Effect of Preparation Method on Catalytic Properties of Double Perovskite Oxides LaSrFeMo0.9Co0.1O6 for Methane Combustion


The double perovskite oxides LaSrFeMo0.9Co0.1O6 was prepared by co-precipitation method and sol-gel method. The title catalysts were calcined at 800°C and characterized by XRD H2-TPR, SEM and TG-DTA techniques. The catalytic activity was evaluated for methane combustion. The specific surface area of them was calculated by BET model. The samples exhibit significant catalytic activity for methane combustion at 800°C. Upon calcination at 800°C, the LaSrFeMo0.9Co0.1O6 prepared by sol-gel method retains a specific surface area of 24 m2.g-1 and shows an excellent activity for methane combustion (the conversion of 10% and 90% are obtained at 505°C and 660°C, respectively).

Share and Cite:

Zheng, J. , Lang, X. and Wang, C. (2014) Effect of Preparation Method on Catalytic Properties of Double Perovskite Oxides LaSrFeMo0.9Co0.1O6 for Methane Combustion. Advances in Chemical Engineering and Science, 4, 367-373. doi: 10.4236/aces.2014.43040.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] Yan, X. and Crookes, R.J. (2010) Progress in Energy and Combustion Science. Progress in Energy and Combustion Science, 36, 651-676. http://dx.doi.org/10.1016/j.pecs.2010.02.003
[2] Gao, Z. and Wang, R. (2010) Catalytic Activity for Methane Combustion of the Perovskite-Type La1-xSrxCoO3 Oxide Prepared by the Urea Decomposition Method. Applied Catalysis B, 98, 147-153. http://dx.doi.org/10.1016/j.apcatb.2010.05.023
[3] Choudhary, T.V., Banerjee, S. and Choudhary, V.R. (2010) Catalysts for Combustion of Methane and Lower Alkanes. Applied Catalysis A, 234, 1-23. http://dx.doi.org/10.1016/S0926-860X(02)00231-4
[4] Fabbrini, L. and Rossetti, I. (2003) Effect of Primer on Honeycomb-Supported La0.9Ce0.1CoO3 Perovskite for Methane Catalytic Flameless Combustion. Applied Catalysis A, 44, 107-116.
[5] Li, C., Wang, W. and Zhao, N. (2011) Structure Properties and Catalytic Performance in Methane Combustion of Double Perovskites Sr2Mg1-xMnxMoO6. Applied Catalysis B, 102, 78-84.
[6] Li, C. and Wang, W. (2011) Double Perovskite Oxides Sr2Mg1-xFexMoO6 for Catalytic Oxidation of Methane. Journal of Natural Gas Chemistry, 20, 345-349.
[7] Li, S. and Wang, X. (2006) Catalytic Combustion of Methane over Mn-Substituted Ba-La-Hexaaluminate Nanoparticles. Journal of Alloys and Compounds, 432, 333-337.
[8] Todd, H., Gardner, J.J. and Spivey, A.C. (2013) CH4-CO2 Reforming over Ni-Substituted Barium Hexaaluminate Catalysts. Applied Catalysis B, 157, 129-136.
[9] Hu, R.S., Ding, R.R., Chen, J., Hu, J.N. and Zhang, Y.L. (2012) Preparation and Catalytic Activities of the Novel Double Perovskite-Type Oxide La2CuNiO6 for Methane Combustion. Catalysis Communications, 21, 38-41. http://dx.doi.org/10.1016/j.catcom.2012.01.008
[10] Ren, X., Zheng, J. and Song, Y. (2008) Catalytic Properties of Fe and Mn Modified Lanthanum Hexaaluminates for Catalytic Combustion of Methane. Catalysis Communications, 9, 807-810.
[11] Machej, T. and Serwicka, E.M. (2014) Cu/Mn-Based Mixed Oxides Derived from Hydrotalcite-Like Precursors as Catalysts for Methane Combustion. Applied Catalysis A: General, 47, 487-494.
[12] Xiong, Y. and Liang, H. (2009) Partial Oxidation of Methane to Syngas over the Catalyst Derived from Double Perovskite (La0.5Sr0.5)2FeNiO6. Applied Catalysis A: General, 371, 153-160.
[13] Baylet, A., Royer, S. and Mare, P. (2008) Effect of Pd Precursor Salt on the Activity and Stability of Pd-Doped Hexaaluminate Catalysts for the CH4 Catalytic Combustion. Applied Catalysis B: Environmental, 81, 88-96.
[14] Zhang, K., Zhou, G.D. and Li, J. (2009) Effective Additives of A (Ce, Pr) in Modified Hexaaluminate LaxA1-xNiAl11O19 for Carbon Dioxide Reforming of Methane. Catalysis Letters, 130, 246-253. http://dx.doi.org/10.1007/s10562-009-9876-3
[15] Wang, Y., Ouyang, J.H. and Liu, Z. (2010) Influence of Dysprosium Oxide Doping on Thermo Physical Properties of LaMgAl11O19 Ceramics. Materials and Design, 31, 3353-3357.
[16] Falcon, H. and Barbero, J. (2004) Double Perovskite Oxides A2FeMoO6 (A = Ca, Sr and Ba) as Catalysts for Methane Combustion. Applied Catalysis B, 53, 37-45.
[17] Zheng, J.D. and Ren, X.G. (2008) Catalytic Properties of a (A = Ba, Ca, Sr, and Y) Modified Lanthanum Hexaaluminates for Catalytic Combustion of Methane. Reaction Kinetics and Catalysis Letters, 93, 3-9. http://dx.doi.org/10.1007/s11144-007-5165-6

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.