H2O)2K(μ-H2O)Sr]@[Cr(C2O4)3]}n (1) has been synthesized in water and characterized by elemental and thermal analyses, EDX, IR and UV-Vis spectroscopies and by single crystal X-ray structure determination. Compound 1 crystallizes in the chiral space group Fdd2 of orthorhombic system with a = 14.110 (4) ?, b = 36.074 (11)?, c =11.034 (3)? and Z = 16. Compound 1 is a coordination polymer in which the three-dimensional lattice framework is realized by the interconnectivity between K+ cations, Sr2+ cations, aqua ligands and [Cr(C2O4)3]3 complex anions. The asymmetric unit of 1 consists of one cationic motif formally written [(H2O)2K(μ-H2O)Sr]3+ and one anionic entity, [Cr(C2O4)3]3. The K+ and Sr2+ ions in the cationic motif are both eight-coordinate while the Cr3+ ions in the anionic complex are six-coordinate in a distorted octahedral geometry. Coulombic interactions between the ionic motifs and the three-dimensional H-bonding involving aqua ligands help to consolidate the bulk structure. Thermogra-vimetric analysis (TGA) shows that compound 1 is stable to heat up to ca. 80.

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Nenwa, J. , Kaboré, I. , Mbiangué, Y. , Djonwouo, P. and Ndifon, P. (2014) A Chiral Three Dimensional Potassium(I)/Strontium(II)/Chromium(III) Oxalato-Bridged Coordination Polymer: Synthesis, Characterization and Thermal Analysis. Crystal Structure Theory and Applications, 3, 67-75. doi: 10.4236/csta.2014.34008.

Conflicts of Interest

The authors declare no conflicts of interest.


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