Adhesion of Silica Particles on Thin Polymer Films Model of Flax Cell Wall

Samia Mahouche-Chergui^1*, Yves Grohens¹, Eric Balnois¹, Bénédicte Lebeau², Yves Scudeller³

¹Laboratory of Materials Engineering of Brittany, University of South Britany, Morbihan, France.
²Mulhouse Materials Science Institute, University of Haute Alsace, Mulhouse, France.
³LGMPA, University of Nantes-Polytechnic School, France.

DOI: 10.4236/msa.2014.513097                

Abstract

The present work is focused on better understanding of the interfacial interactions of SBA-15 mesoporous silica particles with flax fibers. In order to overcome the inherent complexity of flax fiber surface composition we have prepared model polysaccharide surfaces representing the main component of the flax fibers, e.g. cellulose, polygalacturonic acid (PGUA), and xyloglucan (XG) with thicknesses of about 200 nm, 100 nm, and 110 nm, respectively. The ξ-potential measurements of both silica and polysaccharides were performed in aqueous solutions as a function of pH and ionic strength. ξ-potential, AFM and SEM results supported the important role of electrostatic interactions in the silica adsorption on polysaccharide surfaces, since silica adsorption increased remarkably with ionic strength. The adsorption density of the SBA-15 onto the various polysaccharides was Cellulose > PGUA > XG, and the maximum was observed at pH = 4. Urea used as hydrogen bonds breaker reduced significantly the adsorption of SBA-15 on the polysaccharide surfaces, which highlighted the significant contribution of hydrogen bonding in the adsorption process. It was observed that most adsorbed SBA-15 particles were resistant to ultrasonic washing, which revealed their strong irreversible adsorption. Finally, direct adsorption experiments on both raw and treated real flax fibers yielded results consistent with those of model surfaces showing the important role of the surface fibers treatments on the improvement of the interfacial adhesion of the silica particles with flax fibers. The remarkable affinity of the SBA-15 particles with treated flax fibers is encouraging to design superinsulators composites with tuneable mechanical performances.

Keywords

Adhesion, SBA-15 Mesoporous Silica, Polysaccharides, Model Surfaces, Flax Fibers

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1]	Markus, S., Edgar, R.F.W., Raymond, V. and Thomas, S.J. (2004) Theoretical Studies of High-Temperature Multilayer Thermal Insulations Using Radiation Scaling. Journal of Quantitative Spectroscopy and Radiative Transfer, 84, 477491. http://dx.doi.org/10.1016/S0022-4073(03)00264-4
[2]	Holman, J.P. (2005) Heat Transfer. China Machine Press, Boca Raton.
[3]	Zeng, S.Q., Hunt, A. and Greif, R.J. (1995) Theoretical Modeling of Carbon Content to Minimize Heat Transfer in Silica Aerogel. Journal of Non-Cryst Solids, 186, 271-277. http://dx.doi.org/10.1016/0022-3093(95)00076-3
[4]	Kennard, E.H. (1938) Kinetic Theory of Gases, with an Introduction to Statistical Mechanics. McGraw-Hill, New York.
[5]	Baetensa, R., Jelle, B.P. and Gustavsend, A. (2011) Aerogel Insulation for Building Applications: A State-of-the-Art Review. Energy and Buildings, 43, 761-769. http://dx.doi.org/10.1016/j.enbuild.2010.12.012
[6]	Biesmans, G., Randall, D., Francais, E. and Perrut, M. (1998) Caracterisation des Proprietes des Aerogels. Proceedings of the 5th International Symposium on Aerogels (ISA 5), 225, 220-225.
[7]	Rigacci, A., Marechal, J.C., Repoux, M., Moreno, M. and Achard, P. (2004) Preparation of Polyurethane-Based Aerogels and Xerogels for Thermal Superinsulation. Journal of Non-Crystalline Solids, 350, 372-378. http://dx.doi.org/10.1016/j.jnoncrysol.2004.06.049
[8]	Kim, C.-Y., Lee, J.-K. and Kim, B.-I. (2008) Synthesis and Pore Analysis of Aerogel-Glass Fiber Composites by Ambient Drying Method. Colloids and Surfaces A: Physicochemical Engineering Aspects, 313-314, 179-182. http://dx.doi.org/10.1016/j.colsurfa.2007.04.090
[9]	Clark, J.H. and Macquarrie, D.J. (2009) Tuneable Porous Carbonaceous Materials from Renewable Resources. Journal of Materials Chemistry, 19, 8512-8514. http://dx.doi.org/10.1039/b920323k
[10]	Huijun, W., Jintu, F. and Ning, D. (2007) Thermal Energy Transport within Porous Polymer Materials: Effects of Fiber Characteristics. Journal of Applied Polymer Science, 106, 576-583. http://dx.doi.org/10.1002/app.26603
[11]	Morvan, C., Onzighi, C.A., Girault, R., Himmelsbach, D.S., Driouich, A. and Akin, D.E. (2003) Building Flax Fibres: More than One Brick in the Walls. Plant Physiology and Biochemistry, 41, 935-944. http://dx.doi.org/10.1016/j.plaphy.2003.07.001
[12]	Charlet, K., Baley, C., Morvan, C., Jernot, J.P., Gomina, M. and Bréard, J. (2007) Characteristics of Hermès Flax Fibres as a Function of Their Location in the Stem and Properties of the Derived Unidirectional Composites. Composites Part A: Applied Science and Manufacturing, 38, 1912-1921. http://dx.doi.org/10.1016/j.compositesa.2007.03.006
[13]	Baley, C., Busnel, F., Grohens, Y. and Sire, O. (2006) Influence of Chemical Treatments on Surface Properties and Adhesion of Flaxfibre-Polyester resin. Composites Part A: Applied Science and Manufacturing, 37, 1626-1637. http://dx.doi.org/10.1016/j.compositesa.2005.10.014
[14]	Arbelaiz, A., Cantero, G., Fernández, B., Mondragon, I., Ganán, P. and Kenny, J.M. (2005) Flax Fiber Surface Modifications: Effects on Fiber Physico Mechanical and Flax/Polypropylene Interface Properties. Polymer Composites, 26, 324-332. http://dx.doi.org/10.1002/pc.20097
[15]	Kymalainen, H.R. and Sjoberg, A.M. (2008) Flax and Hemp Fibres as Raw Materials for Thermal Insulations. Building and Environment, 43, 1261-1269. http://dx.doi.org/10.1016/j.buildenv.2007.03.006
[16]	Kozlowski, R., Mieleniak, B., Muzyczek, M. and Mańkowski, J. (2008) Development of Insulation Composite Based on FR Bast Fibers and Wool. International Conference on Flax and Other Bast Plants, Saskatoon, 21-23 July 2008, 176-182.
[17]	El Hajj, N., Mboumba-Mamboundou, B., Dheilly, R.M., Aboura, Z., Benzeggagh, M. and Queneudec, M. (2011) Development of Thermal Insulating and Sound Absorbing Agro-Sourced Materials from Auto Linked Flax-Tows. Industrial Crops and Products, 34, 921-928. http://dx.doi.org/10.1016/j.indcrop.2011.02.012
[18]	Innerlohinger, J., Weber, H.K. and Kraft, G. (2006) Aerocell Aerogels from Cellulose Materials. Lenzinger Berichte, 86, 137-143.
[19]	Choi, H.G., Ha, T.J., Yu, B.G., Jaung, S.P., Kwon, O. and Park, H.H. (2008) Improvement of Uncooled Infrared Imaging Detector by Using Mesoporous Silica as a Thermal Isolation Layer. Asian Meeting on Electroceramics, 34, 833836.
[20]	Holmberg, M., Wigren, R., Erlandsson, R. and Claesson, P.M. (1997) Interactions between Cellulose and Colloidal Silica in the Presence of Polyelectrolytes. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 129-130, 175-183. http://dx.doi.org/10.1016/S0927-7757(97)00036-8
[21]	Hou, A., Shi, Y. and Yu, Y. (2009) Preparation of the Cellulose/Silica Hybrid Containing Cationic Group by Sol-Gel Crosslinking Process and Its Dyeing Properties. Carbohydrate Polymers, 77, 201-205. http://dx.doi.org/10.1016/j.carbpol.2008.12.022
[22]	Kalia, S., Dufresne, A., Cherian, B.M., Kaith, B.S., Avérous, L., Njuguna, J. and Nassiopoulos, E. (2011) CelluloseBased Bioand Nanocomposites: A Review. International Journal of Polymer Science, 2011, Article ID: 837875. http://dx.doi.org/10.1155/2011/837875
[23]	Kapsabelis, S. and Prestidge, C.A. (2000) Adsorption of Ethyl(hydroxyethyl)cellulose onto Silica Particles: The Role of Surface Chemistry and Temperature. Journal of Colloid and Interface Science, 228, 297-305. http://dx.doi.org/10.1006/jcis.2000.6976
[24]	Raj, G., Balnois, E., Baley, C. and Grohens, Y. (2011) Role of Polysaccharides on Mechanical and Adhesion Properties of Flax Fibres in Flax/PLA Biocomposite Role of Polysaccharides on Mechanical and Adhesion Properties of Flax Fibres in Flax/PLA Biocomposite. International Journal of Polymer Science, 2011, Article ID: 503940.
[25]	Bendahou, A., Kaddami, H., Sautereau, H., Raihane, M., Erchiqui, F. and Dufresne, A. (2008) Short Palm Tree Fibers Polyolefin Composites: Effect of Filler Content and Coupling Agent on Physical Properties. Macromolecular Materials and Engineering, 293, 140-148. http://dx.doi.org/10.1002/mame.200700315
[26]	Kalia, S., Kaith, B.S. and Kaur, I. (2009) Pretreatments of Natural Fibers and Their Application as Reinforcing Material in Polymer Composites: A Review. Polymer Engineering and Science, 49, 1253-1272. http://dx.doi.org/10.1002/pen.21328
[27]	Kirby, B.J. and Hasselbrink Jr., E.F. (2004) Theory, Experimental Techniques, and Effects on Separations. Electrophoresis, 25, 187-202. http://dx.doi.org/10.1002/elps.200305754
[28]	Nakamura, A., Furuta, H., Kato, M., Maeda, H. and Nagamatsu, Y. (2003) Effect of Soybean Soluble Polysaccharides on the Stability of Milk Protein under Acidic Conditions. Food Hydrocolloids, 17, 333-343. http://dx.doi.org/10.1016/S0268-005X(02)00095-4
[29]	Kolasińska, M., Zembala, M., Krasowskaa, M. and Warszyńskia, P. (2008) Probing of Polyelectrolyte Monolayers by Zeta Potential and Wettability Measurements. Journal of Colloid and Interface Science, 326, 301-304. http://dx.doi.org/10.1016/j.jcis.2008.06.053
[30]	Obaidat, R., Al-Jbour, N., Al-Sou’d, K., Sweidan, K., Al-Remawi, M. and Badwan, A. (2010) Some Physico-Chemical Properties of Low Molecular Weight Chitosans and Their Relationship to Conformation in Aqueous Solution for Cellulose Chains. Journal of Solution Chemistry, 39, 575-588. http://dx.doi.org/10.1007/s10953-010-9517-x
[31]	Carneiro-da-Cunhaa, M.G., Cerqueira, M.A., Souza, B.W.S., Teixeira, J.A. and Vicente, A.A. (2011) Influence of Concentration, Ionic Strength and pH on Zeta Potential and Mean Hydrodynamic Diameter of Edible Polysaccharide Solutions Envisaged for Multinanolayered Films Production. Carbohydrate Polymers, 85, 522-528. http://dx.doi.org/10.1016/j.carbpol.2011.03.001
[32]	Mishima, T., Hisamatsu, M., York, W.S., Teranishi, K. and Yamada, T. (1998) Adhesion of β-D-Glucans to Cellulose. Carbohydrate Research, 308, 389-395. http://dx.doi.org/10.1016/S0008-6215(98)00099-8
[33]	Bellmann, C., Caspari, A., Doan, T.T.L. and Mader, E. (2004) Electrokinetic Properties of Natural Fibres. International Electrokinetics Conference, Pittsburgh, 13-17 June 2004, 245-248.
[34]	Bismarck, A., Aranbefwi-Askargorta, I., Springer, J., Lampke, T., Wielage, B., Stamboulis, A., et al. (2002) Surface Characterization of Flax, Hemp and Cellulose Fibers; Surface Properties and the Water Uptake Behavior. Polymer Composites, 23, 872-894. http://dx.doi.org/10.1002/pc.10485
[35]	Uetani, K. and Yano, H. (212) Zeta Potential Time Dependence Reveals the Swelling Dynamics of Wood Cellulose Nanofibrils. Langmuir, 28, 818-827. http://dx.doi.org/10.1021/la203404g
[36]	Ribitsch, V., Stana-Kleinschek, K., Kreze, T. and Strnad, S. (2001) The Significance of Surface Charge and Structure on the Accessibility of Cellulose Fibres. Macromolecular Materials and Engineering, 286, 648-654. http://dx.doi.org/10.1002/1439-2054(20011001)286:10<648::AID-MAME648>3.0.CO;2-6
[37]	Necesany, V. (1971) The Isoelectric Point of Lignified Cell Walls. European Journal of Wood and Wood Products, 29, 354-357. http://dx.doi.org/10.1007/BF02621436
[38]	Kosmulski, M. and Dekker, M. (2001) Chemical Properties of Material Surfaces.
[39]	Zhang, Y., Ghasemzadeh, S., Kotliar, A.M., Kumar, S., Presnell, S. and Williams, L. (1999) Fibers from Soybean Protein and Poly(vinyl alcohol). Journal of Applied Polymer Science, 71, 11-19. http://dx.doi.org/10.1002/(SICI)1097-4628(19990103)71:1<11::AID-APP3>3.0.CO;2-1
[40]	Wang, J. and Somasundaran, P. (2005) Adsorption and Conformation of Carboxymethyl Cellulose at Solid-Liquid Interface Using Spectroscopic, AFM and Allied Techniques. Journal of Colloid and Interface Science, 291, 75-83. http://dx.doi.org/10.1016/j.jcis.2005.04.095
[41]	Bledzki1, A.K., Mamun, A.A., Lucka-Gabor, A. and Gutowski, V.S. (2008) The Effects of Acetylation on Properties of Flax Fibre and Its Polypropylene Composites. Express Polymer Letters, 2, 413-422. http://dx.doi.org/10.3144/expresspolymlett.2008.50
[42]	Raj, G., Balnois, E., Baley, C. and Grohens, Y. (2010) Role of Polysaccharides on Mechanical and Adhesion Properties of Flax Fibres in Flax/PLA Biocomposite. International Journal of Polymer Science, 2011, Article ID: 503940. http://dx.doi.org/10.1155/2011/503940
[43]	Wang, B., Panigrahi, S., Tabil, L., Crerar, W. and Sokansanj, S. (2003) Modification of Flax Fibers by Chemical Treatment. CSAE/SVGR Meeting, Montréal, 6-9 July 2003, 88-94.