FT-IR Spectroscopy Applied for Surface Clays Characterization


The present paper should be considered as a review of the application of Fourier Transform Infra-Red for surface clay characterization. The application of surface clay materials for water treatment, oil adsorption, excipients or as active in drugs has largely increased these recent years. The surface clay material presents hydroxyl groups, which can link very easily water molecules. These hydroxyl groups can react with organic groups and by their vibration in the infra-red region, FT-IR can be easily used as a technical method for surface clay characterization. In this paper, we focus on the determination of Lewis and Bronsted acid sites on the clay surface, a critical review of the sample preparation, the surface characterization of bulk clay and the modified surface clay samples using FT-IR spectroscopy.

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Djomgoue, P. and Njopwouo, D. (2013) FT-IR Spectroscopy Applied for Surface Clays Characterization. Journal of Surface Engineered Materials and Advanced Technology, 3, 275-282. doi: 10.4236/jsemat.2013.34037.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] D. W. Cho, C. M. Chon, Y. Kim, B.-H. Jeon, F. W. Schwartz, E.-S. Lee, et al., “Adsorption of Nitrate and Cr(VI) by Cationic Polymer-Modified Granular Activated Carbon,” Chemical Engineering Journal, Vol. 175, 2011, pp. 298-305. http://dx.doi.org/10.1016/j.cej.2011.09.108
[2] K. O. Adebowale, E. I. Unuabonaha and B. I. Olu-Owolabi, “Kinetic and Thermodynamic Aspects of the Adsorption of Pb2+ and Cd2+ Ions on Tripolyphosphate-Modified Kaolinite Clay,” Chemical Engineering Journal, Vol. 136, No. 2-3, 2008, pp. 99-107.
[3] J. Hizal and R. Apak, “Modeling of Cadmium(II) Adsorption on Kaolinite-Based Clays in the Absence and Presence of Humic Acid,” Applied Clay Science, Vol. 32, No. 3-4, 2006, pp. 232-244.
[4] P. Djomgoue, M. Siewe, E. Djoufac, P. Kenfack and D. Njopwouo, “Surface Modification of Cameroonian Magnetite Rich Clay with Eriochrome Black T. Application for Adsorption of Nickel in Aqueous Solution,” Applied Surface Science, Vol. 258, No. 19, 2012, pp. 7470-7479.
[5] J. L. Marco-Brown, C. M. Barbosa-Lema, R. M. Torres Sanchez, R. C. Mercader and M. dos Santos Afonso, “Adsorption of Picloram Herbicide on Iron Oxide Pillared Montmorillonite,” Applied Clay Science, Vol. 58, 2012, pp. 25-33. http://dx.doi.org/10.1016/j.clay.2012.01.004
[6] M. S. El-Geundi, M. M. Nassar, T. E. Farrag and M. H. Ahmed, “Removal of an Insecticide (methomyl) from Aqueous Solutions Using Natural Clay,” Alexandria Engineering Journal, Vol. 51, No. 1, 2012, pp. 11-18.
[7] N. Oztürk and T. E. Bektas, “Nitrate Removal from Aqueous Solution by Adsorption onto Various Materials,” Journal of Hazardous Materials, Vol. 112, No. 1-2, 2004, pp. 155-162.
[8] A. Azzouz, E. Assaad, A.-V. Ursu, T. Sajin, D. Nistor and R. Roy, “Carbon Dioxide Retention over Montmorillonite-Dendrimer Materials,” Applied Clay Science, Vol. 48, No. 1-2, 2010, pp. 133-137.
[9] C. R. Reddy, Y. S. Bhat, G. Nagendrappa and B. S. Jai Prakash, “Bronsted and Lewis Acidity of Modified Montmorillonite Clay Catalysts Determined by FT-IR Spectroscopy,” Catalysis Today, Vol. 141, No. 1-2, 2009, pp. 157-160. http://dx.doi.org/10.1016/j.cattod.2008.04.004
[10] H. Cheng, Q. Liu, J. Yang, S. Ma and R. L. Frost, “The Thermal Behavior of Kaolinite Intercalation ComplexesA Review,” Thermochimica Acta, Vol. 545, 2012, pp. 1-13. http://dx.doi.org/10.1016/j.cattod.2008.04.004
[11] T. Shichi and K. Takagi, “Clay Minerals as Photochemical Reaction Fields,” Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 1, No. 2, 2000, pp. 113-130.
[12] H. He, Q. Tao, J. Zhu, P. Yuan, W. Shen and S. Yang, “Silylation of Clay Mineral Surfaces,” Applied Clay Science, Vol. 71, 2013, pp. 15-20.
[13] E. Eren, “Removal of Copper Ions by Modified Unye Clay, Turkey,” Journal of Hazardous Materials, Vol. 159, No. 2-3, 2008, pp. 235-244.
[14] Z. Qian, G. Hu, S. Zhang and M. Yang, “Preparation and Characterization of Montmorillonite-Silica Nanocomposites: A Sol-Gel Approach to Modifying Clay Surfaces,” Physica B: Condensed Matter, Vol. 403, No. 18, 2008, pp. 3231-3238. http://dx.doi.org/10.1016/j.physb.2008.04.008
[15] F. Hussin, M. K. Aroua and W. M. A. W. Daud, “Textural Characteristics, Surface Chemistry and Activation of Bleaching Earth: A Review,” Chemical Engineering Journal, Vol. 170, No. 1, 2011, pp. 90-106.
[16] V. A. Bell, V. R. Citro and G. A. L. D. Hodge, “Effect of Pellet Pressing on the Infrared Spectrum of Kaolinite,” Clays and Clay Minerals, Vol. 39, No. 3, 1991, pp. 290-292. http://dx.doi.org/10.1346/CCMN.1991.0390309
[17] J. Madejova and P. Komadel, “Baseline Studies of the Clay Minerals Society Source Clays: Infrared Methods,” Clays and Clay Minerals, Vol. 49, No. 5, 2001, pp. 410-432. http://dx.doi.org/10.1346/CCMN.2001.0490508
[18] G. Murali Krishna, M. Muthukumaran, B. Krshnamoorthy and A. Nishat, “A Critical Review on Fundamental and Pharmaceutical Analysis of FTIR Spectroscopy,” International Journal of Pharmacy, Vol. 3, No. 2, 2013, pp. 396-406.
[19] S. Yariv, “Thermo-IR-Spectroscopy Analysis of the Interactions between Organic Pollutants and Clay Minerals,” Thermochimica Acta, Vol. 274, 1996, pp. 1-35.
[20] W. J. Brian, B. Jorg, D. Karl and P. Bruno, “Practical Considerations of the Ir Attenuated-Total-Reflection (ir-ATR) Technique for Electrochemical Investigations,” Electrochimica Acta, Vol. 37, No. 12, 1992, pp. 2321-2329.
[21] M. Elena Ramos and F. Javier Huertas, “Adsorption of Glycine on Montmorillonite in Aqueous Solutions,” Applied Clay Science, Vol. 80-81, 2013, pp. 10-17.
[22] R. L. Frost and E. Mendelovici, “Modification of Fibrous Silicates Surfaces with Organic Derivatives: An Infrared Spectroscopic Study,” Journal of Colloid and Interface Science, Vol. 294, No. 1, 2006, pp. 47-52.
[23] S. Shoval, S. Yariv, K. Michaelian, I. Lapides, M. Boudeuille and G. Panczer, “A Fifth OH-Stretching Band in IR Spectra of Kaolinites,” Journal of Colloid and Interface Science, Vol. 212, No. 2, 1999, pp. 523-529.
[24] G. Sposito, “Infrared Spectroscopic Study of Adsorbed Water on Reduced-Charge Na/Li-Montmorillonites,” Clays and Clay Minerals, Vol. 31, No. 1, 1983, pp. 9-16.
[25] S. Korichi, A. Elias and A. Mefti, “Characterization of Smectite after Acid Activation with Microwave Irradiation,” Applied Clay Science, Vol. 42, No. 3-4, 2009, pp. 432-438. http://dx.doi.org/10.1016/j.clay.2008.04.014
[26] J. Murakami, “Synthesis of Kaolinite-Organic Nanohybrids with Butanediols,” Solid State Ionics, Vol. 172, No. 1-4, 2004, pp. 279-282.
[27] P. M. Amarasinghe, K. S. Katti and D. R. Katti, “Nature of Organic Fluid-Montmorillonite Interactions: An FTIR Spectroscopic Study,” Journal of Colloid and Interface Science, Vol. 337, No. 1, 2009, pp. 97-105.
[28] L. Jankovic, “Metal Cation-Exchanged Montmorillonite Catalyzed Protection of Aromatic Aldehydes with Ac2O,” Journal of Catalysis, Vol. 218, No. 1, 2003, pp. 227-233.
[29] G. Y. Zhang and D. Peak, “Studies of Cd(II)-Sulfate Interactions at the Goethite-Water Interface by Atr-Ftir Spectroscopy,” Geochimica Et Cosmochimica Acta, Vol. 71, No. 9, 2007, pp. 2158-2169.
[30] Y. Brechbühl, I. Christl, E. J. Elzinga and R. Kretzschmar, “Competitive Sorption of Carbonate and Arsenic to Hematite: Combined ATR-FTIR and Batch Experiments,” Journal of Colloid and Interface Science, Vol. 377, No. 1, 2012, pp. 313-321.
[31] K. Morimoto, S. Anraku, J. Hoshino, T. Yoneda and T. Sato, “Surface Complexation Reactions of Inorganic Anions on Hydrotalcite-Like Compounds,” Journal of Colloid and Interface Science, Vol. 384, No. 1, 2012, pp. 99-104. http://dx.doi.org/10.1016/j.jcis.2012.06.072
[32] K. P. Nicolini, C. R. B. Fukamachi, F. Wypych and A. S. Mangrich, “Dehydrated Halloysite Intercalated Mechanochemically with Urea: Thermal Behavior and Structural Aspects,” Journal of Colloid and Interface Science, Vol. 338, No. 2, 2009, pp. 474-479.
[33] A. Spence and B. P. Kelleher, “FT-IR Spectroscopic Analysis of Kaolinite-Microbial Interactions,” Vibrational Spectroscopy, Vol. 61, 2012, pp. 151-155.
[34] H. Long, P. Wu and N. Zhu, “Evaluation of Cs+ Removal from Aqueous Solution by Adsorption on EthylamineModified Montmorillonite,” Chemical Engineering Journal, Vol. 225, 2013, pp. 237-244.
[35] V. Matějka, M. Supova, V. Klemm, D. Rafaja, M. ValaSkova, J. Tokarsky, et al., “Vermiculite Interlayer as a Reactor for CdS Ultrafine Particles Preparation,” Microporous and Mesoporous Materials, Vol. 129, No. 1-2, 2010, pp. 118-125.
[36] P.-H. Chang, Z. Li, J.-S. Jean, W.-T. Jiang, C.-J. Wang and K.-H. Lin, “Adsorption of Tetracycline on 2:1 Layered Non-Swelling Clay Mineral Illite,” Applied Clay Science, Vol. 67-68, 2012, pp. 158-163.
[37] H. Tan, W. Skinner and J. Addai-Mensah, “Leaching Behaviour of Low and High Fe-Substituted Chlorite Clay Minerals at Low pH,” Hydrometallurgy, Vol. 125-126, 2012, pp. 100-108.
[38] Y. Deng, J. B. Dixon, G. N. White, R. H. Loeppert and A. S. R. Juo, “Bonding between Polyacrylamide and Smectite,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 281, No. 1-3, 2006, pp. 82-91.
[39] C. Bisio, G. Gatti, E. Boccaleri, L. Marchese, G. B. Superti, H. O. Pastore and M. Thommes, “Understanding Physico-Chemical Properties of Saponite Synthetic Clays,” Microporous and Mesoporous Materials, Vol. 107, No. 1-2, 2008, pp. 90-101.
[40] S. Akyuz, T. Akyuz and E. Akalin, “Adsorption of Isoniazid onto Sepiolite-Palygorskite Group of Clays: An IR Study, Spectrochimica Acta. Part A,” Molecular and Biomolecular Spectroscopy, Vol. 75, No. 4, 2010, pp. 1304-1307. http://dx.doi.org/10.1016/j.saa.2009.12.069
[41] M. Zamama and M. Knidiri, “IR Study of Dickite-Formamide Intercalate, Al2Si2O5(OH)4-H2NCOH,” Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, Vol. 56, No. 6, 2000, pp. 1139-1147.
[42] B. Feng, Q. Feng and Y. Lu, “The Effect of Lizardite Surface Characteristics on Pyrite Flotation,” Applied Surface Science, Vol. 259, 2012, pp. 153-158.

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