Effect of Surface Modification on Candidate Alloys for Canadian SCWR Fuel Cladding

Abstract

The Canadian Generation-IV supercritical water reactor (SCWR) requires peak cladding surface temperature of 800℃ for a core outlet temperature of 625℃. Materials selection for high temperature fuel cladding is becoming one of the major challenging tasks. Austenitic stainless steels with excellent corrosion resistance are often susceptible to stress corrosion cracking upon SCW exposure. Low-Cr steels such as P91 exhibit good high-temperature mechanical properties, but the lack of sufficient Cr content makes this group of alloys corrode too fast. One possible solution is to use coatings or surface modification techniques to improve the surface resistance to corrosion. In this study, we investigated the effect of surface modification on commercial 316L stainless steel. Surface modification by mechanical deformation has marked improvement in corrosion resistance during SCW exposure. Possible mechanisms for such improvement are discussed.

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Li, J. , Liu, P. , Zavadil, R. , Malis, T. and Penttilä, S. (2014) Effect of Surface Modification on Candidate Alloys for Canadian SCWR Fuel Cladding. Journal of Minerals and Materials Characterization and Engineering, 2, 129-134. doi: 10.4236/jmmce.2014.22017.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Allen, T.R., Sridharan, K., Chen, Y., Tan, L., Ren, X. and Druizenga, A. (2008) Materials Development and Selection for Corrosion Resistance: A Critical Issue in Supercritical Water Reactors. 16th Pacific Basin Nuclear Conference, Aomori, 13-18 October 2008, Paper ID: P16P1032.
[2] Hong, G.T., Ordway, D.W. and Ziberstein, V.A. (1995) Materials Testing in Supercritical Water Oxidation Systems. First International Workshop on Supercritical Water Oxidation, Jacksonville, 6-9 February 1995.
[3] Kritzer, P., Boukis, N. and Dinjus, E. (1998) Corrosion of Alloy 625 in Aqueous Solutions Containing Chloride and Oxygen.Corrosion 98, Paper No. 415, NACE, Houston.
[4] Kriksunov, L.B. and Macdonald, D.D. (1995) Corrosion in Supercritical Water Oxidation Systems: A Phenomenological Analysis. Journal of the Electrochemical Society, 142, 4069-4073.
http://dx.doi.org/10.1149/1.2048464
[5] Huang, S., Daehling, K., Carleson, T.E., Abdel-latif, M., Taylor, P., Wai, C. and Propp, A. (1989) Electrochemical Measurements of Corrosion of Iron Alloys in Supercritical Water. Supercritical Fluid Science and Technology, ACS Symposium Series 406, ACS, Washington DC, 287.
[6] Li, J., Guzonas, D., Wills, J., Dole, H., Michael, J., Zheng, W., Woo, O.-T. and Cook, W. (2009) Property of Passive Films Form on Alloys Tested in SCW Water. 4th International Symposium on Supercritical Water-Cooled Reactors, Heidelberg, 8-11 March 2009, Paper #56.
[7] Mitton, D.B., Eliaz, N., Cline, J.A. and Latanision, R.M. (2001) Corrosion 2001, Paper No. 01352, NACE, Houston.
[8] Kaneda, J., Kasahara, S., Kano, F., Saito, N., Shikama, T. and Matsui, M. (2011) Material Development for Supercritical Water-Cooled Reactor. 5th International Conference on SCWR (ISSCWR-5), Vancouver, 13-16 March 2011.
[9] Li, J. (2006) Focused Ion Beam Microscope. Journal of Metal, 58, 27-31.
[10] Li, J. (2008) The Detection of Local Plastic Strain in Microscopic Scale. Materials Letters, 62, 804-807. http://dx.doi.org/10.1016/j.matlet.2007.06.065
[11] Penttilä, S. Horvath, A., Toivonen, A. and Zolnai, Z. (2011) Effect of Surface Modification on the Corrosion Resistivity in Supercritical Water. 5th International Symposium on Supercritical Water-cooled Reactors (ISSCWR-5), Vancouver, 13-16 March 2011.
[12] Tsuchiya, Y., Kano, F., Saito, N., Ookawa, M., Kaneda, J. and Hara, N. (2007) Corrosion and SCC Properties of Fine Grain Stainless Steel in Subcritical and Supercritical Pure Water. CORROSION 2007, Nashville, 11-15 March 2007, Paper 07415.
[13] Ruther, W.E., Schlueter, R.R., Lee, R.H. and Hart, R.K. (1965) Corrosion Behavior of Steels and Nickel Alloys in Superheated Steam. In: NACE—International Corrosion Conference Series.
[14] Maekawa, T., Kagawa, M. and Nakajima, N. (1968) Corrosion Behaviors of Stainless Steel in High-Temperature Water and Superheated Steam. Transactions of the Japan Institute of Metals, 9, 130-136.
[15] Ziemniak, S.E., Guilmette, P.A., Turcotte, R.A. and Tunison, H.M. (2008) Oxidative Dissolution of Nickel Metal in Hydrogenated Hydrothermal Solutions. Corrosion Science, 50, 449-462.
http://dx.doi.org/10.1016/j.corsci.2007.07.013

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