Sodium Titanates Formation by Roasting of Pellets or Powder Mixture of Soda Ash and Rossetta Region Ilmenite Ore Concentrate in Air

DOI: 10.4236/ojmetal.2014.42003   PDF   HTML     4,495 Downloads   5,756 Views  


Alkaline metals and hydrogen titanates are of great interest for possible applications. The qualities of soda ash and Rosetta ilmenite ore concentrate pellets were investigated. The kinetic formation of sodium titanate via roasting of soda ash and ilmenite pellets and powder was studied in the temperature range of 800C to 900C.

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Nafeaa, I. , Zekry, A. , Khalifa, M. , Farag, A. , El-Hussiny, N. , El Hossiny, K. and Shalabi, M. (2014) Sodium Titanates Formation by Roasting of Pellets or Powder Mixture of Soda Ash and Rossetta Region Ilmenite Ore Concentrate in Air. Open Journal of Metal, 4, 20-30. doi: 10.4236/ojmetal.2014.42003.

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The authors declare no conflicts of interest.


[1] Doan, P. (2003) Sustainable Development in the TiO2 Industry: Challenges and Opportunities. The TiO2 Intertech Conference, Miami, 3-5 February 2003.
[2] Tathavadkar, V. and Jha, A. (2004) The Effect of Molten Sodium Titanate and Carbonate Salt Mixture on the Alkali Roasting of Ilmenite and Rutile Minerals. VII International Conference on Molten Slags Fluxes and Salts, Cape Town, 25-28 January 2004, 255-261.
[3] El-Tawil, S.Z., Morsi, I.M., Yehia, A. and Francis, A.A. (1996) Alkali Reductive Roasting of Ilmenite Ore. Canadian Metallurgical Quarterly, 35, 31-37.
[4] Hobbs, D.T. (2011) Properties and Uses of Sodium Titanates and Peroxotitanates. Journal of the South Carolina Academy of Science, 9, 20-24.
[5] Lynch, R., Dosch, R., Kenna, B., Johnstone, J. and Nowak, E. (1976) The Sandia Solidification Process: A Broad Range Aqueous Solidification Method. Symposium on the Management of Radioactive Waste, Vienna, 22-26 March 1976, 360-372.
[6] Clearfield, A. and Lehto, J. (1988) Preparation, Structure, and Ion-Exchange Properties of Na4Ti9O20XH2O. Journal of Solid State Chemistry, 73, 98-106.
[7] Nyman, M.D. and Hobbs, D.T. (2006) A Family of Peroxo-Titanate Materials Tailored for Optimal Strontium and Actinide Sorption. Chemistry of Materials, 18, 6425-6435.
[8] Nyman, M.D. and Hobbs, D.T. (2009) Hydrogen Peroxide Modified Sodium Titanates with Improved Sorption Capabilities. US Patent 7494640B1.
[9] Elvington, M.C., Click, D.R. and Hobbs, D.T. (2010) Improved Strontium and Actinide Separations. Separation Science and Technology, 45, 66-72.
[10] Hobbs, D.T., Clearfield, A. and Burns, J. (2010) Presentation at the 34th Actinide Separations Conference, Argonne, 18 May 2010.
[11] Hobbs, D.T., Messer, R.L.W., Lewis, J.B., Click, D.R., Lockwood, P.E. and Wataha, J.C. (2006) Adsorption of Biometals to Monosodium Titanate in Biological Environments. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 78B, 296-301.
[12] Davis, R.R., Hobbs, D.T., Lockwood, P.E., Messer, R.L.W., Prices, R., Lewis, J. B. and Wataha, J.C. (2007) In Vitro Biological Effects of Sodium Titanate Materials. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 83, 505-511.
[13] Wataha, J.C., Hobbs, D.T., Lockwood, P.E., Davis, R.R., Elvington, M.C., Lewis, J.B. and Messer, R.L.W. (2009) Peroxotitanates for Biodelivery of Metals. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 91B, 489-496.
[14] Davis, R.R., Hobbs, D.T., Khashaba, R., Sehkar, P., Seta, F.N., Messer, R.L.W., Lewis, J.B. and Wataha, J.C. (2010) Titanate Particles as Agents to Deliver Gold Compounds to Fibroblasts and Monocytes. Journal of Biomedical Materials Research Part A, 93A, 864-769.
[15] Wataha, J.C., Hobbs, D.T., Wong, J.J., Dogan, S., Zhang, H., Chung, K.-H. and Elvington, M.C. (2010) Titanates Deliver Metal Ions to Monocytes. Journal of Materials Science: Materials in Medicine, 21, 1289-1295.
[16] Meng, X.D., Wang, D., Liu, J. and Zhang, S. (2004) Preparation and Characterization of Sodium Titanate Nanowires from Brookite Nano Crystallites. Materials Research Bulletin, 39, 2163-2170.
[17] Choy, J.H., Lee, H.C., Jung, H. and Huang, S.J. (2001) A Novel Synthetic Route to TiO2 Pillared Layered Titanate with Enhanced Photo Catalytic Activity. Journal of Materials Chemistry, 11, 22-32.
[18] Corcoran, D.J.D., Tunstall, D.P. and Irvine, J.T.S. (2000) Hydrogen Titanates as Potential Proton Conducting Fuel Cell Electrolytes. Solid State Ionics, 136-137, 297-303.
[19] El-Naggar, I.M., Mowafy, E.A., Ali, I.M. and Aly, H.F. (2002) Synthesis and Sorption Behavior of Some Radioactive Nuclides on Sodium Titanate as Cation Exchanger Adsorption. Adsorption, 8, 225-234.
[20] Ramirez-Salgado, J. and Fabry, P. (2002) Feasibility of Potentiometric Oxygen Gas Sensor Based on Perovskite and Sodium Titanate Measuring Electrode. Sensors and Actuators B Chemical, 82, 34.
[21] Ramirez-Salgado, J., Djurado, E. and Fabry, P. (2004) Synthesis of sodium Titanate Composites by Sol-Gel Method for Use in Gas Potentiometric Sensors. Journal of the European Ceramic Society, 24, 2477-2483.
[22] Zarate, R.A., Fuentes, R.A.S. and Fuenzalida, V.M. (2006) Chemical Composition and Phase Identification of Sodium Titanate Nanostructures Grown from Titania by Hydrothermal Processing. LNLS Activity Report, Brazilian Synchrotron Light Laboratory.
[23] Morsi, I.M., Abdullah F.H.A., Mohamed O.A., Shalabi M.E.H. and El-Tawil S.Z. (1992) Processing of Ilmenite Ore by Sintering/Roasting Technique. 3rd Mining, Petroleum and Metallurgy Conference, Cairo, 2-4 February 1992.
[24] Lasheen, T.A. (2008) Soda Ash Roasting of Titana Slag Product from Rosetta Ilmenite. Hydrometallurgy, 93, 124-128.
[25] El-Hussiny, N.A. and Shalabi M.E.H. (2012) Studying the Pelletization of Rosetta Ilmenite Concentrate with Coke Breeze Using Molasses and Reduction Kinetics of Produced Pellets at 800C to 1150C. Science of Sintering, 44, 113-126.
[26] El-Gawad, H.H.A., El-Hussiny, N.A., Wassef, M.A., Khalifa, M.G., Soliman, A.A.A. and Shalabi, M.E.H. (2012) Reducibility Study of Egyptian Ilmenite Ore Briquettes and Powder with Coke Breeze at 800C - 1100C. Indian Chemical Engineer, 54, 83-94.
[27] Mayer, K. (1980) Pelletization of Iron Ores. Springer-Verlag, Berlin. Heidelberg.
[28] El-Hussiny, N.A. and Shalabi, M.E.H. (2011) A Self-Reduced Intermediate Product from Iron and Steel Plates Waste Materials Using a Briquetting Process. Powder Technology, 205, 217-223.
[29] Mangena, S.J. and Du Cann, V.M. (2007) Binder Less Briquetting of Some Selected South African Prim Coking, Blend Coking and Weathered Bituminous Coals and the Effect of Coal Properties on Binder Less Briquetting. International Journal of Coal Geology, 71, 303-312.
[30] Mohamed, F.M., Ahmed, Y.M.Z. and Shalabi, M.E.H. (2004) Briquetting of Waste Manganese Ore Sinter Fine Using Different Binding Materials, Environmental Issues and Waste Management in Energy and Mineral Production SWEMP, 567-573.
[31] Jander, W. and Anorg, Z. (1927) Kinetic Model for Solid-State Reactions. Zeitschrift für Anorganische und Allgemeine Chemie, 163, 1-30.

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