Chromium Electroplating of Aluminium Alloys Using Electroless Nickel as Underlayer

Abstract

The growing demand for chromium coated aluminium components especially for the automotive industry is due to their favourable physical properties (density, strength to weight ratio etc.). However, their frequent use under harsh environmental conditions renders them corrosion sensitive and consequently they need to be protected. An approach that has been applied in industry is to directly electroplate nickel onto aluminium substrate prior to a top metallic finish; however, in components with complex geometry, certain areas could become exposed to corrosion attack due to poor surface coverage during plating. In this study, a modified electroless nickel undercoat was applied to pre-treated aluminium alloys prior to duplex nickel and chromium plating with a view to enhance corrosion resistance, improve coating adherence and durability, and overall, to achieve substrate protection. Hexavalent and trivalent chromium were applied to pre-treated Al 1050 and Al 6061 following electroless nickel deposition, and plating performance was assessed by surface and corrosion techniques, while durability was measured by scratch, adhesion and hardness tests. Overall, while chromium plating with an electroless nickel undercoat did not improve corrosion resistance or hardness of the materials, it provided an additional protective layer for the substrate with a potential for longer term durability.

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Oduoza, C. , Khan, E. and Sihra, T. (2014) Chromium Electroplating of Aluminium Alloys Using Electroless Nickel as Underlayer. Journal of Materials Science and Chemical Engineering, 2, 59-74. doi: 10.4236/msce.2014.27007.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Funatani, K. (2000) Emerging Technology in Modification of Light Metals. Journal of Surface and Coating Technology, 133-144, 264-272
[2] Carle, D. and Blount, G. (1999) The Suitability of Aluminium as an Alternative Material for Car Bodies. Journal of Materials and Design, 20, 267-272. http://dx.doi.org/10.1016/S0261-3069(99)00003-5
[3] Wernick, S., Pinner, R. and Sheasby, P.G. (1987) The Surface Treatment and Finishing of Aluminium and Its Alloys. 5th Edition, Vol. 1-2, Finishing Publications Limited, Teddington, 1-1083.
[4] Khan, M.E., Farr, J.P.G., Pearson, T. and Oduoza, C.F. (2004) Pretreatment of Aluminium Alloys for Sustainable Electroplating—A Preliminary Study. European Symposium on Electrochemical Engineering, Toulouse, 3-5 October 2005, 505-510.
[5] Dennis, J. K. and Such, T.E. (1993) 3rd Edition, Woodhead Publishing Limited, Cambridge, 206-344.
[6] Takacs, D., ziraki, L.S., Torok, T.I., Solyom, J., Gacsi, Z. and Gal-Solymos, K. (2007) Effects of Pre-Treatments on the Corrosion Properties of Electroless Ni-P Layers Deposited on AlMg2 Alloy, Surface &Coatings Technology, 201, 4526-4535.
http://dx.doi.org/10.1016/j.surfcoat.2006.09.045
[7] Hino, M., Murakami, K., Mitooka, Y., Muraoka, K. and Kamdani, T. (2009) The Effects of Zincate Treatment on Adhesion of Electroless Ni-P Coating onto Various Aluminium Alloys. Transactions of Nonferrous Metals Society of China, 19, 814-818. http://dx.doi.org/10.1016/S1003-6326(08)60356-8
[8] Voorwald, H.J.C., Padilha, R., Costa, M.Y.P., Pigatin, W.L. and Cioffi, M.O.H. (2007) Effect of Electroless Nickel Interlayer on the Fatigue Strength of Chromium Electroplated AISI 4340 Steel. International Journal of Fatigue, 29, 695-704.
http://dx.doi.org/10.1016/j.ijfatigue.2006.07.004
[9] Abdel Hamid, Z. and Abou Elkhair, M.T. (2002) Development of Electroless Nickel-Phosphorus Composite Deposits for Wear Resistance of 6061 Aluminium Alloy. Material Letters, 57, 720-726.
http://dx.doi.org/10.1016/S0167-577X(02)00860-1
[10] Wu, L.-P., Zhao, J.-J., Xie, Y.-P. and Yang, Z.D. (2010) Progress of Electroplating and Electroless Plating on Magnesium Alloy. Transactions of Nonferrous Metals Society of China, 20, 630-637.
http://dx.doi.org/10.1016/S1003-6326(10)60552-3
[11] Khan, M.E., Oduoza, C.F. and Laoui, T. (2005) Conference Electrochem. Newcastle-Upon-Tyne, UK.
[12] Baral, A. and Engelken, R.D. (2002) Chromium-Based Regulations and Greening in Metal Finishing Industries in the USA. Environmetal Science Policy, 5, 121-133.
[13] Khan, M.E. (2009) Investigation of Electroless Nickel Undercoat for Duplex Nickel Chromium Electrodeposition onto Aluminium Alloys. MPhil Thesis, University of Wolverhampton, Wolverhampton.
[14] Aluminium Federation (2003) Birmingham, UK.
[15] MacDermid plc (2000) Bondal Process Technical Data Sheet, Birmingham, UK.
[16] MacDermid plc (2000) Minco Cleaner, Technical Data Sheet, Birmingham, UK.
[17] MacDermid plc (2000) 66-Microetch, Technical Data Sheet, Birmingham, UK.
[18] MacDermid plc (2000) VAND ALOY 6000, Technical Data Sheet, Birmingham, UK.
[19] MacDermid plc (2000) NiMac Technical Data Sheet, Birmingham, UK.
[20] MacDermid plc (2000) NiMac Clarion II Technical Data Sheet, Birmingham, UK.
[21] MacDermid plc (2000) NiMac Hypore XL Technical Data Sheet, Birmingham, UK.
[22] MacDermid plc (2000) Mach 2 Technical Data Sheet, Birmingham, UK.
[23] MacDermid plc (2000) Tri Mac HI Technical Data Sheet, Birmingham, UK.
[24] Meade, L.C. (2000) Accelerated Corrosion Testing. Journal of Metal Finishing, 98, 542-545.
[25] Lewis, D.B. (1992) Scanning Electron Microscopy and X-Ray Microanalysis. Transactions of Institute of Metal Finishing, 70, 198.
[26] Smith, J., Campbell, S. and Walsh, F.C. (1998) The Use of Scanning Probe Microscopy in Surface Finishing and Engineering. Transactions of the Institute of Metal Finishing, 76, B53-B61.
[27] Smith, J., Campbell, S. and Breakspear, S. (2003) Introduce AFM for Surface Finishing, Part I and II. Transactions of the Institute of Metal Finishing, 81, 35-40, 35-38.
[28] Tait, W.S. (1994) An Introduction to Electrochemical Corrosion Testing for Practising Engineers and Scientists. Chapter IV, Pair O Docs Professionals L.L.C., Madison, 43-51.
[29] Mansfeld, F. (2003) Electrochemical Methods of Corrosion Testing. ASM Handbook, Volume 13A, Corrosion: Fundamentals, Testing and Protection, Association of Corrosion Engineers, 446-462.
[30] Stallard, J., Teer, D.G. and Poulat, S. (2006) The Study of Adhesion of TiN Coating on Steel and Titanium Alloy Substrate Using a Multi Mode Scratch Tester. Tribology International, 39, 159-166.
http://dx.doi.org/10.1016/j.triboint.2005.04.011
[31] Snyder, D.L. (2000) Decorative Chromium Plating. Metal Finishing, 98, 215-222.
http://dx.doi.org/10.1016/S0026-0576(00)80328-1
[32] Bull, S.J. and Berasetgu, E.G. (2006) An Overview of the Potential of Quantitative Coating Adhesion Measurement by Scratch Testing. Tribology International, 39, 99-114.
http://dx.doi.org/10.1016/j.triboint.2005.04.013
[33] Chandler, H. (1999) Hardness Testing. 2nd Edition, the American Society of Testing and Materials, West Conshohocken, 1999.
[34] Dyrda, K. and Sayer, M. (1999) Critical Loads and Effective Frictional Force Measurements in the Industrial Scratch Testing of TiN on M2 Tool Steels. Thin Solid Films, 355-356, 277-283.
http://dx.doi.org/10.1016/S0040-6090(99)00450-2

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