Biopolymer Films and Coatings in Packaging Applications—A Review of Recent Developments

Abstract

This review covers the recent developments in the field of biobased packaging materials. Special emphasis is placed on the barrier properties, which are crucial in terms of food packaging. The state-of-the-art of several biopolymers including pectin, starch, chitosan, xylan, galactoglucomannan, lignin and cellulose nanofibrils is discussed. As in most cases the packaging related properties of single layer biopolymer films are inadequate, the thin film coatings, such as sol-gel and ALD (atomic layer deposition), as well as the multilayer coatings are also briefly touched.

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Vartiainen, J. , Vähä-Nissi, M. and Harlin, A. (2014) Biopolymer Films and Coatings in Packaging Applications—A Review of Recent Developments. Materials Sciences and Applications, 5, 708-718. doi: 10.4236/msa.2014.510072.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Johansson, C., Bras, J., Mondragon, I., Nechita, P., Plackett, D., Simon, P., Gregor Svetec, D., Virtanen, S., Giacinti Baschetti, M., Breen, C., Clegg, F. and Aucejo, S. (2012) Renewable Fibers and Bio-Based Materials for Packaging Applications—A Review of Recent Developments. BioResources, 7, 2506-2552.
[2] Harkki, O., Karttunen, M., Kortet, S., Koponen, M. and Harlin, A. (2011) Biaxially Oriented PLA-MontmorilloniteNanocomposite for Barrier Film Applications. Nanocomposites 2011, Paris-Est, Creteil University, 6 p.
[3] Koivistoinen, O. (2013) Catabolism of Biomass-Derived Sugars in Fungi and Metabolic Engineering as a Tool for Organic Acid Production. Espoo, 43.
[4] Vartiainen, J., Tammelin, T., Pere, J., Tapper, U. and Harlin, A. (2010) Biohybrid Barrier Films from Fluidized Pectin and Nanoclay. Carbohydrate Polymers, 82, 989-996.
http://dx.doi.org/10.1016/j.carbpol.2010.06.031
[5] Vartiainen, J., Kunnari, V. and Kokko, A. (2012) Bio-Hybrid Nanocomposite Roll-to-Roll Coatings for Fiber-Based Materials and Plastics. In: Thomas, S., et al., Eds., Natural Polymers, Biopolymers, Biomaterials, and Their Composites, Blends and IPNS, Advances in Materials Science, 2, 207-212.
[6] Matilainen, K., Harlin, A., Kunnari, V., Tammelin, T., Vartiainen, J., Pere, J., Vaha-Nissi, M., Mustonen, T., Hartman, J., Peltonen, S. and Harkonen, M. (2011) Up-Scaling Biohybrid Barrier Coating to Pilot Coater. International Workshop Safe Nanostructured Polymer Materials: Characterization and New Processing Technologies, Naples, 3-4 March 2011, 69.
[7] Forssell, P., Mikkila, J., Moates, G. and Parker, R. (1997) Phase and Glass Transition Behaviour of Concentrated Barley Starch-Glycerol-Water Mixtures, a Model for Thermoplastic Starch. Carbohydrate Polymers, 34, 275-282.
http://dx.doi.org/10.1016/S0144-8617(97)00133-1
[8] Forssell, P., Hulleman, S., Myllarinen, P., Moates, G. and Parker, R. (1999) Ageing of Rubbery Thermoplastic Barley and Oat Starches. Carbohydrate Polymers, 39, 43-51. http://dx.doi.org/10.1016/S0144-8617(98)00128-3
[9] Myllarinen, P., Buleon, A., Lahtinen, R. and Forssell, P. (2002) The Crystallinity of Amylose and Amylopectin Films. Carbohydrate Polymers, 48, 41-48.
http://dx.doi.org/10.1016/S0144-8617(01)00208-9
[10] Shamekh, S., Myllarinen, P., Poutanen, K. and Forssell, P. (2002) Film Formation Properties of Potato Starch Hydrolysates. Starch-Starke, 54, 20-24.
http://dx.doi.org/10.1002/1521-379X(200201)54:1<20::AID-STAR20>3.0.CO;2-M
[11] Talja, R., Helén, H., Roos, Y. and Jouppila, K. (2007) Effect of Various Polyols and Polyol Contents on Physical and Mechanical Properties of Potato Starch-Based Films. Carbohydrate Polymers, 67, 288-295.
http://dx.doi.org/10.1016/j.carbpol.2006.05.019
[12] Myllarinen, P., Partanen, R., Seppala, J. and Forssell, P. (2002) Effect of Glycerol on Behaviour of Amylose and Amylopectin Films. Carbohydrate Polymers, 50, 355-361.
http://dx.doi.org/10.1016/S0144-8617(02)00042-5
[13] Talja, R., Helén, H., Roos, Y. and Jouppila, K. (2008) Effect of Type and Content of Binary Polyol Mixtures on Physical and Mechanical Properties of Starch-Based Edible Films. Carbohydrate Polymers, 71, 269-276.
http://dx.doi.org/10.1016/j.carbpol.2007.05.037
[14] Forssell, P., Lahtinen, R., Lahelin, M. and Myllarinen, P. (2002) Oxygen Permeability of Amylose and Amylopectin Films. Carbohydrate Polymers, 47, 125-129.
http://dx.doi.org/10.1016/S0144-8617(01)00175-8
[15] Gaudin, S., Lourdin, D., Forssell, P. and Colonna, P. (2000) Antiplasticisation and Oxygen Permeability of StarchSorbitol Films. Carbohydrate Polymers, 43, 33-37.
http://dx.doi.org/10.1016/S0144-8617(99)00206-4
[16] Myllymaki, O., Myllarinen, P., Forssell, P., Suortti, T., Lahteenkorva, K., Ahvenainen, R. and Poutanen, K. (1998) Mechanical and Permeability Properties of Biodegradable Extruded Starch/Polycaprolactone Films. Packaging Technology and Science, 11, 265-274.
http://dx.doi.org/10.1002/(SICI)1099-1522(199811/12)11:6<265::AID-PTS438>3.0.CO;2-8
[17] Vartiainen, J. and Harlin, A. (2011) Crosslinking as an Efficient Tool for Decreasing Moisture Sensitivity of Biobased Nanocomposite Films. Materials Sciences and Applications, 2, 346-354.
http://dx.doi.org/10.4236/msa.2011.25045
[18] Vartiainen, J., Tuominen, M. and Nattinen, K. (2010) Bio-Hybrid Nanocomposite Coatings from Sonicated Chitosan and Nanoclay. Journal of Applied Polymer Science, 116, 3638-3647.
[19] Vartiainen, J., Motion, R., Kulonen, H., Ratto, M., Skytta, E. and Ahvenainen, R. (2004) Chitosan-Coated Paper: Effects of Nisin and Different Acids on the Antimicrobial Activity. Journal of Applied Polymer Science, 94, 986-993.
http://dx.doi.org/10.1002/app.20701
[20] Vartiainen, J., Ratto, M., Tapper, U., Paulussen, S. and Hurme, E. (2005) Surface Modification of Atmospheric Plasma Activated BOPP by Immobilizing Chitosan. Polymer Bulletin, 54, 343-352.
[21] Vartiainen, J., Ratto, M., Lantto, R., Nattinen, K. and Hurme, E. (2008) Tyrosinase-Catalysed Grafting of Food-Grade Gallates to Chitosan: Surface Properties of Novel Functional Coatings. Packaging Technology and Science, 21, 317328.
http://dx.doi.org/10.1002/pts.813
[22] Hartman, J., Setala, H., Laine, C., Anghelescu-Hakala, A., Matilainen, K., Hohenthal, C., Harkonen, M. and Harlin, A. (2013) Biobarrier Coatings for Fibre-Based Packaging. Proceedings of the 26th IAPRI Symposium of Packaging, Espoo, 10-13 June 2013, 210-219.
[23] Laine, C., Harlin, A., Hartman, J., Hyvarinen, S., Kammiovirta, K., Krogerus, B., Pajari, H., Rautkoski, H., Setala, H., Sievanen, J., Uotila, J. and Vaha-Nissi, M. (2013) Hydroxyalkylated Xylans: Their Synthesis and Application in Coatings for Packaging and Paper. Industrial Crops and Products, 44, 692-704.
http://dx.doi.org/10.1016/j.indcrop.2012.08.033
[24] Mikkonen, K., Laine, C., Kontro, I., Talja, R., Serimaa, R. and Tenkanen, M. (2014) Combination of Internal and External Plasticization of Hydroxypropylated Birch Xylan Tailors the Properties of Sustainable Barrier Films. Submitted to Green Chemistry.
[25] Talja, R., Kulomaa, T., Labafzadeh, S., Kyllonen, L., King, A., Kilpelainen, I. and Poppius-Levlin, K. (2011) Cellulose Esters from Birch Kraft Pulps: New Biomaterials for Barrier Coating. 16th International Symposium on Wood, Fiber and Pulping Chemistry (16th ISWFPC), Vol. 2, Tianjin, 8-10 June 2011, 1394-1398.
[26] Labafzadeh, S., Kulomaa, T., Talja, R., Kyllonen, L., King, A., Poppius-Levlin, K. and Kilpelainen, I. (2011) Fatty Acid Derivatives of Cellulose for Barrier Applications. Stockholm, Sweden: Innventia Ab. The 3rd Nordic Wood Biorefinery Conference, NWBC 2011, Stockholm, 22-24 March 2011, 250-252.
[27] Talja, R., Shan, J., Vaha-Nissi, M., King, A., Kilpelainen, I. and Poppius-Levlin, K. (2010) A New Birch Xylan Derivative by Aqueous Benzylation. 11th European Workshop on Lignocellulosics and Pulp (EWLP), Hamburg, 16-18 August 2010, 403-406.
[28] Vuoti, S., Laatikainen, E., Heikkinen, H., Johansson, L.S., Saharinen, E. and Retulainen, E. (2013) Chemical Modification of Cellulosic Fibers for Better Convertibility in Packaging Applications. Carbohydrate Polymers, 96, 549-559.
http://dx.doi.org/10.1016/j.carbpol.2012.07.053
[29] Talja, R., Clegg, F., Breen, C. and Poppius-Levlin, K. (2011) Nano Clay Reinforced Xylan Barriers. Stockholm, Sweden: Innventia Ab. The 3rd Nordic Wood Biorefinery Conference, NWBC 2011, Stockholm, 22-24 March 2011, 132137.
[30] Hartman, J., Albertsson, A.C., Soderqvist Lindblad, M. and Sjoberg, J. (2006) Oxygen Barrier Materials from Renewable Sources: Material Properties of Softwood Hemicellulose-Based Films. Journal of Applied Polymer Science, 100, 2985-2991.
http://dx.doi.org/10.1002/app.22958
[31] Hult, E.L., Ropponen, J., Poppius-Levlin, K., Ohra-Aho, T. and Tamminen, T. (2013) Enhancing the Barrier Properties of Paper Board by a Novel Lignin Coating. Industrial Crops and Products, 50, 694-700.
http://dx.doi.org/10.1016/j.indcrop.2013.08.013
[32] Hult, E.L., Koivu, K., Asikkala, J., Ropponen, J., Wrigstedt, P., Sipila, J. and Poppius-Levlin, K. (2013) Esterified Lignin Coating as Water Vapour and Oxygen Barrier for Fiber-Based Packaging. Holzforschung, 67, 899-905.
[33] Vartiainen, J. and Vikman, M. (2013) Health and Environmental Safety Aspects of CNF. Production and Applications of Cellulose Nanomaterials, Book Chapter. TAPPI, 57-58.
[34] Vartiainen, J., Pohler, T., Sirola, K., Pylkkanen, L., Alenius, H., Hokkinen, J., Tapper, U., Lahtinen, P., Kapanen, A., Putkisto, K., Hiekkataipale, P., Eronen, P., Ruokolainen, J. and Laukkanen, A. (2011) Health and Environmental Safety Aspects of Friction Grinding and Spray Drying of Microfibrillated Cellulose. Cellulose, 18, 775-786.
http://dx.doi.org/10.1007/s10570-011-9501-7
[35] Vartiainen, J., Lahtinen, P., Kaljunen, T., Kunnari, V., Peresin, M.S. and Tammelin, T. (2014) Comparison of Properties between Cellulose Nanofibrils Made from Banana, Sugar Beet, Hemp, Softwood and Hardwood Pulps. 47th Pulp and Paper International Congress, Sao Paulo, 7-9 October 2014, 10.
[36] Spoljaric, S., Salminen, A., Luong, N., Lahtinen, P., Vartiainen, J., Tammelin, T. and Seppala, J. (2013) Nanofibrillated Cellulose, Poly(Vinyl Alcohol), Montmorillonite Clay Hybrid Nanocomposites with Superior Barrier and Thermomechanical Properties. Polymer Composites, 35, 1117-1131.
[37] Vartiainen, J., Kaljunen, T., Kunnari, V., Lahtinen, P. and Tammelin, T. (2013) Large-Scale Production of CNF Films. Production and Applications of Cellulose Nanomaterials, Book Chapter. TAPPI, 239-240.
[38] Lahtinen, K., Nattinen, K. and Vartiainen, J. (2009) Influence of High-Temperature Heat Treatment on Barrier and Functional Properties of Polyolefin-Coated Papers. Polymer-Plastics Technology and Engineering, 48, 561-569.
http://dx.doi.org/10.1080/03602550902824382
[39] Vartiainen, J., Kaljunen, T., Kunnari, V., Lahtinen, P., Salminen, A., Seppala, J. and Tammelin, T. (2013) Nanocellulose Films: Towards Large Scale and Continuous Production. 26th IAPRI Symposium on Packaging, VTT, IAPRI, Espoo, 10-13 June 2013, 197-209.
[40] Juvonen, H., Smolander, M., Boer, H., Pere, J., Buchert, J. and Peltonen, J. (2011) Film Formation and Surface Properties of Enzymatically Crosslinked Casein Films. Journal of Applied Polymer Science, 119, 2205-2213.
http://dx.doi.org/10.1002/app.32943
[41] Ramo, V., Anghelescu-Hakala, A., Nurmi, L., Mehtio, T., Salomaki, E., Harkonen, M. and Harlin, A. (2012) Preparation of Aqueous Crosslinked Dispersions of Functionalized Poly(d,l-Lactic Acid) with a Thermomechanical Method. European Polymer Journal, 48, 1495-1503.
http://dx.doi.org/10.1016/j.eurpolymj.2012.06.005
[42] Hartman, J., Albertsson, A.C. and Sjoberg, J. (2006) Surfaceand Bulk-Modified Galactoglucomannan Hemicellulose Films and Film Laminates for Versatile Oxygen Barriers. Biomacromolecules, 7, 1983-1989.
http://dx.doi.org/10.1021/bm060129m
[43] Saarikoski, E., Rautkoski, H., Rissanen, M., Hartman, J. and Seppala, J. (2014) Cellulose/Acrylic Acid Copolymer Blends for Films and Coating Applications. Journal of Applied Polymer Science, 131, 40286-40295.
http://dx.doi.org/10.1002/app.40286
[44] Saastamoinen, P., Mattinen, M., Hippi, U., Nousiainen, P., Sipila, J., Lille, M., Suurnakki, A. and Pere, J. (2012) Laccase Aided Modification of Nanofibrillated Cellulose with Dodecyl Gallate. BioResources, 7, 5749-5770.
[45] Osterberg, M., Vartiainen, J., Lucenius, J., Hippi, U., Seppala, J., Serimaa, R. and Laine, J. (2013) A Fast Method to Produce Strong NFC Films as a Platform for Barrier and Functional Materials. American Chemical Society, ACS Applied Materials and Interfaces, 5, 4640-4647.
http://dx.doi.org/10.1021/am401046x
[46] Hult, E.L., Iotti, M. and Lenes, M. (2010) Efficient Approach to High Barrier Packaging Using Microfibrillar Cellulose and Shellac. Cellulose, Springer, 17, 575-586.
http://dx.doi.org/10.1007/s10570-010-9408-8
[47] Peresin, M.S., Vartiainen, J., Kunnari, V., Kaljunen, T., Tammelin, T. and Qvintus, P. (2012) Large-Scale Nanofibrillated Cellulose Film: An Overview on Its Production, Properties, and Potential Applications. 4th International Conference of Pulping, Papermaking and Biotechnology, ICPPB 2012, Nanjing, 7-9 November 2012, Book of Abstracts.
[48] Virtanen, S., Vartiainen, J., Setala, H., Tammelin, T. and Vuoti, S. (2014) Modified Nanofibrillated Cellulose-Polyvinyl Alcohol Films with Improved Mechanical Performance. The Royal Society of Chemistry, RSC Advances, 4, 11343-11350.
http://dx.doi.org/10.1039/c3ra46287k
[49] Lozhechnikova, A., Dax, D., Vartiainen, J., Willfor, S., Xu, C. and Osterberg, M. (2014) Modification of Nanofibrillated Cellulose Using Amphiphilic Block-Structured Galactoglucomannans. Carbohydrate Polymers, 110, 163-172.
http://dx.doi.org/10.1016/j.carbpol.2014.03.087
[50] Wang, S., Mahlberg, R., Nikkola, J., Mannila, J., Jamsa, S., Ritschkoff, A. and Peltonen, J. (2012) Surface Characteristics and Wetting Properties of Sol-Gel Coated Base Paper. Surface and Interface Analysis, 44, 539-547.
http://dx.doi.org/10.1002/sia.3841
[51] Nikkola, J., Vartiainen, J., Vaha-Nissi, M. and Nattinen, K. (2013) Novel Packaging Materials Using Functional Thin Films and Coatings. European Coatings Conference-Packaging and Can Coatings, Düsseldorf, 11-12 June 2013, Vincentz Network GmbH & Co.
[52] Nikkola, J. (2011) Raising the Barriers. European Coatings Journal, 41-47.
[53] Nattinen, K., Nikkola, J., Minkkinen, H., Heikkila, P., Lavonen, J. and Tuominen, M. (2011) Reel-to-Reel Inline Atmospheric Plasma Deposition of Hydrophobic Coatings. Journal of Coatings Technology and Research, 8, 237-245.
http://dx.doi.org/10.1007/s11998-010-9292-z
[54] Vaha-Nissi, M., Sundberg, P., Kauppi, E., Hirvikorpi, T., Sievanen, J., Sood, A., Karppinen, M. and Harlin, A. (2012) Barrier Properties of Al2O3 and Alucone Coatings and Nanolaminates on Flexible Biopolymer Films. Thin Solid Films, 520, 6780-6785.
http://dx.doi.org/10.1016/j.tsf.2012.07.025
[55] Hirvikorpi, T., Vaha-Nissi, M., Mustonen, T., Iiskola, E. and Karppinen, M. (2010) Atomic Layer Deposited Aluminum Oxide Barrier Coatings for Packaging Materials. Thin Solid Films, 518, 2654-2658.
http://dx.doi.org/10.1016/j.tsf.2009.08.025
[56] Hirvikorpi, T., Vaha-Nissi, M., Nikkola, J., Harlin, A. and Karppinen, M. (2011) Thin Al2O3 Barrier Coatings onto Temperature-Sensitive Packaging Materials by Atomic Layer Deposition. Surface and Coatings Technology, 205, 5088-5092.
http://dx.doi.org/10.1016/j.surfcoat.2011.05.017
[57] Hirvikorpi, T., Vaha-Nissi, M., Harlin, A., Marles, J., Miikkulainen, V. and Karppinen, M. (2010) Effect of Corona Pre-Treatment on the Performance of Gas Barrier Layers Applied by Atomic Layer Deposition onto Polymer Coated Paperboard. Applied Surface Science, 257, 736-740.
http://dx.doi.org/10.1016/j.apsusc.2010.07.051
[58] Vaha-Nissi, M., Pitkanen, M., Salo, E., Kentta, E., Tanskanen, A., Sajavaara, T., Putkonen, M., Sievanen, J., Sneck, A., Ratto, M., Karppinen, M. and Harlin, A. (2014) Antibacterial and Barrier Properties of Oriented Polymer Films with ZnO Thin Films Applied with Atomic Layer Deposition at Low Temperatures. Thin Solid Films, 562, 331-337.
[59] Hirvikorpi, T., Vaha-Nissi, M., Harlin, A., Salomaki, M., Areva, S., Korhonen, J. and Karppinen, M. (2011) Enhanced Water Vapour Barrier Properties for Biopolymer Films by Polyelectrolyte Multilayer and Atomic Layer Deposited Al2O3 Double-Coating. Applied Surface Science, 257, 9451-9454.
[60] Hirvikorpi, T., Vaha-Nissi, M., Harlin, A. and Karppinen, M. (2010) Comparison of Some Coating Techniques to Fabricate Barrier Layers on Packaging Materials. Thin Solid Films, 518, 5463-5466.
http://dx.doi.org/10.1016/j.tsf.2010.04.018
[61] Hirvikorpi, T., Laine, R., Vaha-Nissi, M., Kilpi, V., Salo, E., Lia, W.M., Lindfors, S., Vartiainen, J., Kentta, E., Nikkola, J., Harlin, A. and Kostamo, J. (2013) Barrier Properties of Plastic Films Coated with an Al2O3 Layer by Roll-toRoll Atomic Layer Deposition. Thin Solid Films, 550, 164-169.
[62] Hohenthal, C. and Veuro, S. (2011) The Role of LCA in Guiding Projects. FlexPakRenew Workshop, Lyon, 10 May 2011.
[63] Hult Mori, E.L. (2012) Bio-Based Adhesives Packaging. In: Sundqvist, H., Ed., Research Highlights in Industrial Biomaterials, VTT Research Highlights, VTT, Espoo, No. 2, 79-81.
[64] Vartiainen, J., Kaljunen, T., Nykanen, H., Malm, T. and Tammelin, T. (2014) Improving Multilayer Packaging Performance with Nanocellulose Barrier Layer. TAPPI Place Conference 2014, Ponte Vedra, 13-15 May 2014, 5.

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