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Synthesis, Thermal Behaviour, XRD, and Luminescent Properties of Lighter Lanthanidethiodipropionate Hydrates Containing Aminogunidine as Neutral Ligand

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DOI: 10.4236/ojic.2014.43006    4,363 Downloads   5,073 Views   Citations

ABSTRACT

Aminoguanidine lanthanide thiodipropionate hydrates of composition [Ln(Agun)2(tdp)3·nH2O], Agun = Aminoguanidine, tdp = thiodipropionic acid, where Ln = La, Pr, Nd and Sm if n = 2, have been prepared and characterized by physic-chemical techniques.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Packiaraj, S. and Govindarajan, S. (2014) Synthesis, Thermal Behaviour, XRD, and Luminescent Properties of Lighter Lanthanidethiodipropionate Hydrates Containing Aminogunidine as Neutral Ligand. Open Journal of Inorganic Chemistry, 4, 41-49. doi: 10.4236/ojic.2014.43006.

References

[1] Wang, Y.-L., Yuan, D.-Q., Bi, W.-H., Li, X., Li, X.-J., Li, F. and Cao, R. (2005) Syntheses and Characterizations of Two 3D Cobalt-Organic Frameworks from 2D Honeycomb Building Blocks. Crystal Growth Design, 5, 1849-1885.
http://dx.doi.org/10.1021/cg0501128
[2] Zhu, X.D., Lu, J., Li, X.J., Gao, S.Y., Li, G.L. and Cao, R. (2008) Syntheses, Structures, Near-Infrared, and Visible Luminescence of Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands. Crystal Growth Design, 8, 1897-1901. http://dx.doi.org/10.1021/cg701098t
[3] Yuan, F.G., Liu, X.J. and Zhang, Y. (2005) Reaction of (Ph2N)2Sm(THF)4 with Azobenzene: Synthesis, X-Ray Structure and Catalytic Behavior of [(Ph2N)(DME)Sm]2(μ-η2:η2-N2Ph2)2. Chinese Journal of Chemistry, 23, 749-752.
http://dx.doi.org/10.1002/cjoc.200590749
[4] Boldyrev, V.V., Tukhtaev, R.K., Gavrilov, A.I., Larionov, S.V., Savel'eva, Z.A. and Lavrenova, L.G. (1998) Combustion of Nickel and Copper Nitrate Complexes of Hydrazine Derivatives as a Method for Manufacturing Fine-Grained and Porous Metals. Russian Journal of Inorganic Chemistry, 43, 302-305.
[5] Zubkov, S.V. and Shafranskii, I.I. (1979) Russian Journal of General Chemistry, 49, 428.
[6] Aitken, D.J., Albinati, A., Husson, H.-P., Morgant, G., Nguyen-Huy, D., Kozelka, J., Lemoine, P., Ongeri, S., Rizzato, S. and Viossat, B. (2007) Platinum(II) and Palladium(II) Complexes with N-Aminoguanidine. European Journal of Inorganic Chemistry, 21, 3327-3334. http://dx.doi.org/10.1002/ejic.200600998
[7] Chandra, S. and Sharma, A.K. (2009) Antifungal and Spectral Studies of Cr(III) and Mn(II) Complexes Derived from 3, 3’-Thiodipropionic Acid Derivative. Research Letters in Inorganic Chemistry, 2009, Article ID: 945670.
http://dx.doi.org/10.1155/2009/945670
[8] Premkumar, T. and Govindarajan, S. (2002) The Chemistry of Hydrazine Derivatives—Thermal Behavior and Characterisation of Hydrazinium Salts and Metal Hydrazine Complexes of 4,5-Imidazoledicarboxylic Acid. Thermochimica Acta, 386, 35-42. http://dx.doi.org/10.1016/S0040-6031(01)00756-0
[9] Roux, J.A. and Wood, B.E. (1983) Infrared Optical Properties of Solid Monomethyl Hydrazine, N2O4, and N2H4 at Cryogenic Temperatures. Optical Society of America, 73, 1181-1188.
http://dx.doi.org/10.1364/JOSA.73.001181
[10] Brzyska, W. and Ozga, W. (1996) Preparation and Properties of Y(III) and Lanthanide(III) Complexes with Pyridine- 2,4-dicarboxylic Acid. Thermochimica Acta, 273, 205-216. http://dx.doi.org/10.1016/0040-6031(95)02393-3
[11] Karraker, D.G. (1968) Hypersensitive Transitions of Hydrated Neodymium-(III)holmium-(III) and Erbium-(III) Ions. Inorganic Chemistry, 7, 473-479. http://dx.doi.org/10.1021/ic50061a018
[12] Peacock, R.D. (1975) The Intensities of Lanthanide f—f Transitions. Structure and Bonding, 22, 83-122.
http://dx.doi.org/10.1007/BFb0116556
[13] Sinha, S.P. (1965) 2,2’-Dipyridyl Complexes of Rare Earths—II: Reflection Spectra of Nd(III)-bis-(2,2’-dipyridyl) and Nd(III)-bis-(4,4’-dimethyl-2,2’-dipyridyl) Chlorides. Journal of Inorganic and Nuclear Chemistry, 27, 115-118.
http://dx.doi.org/10.1016/0022-1902(65)80199-3
[14] Henrie, D.E. and Choppin, G.R. (1968) Environmental Effects on f-f Transitions. II. “Hypersensitivity” in Some Complexes of Trivalent Neodymium. The Journal of Chemical Physics, 49, 477.
http://dx.doi.org/10.1063/1.1670099
[15] Premkumar, T. and Govindarajan, S. (2003) Synthesis and Spectroscopic, Thermal, and XRD Studies on Trivalent Lighter Rare-Earth Complexes of 2,3-Pyrazinedicorboxylate with Hydrazinium Cation. Inorganic Chemistry Communications, 6, 1385-1389. http://dx.doi.org/10.1016/j.inoche.2003.08.025
[16] Kuppusamy, K. and Govindarajan, S. (1996) New Trivalent Lanthanide Complexes of Phthalate-Containing Hydrazinium Cationc Preparation, and Spectral and Thermal Studies. Thermochimica Acta, 279, 143-165.
http://dx.doi.org/10.1016/0040-6031(96)90076-3
[17] DcBettencourt, D.A. and Viswanath, S. (2004) Chemical Communications, 1024.
[18] Zhan II, X., Xiao, Z.L. and Zhan, H.H. (2008) Rare Earths, 26, 390.
[19] Zang, Z.H., Okamura, T., Hasegawa, Y., et al. (2005) Syntheses, Structures, and Luminescent and Magnetic Properties of Novel Three-Dimensional Lanthanide Complexes with 1,3,5-Benzenetriacetate. Inorganic Chemistry, 44, 6219-6227. http://dx.doi.org/10.1021/ic050453a
[20] Allan, J.R., Paton, A.D., Turvey, K., Bowley, H.J. and Gerrard, D.L. (1987) Spectral, Magnetic and Electrical Studies on Complexes of Some First Row Transition Elements with Pyrazinecarboxylic Acid. Inorganica Chimica Acta, 132, 41-47. http://dx.doi.org/10.1016/S0020-1693(00)83988-2

  
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