Electrical Properties of Nano-TiO2 Thin Film Using Spin Coating Method

Abstract

This work investigated the electrical properties of TiO2 thin film on empty glass and ITO glass by spin coating method. Highly transparent titanium oxide thin films were prepared on empty glass and Indium Tin Oxide (ITO) from a titanium (III) chloride precursor. The sheet resistance of the film prepared from both the synthesised and the commercially available TiO2 was measured by the Keithley four-point probe tester (KFPPT). A comparable sheet resistance of 10.69E + 00 Ω/sq was obtained on the ITO. The electrical conductivity of the TiO2 film on ITO glass substrate was found to be very high (3.46E + 05 Ω-1?cm-1) and comparable to that of the bare ITO glass.

Share and Cite:

Daniyan, A. , Umoru, L. , Fasasi, A. , Borode, J. , Oluwasegun, K. and Olusunle, S. (2014) Electrical Properties of Nano-TiO2 Thin Film Using Spin Coating Method. Journal of Minerals and Materials Characterization and Engineering, 2, 15-20. doi: 10.4236/jmmce.2014.21003.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] A. A. Afonja, “Novel Materials for Energy Applications,” Nigerian Journal of Materials Science and Engineering, Vol. 1, No. 1, 2009, pp. 63-72.
[2] O. O. Adewoye, “Advances in Engineering Materials Development,” In Proceedings of Nigeria Materials Congress (NIMACON 2007), Centre for Energy, Research and Development (CERD), Obafemi Awolowo University, Ile-Ife, 2007, pp. 118-122.
[3] C. X. Shan, X. H. Hou and K.-L. Choy, “Corrosion Resistance of TiO2 Films Grown on Stainless Steel by Atomic Layer Deposition,” Surface and Coatings Technology, Vol. 202, No. 11, 2008, pp. 2399-2402. http://dx.doi.org/10.1016/j.surfcoat.2007.08.066
[4] T. Nishide, M. Sato and H. Hara, “Crystal Structure and Optical Property of TiO2 Gels and Films Prepared from Ti-Edta Complexes as Titania Precursors,” Journal of Materials Science, Vol. 35, No. 2, 2000, pp. 465-469. http://dx.doi.org/10.1023/A:1004731804075
[5] B. H. Kim, J. H. Ahn, J. H. Jeong, Y. S. Jeon, K. O. Jeon and K. S. Hwang, “Preparation of TiO2 Thin Film on SiO2 Glass by a Spin Coating—Pyrolysis Process,” Ceramics International, Vol. 32, 2006, pp. 223-225.
[6] Z. L. Tang, J. Y. Zhang, Z. Cheng and Z. T. Zhang, “Synthesis of Rutile TiO2 at Low Temperature,” Materials Chemistry and Physics, Vol. 77, No. 2, 2001, pp. 314-317. http://dx.doi.org/10.1016/S0254-0584(02)00003-2
[7] J. C. Yu, J. G. Yu, L. Z. Zhang and W. K. Ho, “Photocatalytic Activity of Nano-Sized TiO2 Powders by Sol-Gel Method, Using Titanium Tetraisopropoxide and EtOH/ H2O Solution,” Journal of Photochemistry and Photobiology A: Chemistry, Vol. 148, No. 1-3, 2002, pp. 263-271. http://dx.doi.org/10.1016/S1010-6030(02)00052-7
[8] Y. Z. Li, N. H. Lee, E. G. Lee, J. S. Song and S. Kim, “Preparation and Characterization of Nano-TiO2 Powder by Sol-Gel Method,” Chemical Physics Letters, Vol. 389, No. 1-3, 2004, pp. 124-128. http://dx.doi.org/10.1016/j.cplett.2004.03.081
[9] A. M. Ruiz, G. Sakai, A. Cornet, K. Shimanoe, J. R. Morante and N. Yamazoe, “Microstructure Control of Thermally Stable TiO2 Obtained by Hydrothermal Process,” Sensors and Actuators B: Chemical, Vol. 103, No. 1-2, 2004, pp. 312-317. http://dx.doi.org/10.1016/j.snb.2004.04.061
[10] S. Qiu and S. Kalita, “Synthesis, Processing and Characterization of Nanocrystalline Titanium Dioxide,”
Department of Mechanical, Materials and Aerospace Engineering College of Engineering and Computer Science,University of Central Florida, Orlando, Florida. http://www.google.com.ng/url?
q=http://etd.fcla.edu/CF/CFE0001432/QIU_SHIPENG_200612_MS.pdf&sa=U&ei
=4myxUpOtLaen0AXwxoAY&ved=0CB8QFjAA&usg=AFQjCNGnT3HeNSMtrE8rS0BDb4bbsDiXfw
[11] S. F. Chen, J. P. Li, K. Qian, W. P. Xu, Y. Lu, W. X. Huang and S. H. Yu, “Large Scale Photochemical Synthesis of M@TiO2 Nanocomposites (M = Ag, Pd, Au, Pt) and Their Optical Properties, CO Oxidation Performance, and Antibacterial Effect,” Nano Research, Vol. 3, No. 4, 2010, pp. 244-255. www.springerlink.com
[12] J. Y. Choi, K. Kim, J. Yoo and D. Kim, “Properties of Cadmium Sulphide Films Deposited by Chemical Bath Deposition with Ultrasonication,” Solar Energy, Vol. 64, No. 1-3, 1998, pp. 41-47. http://dx.doi.org/10.1016/S0038-092X(98)00047-4
[13] D. S. Reddy, D. R. Reddy, B. K. Reddy, A. M. Reddy, K. R. Gunasekhar and P. S. Reddy, “Annealing Effect on Physical Properties of Thermally Evaporated MnS Nanocrystalline Films,” Journal of Optoelectronics And Advanced Materials, Vol. 9, No. 7, 2007, pp. 2019-2022.
[14] R. K. Wahi, Y. Liu, J. C. Falkner and V. L. Colvin, “Solvothermal Synthesis and Characterization of Anatase TiO2 Nanocrystals with Ultrahigh Surface Area,” Journal of Colloid and Interface Science, Vol. 302, No. 2, 2006, pp. 530-536. http://dx.doi.org/10.1016/j.jcis.2006.07.003
[15] M. Addamo, V. Augugliaro, A. Paola, E. García-López, V. Loddo, G. Marcì and L. Palmisano, “Photocatalytic Thin Films of TiO2 Formed by a Sol-Gel Process Using Titanium Tetraisopropoxide as the Precursor,” Thin Solid Films, Vol. 516, No. 12, 2007, pp. 3802-3807.
http://dx.doi.org/10.1016/j.tsf.2007.06.139
[16] B.-H. Kim, J.-H. Ahn, J.-H. Jeong, Y.-S. Jeon, K.-O. Jeon and K.-S. Hwang, “Preparation of TiO2 Thin Film on SiO2 Glass by a Spin Coating—Pyrolysis Process,” Ceramics International, Vol. 32, No. 2, 2006, pp. 223-225. http://dx.doi.org/10.1016/j.ceramint.2005.01.016
[17] K. Bautista, “Thin Film Deposition,” Four-Point Probe Operation, 2004, pp. 1-8. Accessed on 18th July, 2011.
[18] M. Stamate, G. Lazar and I. Lazar, “Anatase—Rutil TiO2 Thin Films Deposited in a D.C. Magnetron Sputtering System,” Romanian Journal of Physics, Vol. 53, No. 1-2, 2008, pp. 217-221.
[19] R. Li and L. Chen, “A Nano Silver, and Its Preparation Method,” Chinese Patent CN10027622, 2005.
[20] T. Miyata, S. Tsukada and T. Minami, “Preparation of Anatase TiO2 Thin Films by Vacuum Arc Plasma Evaporation,” Thin Solid Film, Vol. 496, No. 1, 2006, pp. 136-140.
http://dx.doi.org/10.1016/j.tsf.2005.08.294
[21] J. H. Jia, P. Zhou, H. Xie, H. Y. You, J. Li and L. Y. Chen, “Study of Optical and Electrical Properties of TiO2/ Ag/TiO2 Multilayers,” Journal of the Korean Physical Society, Vol. 44, No. 3, 2003, pp. 717-721.

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.