Risk Points of Flame Retardant Textiles by Halogen and Halogen-Free Laminating Film

Yoon Jeong Baek; Jeoung Hwa Shin

doi:10.4236/msa.2014.511083

Home > Journals > Chemistry & Materials Science > MSA

Materials Sciences and Applications > Vol.5 No.11, September 2014

Risk Points of Flame Retardant Textiles by Halogen and Halogen-Free Laminating Film ()

¹Department of Textiles, Merchandising and Fashion Design, Seoul National University, Seoul, Korea.
²Seoul Center, Korea Basic Science Institute, Seoul, Korea.

DOI: 10.4236/msa.2014.511083 PDF HTML 3,895 Downloads 4,408 Views Citations

Abstract

This study was to develop the flame retardant (FR) protective clothing which had multifunction such anti-bacterial, UV cut, FR function with water repellent and water vapor permeable laminating textiles for industrial workers. First of all, the FR yarn and FR textiles were developed for this purpose. Second, the comparison analysis between the halogen laminating textiles and halogen-free laminating textiles were tested to figure out the eco-friendly laminating method. Third, the flame retardant ability was compared the halogen laminated textiles to halogen-free laminated textiles. LOI, UV protection ratio, antibiosis after 50 laundry test, water proof pressure, and moisture permeability of developed textiles were tested. GC-HR-TOF-MS was used for analysis of laminating film (halogen and halogen-free). 4.1 wt% TiO2 yarn showed antibacterial function (Pneumococcus & Staphylococcus aureus: 99.9%), UV Protection (UVA: 90.8, UVB: 92.1), and LOI (33.6). The chosen optimal compounding ratio for PU compound of HRF and HFFR were as followed: PU resin 58.3%, DMF (Dimethyl formamide, δ = 12.2) 8.3%, MEK (Methylethylketone) 8.3% and FR (flame retardants) 25.0%. Binder for laminating should not be included over 10% of FRs because of adhesion between textiles and FR laminating film. There were detected phosphorus compounds in the textiles treated by halogenated type flame retardants and halogenated-free type flame retardants. There were not any detected harmful compounds from all textile samples.

Keywords

Flame Retardant Yarn, Flame Retardant Textiles, GC-HR-TOF-MS, Halogen Laminating Textiles, Halogen-Free Laminating Textiles

Share and Cite:

Baek, Y. and Shin, J. (2014) Risk Points of Flame Retardant Textiles by Halogen and Halogen-Free Laminating Film. Materials Sciences and Applications, 5, 830-836. doi: 10.4236/msa.2014.511083.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1]	Jang, B.N. and Choi, J. (2009) Research Trend of Flame Retardant and Flame Retardant Resin. Polymer Science and Technology, 20, 8-15.
[2]	National Emergency Management Agency (2008) Standards of Flame Retardant Performance. Notification No. 2008-24.
[3]	Lee, S.H. (2013) Fabrication and Characteristics of Flame Retardant Fabric Developed by Using Bicomponent Filament. Textile Coloration and Finishing, 25, 110-117. http://dx.doi.org/10.5764/TCF.2013.25.2.110
[4]	Ko, J. and Park, P. (2010) An Experimental Study on the Fire Risk Assessment and Calculation Breakthrough Time through Permeation Test of Chemical Protective Clothing. Journal of Korean Institute of Fire Science and Engineering, 24, 21-30.
[5]	OECD (1994) Risk Reduction Monograph 3. OECD, Paris.
[6]	WHO (1994) Environmental Health Criteria 162. International Program on Chemical Safety, WHO, Geneva.
[7]	WHO (1997) Environmental Health Criteria 192. International Program on Chemical Safety, WHO, Geneva.
[8]	WHO (1998) Environmental Health Criteria 209. International Program on Chemical Safety, WHO, Geneva.
[9]	Al-Maamori, M., Al-Mosawi, A. and Hasim, A. (2011) Flame Retardancy Enhancement of Hybrid Composite Material by Using Inorganic Retardants. Materials Science and Application, 2, 1134-1138. http://dx.doi.org/10.4236/msa.2011.28153
[10]	Green, J. (2000) Fire Retardancy of Polymeric Materials. Marcel Dekker, New York.
[11]	Jang, B.N., Jung, I. and Choi, J. (2009) Study of a Novel Halogen-Free Flame Retardant System through TGA and Structure Analysis of Polymers. Journal of Applied Polymer Science, 112, 2669-2675. http://dx.doi.org/10.1002/app.29803
[12]	Morgan, A.B. and Gilman, J.W. (2013) An Overview of Flame Retardancy of Polymeric Materials: Application, Technology, and Future Directions. Fire and Materials, 37, 259-279. http://dx.doi.org/10.1002/fam.2128