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Colloidal Synthesis of Silver Nanoprisms in Aqueous Medium: Influence of Chemical Compounds in UV/Vis Absorption Spectra

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DOI: 10.4236/anp.2013.23030    5,556 Downloads   9,906 Views   Citations


In this work we explore the influence of the factors that affect the formation of silver nanoprisms (AgNPs) with distinct size and size distribution as well as the most intense absorption peak shift. Box-Behnken design analysis was applied to optimize the production of silver nanoprism via colloidal synthesis. The analysis of the responses was based on the nanoprisms plasmon peak wavelength related to in-plane dipole (tunable band) at λmax. ≥ 420 nm. The obtained results indicate that Silver ion is the main variable for the tuning of the size and the Localized Surface Plasmon Resonance (LSPR) frequency. By using the Box-Behnken design it was possible to synthesize nanoparticles with a predictable size and to establish a rigorous control of the plasmon frequency at the range of 600 up to 800 nm.

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The authors declare no conflicts of interest.

Cite this paper

Silva, J. , Saade, J. , Farias, P. and Falcão, E. (2013) Colloidal Synthesis of Silver Nanoprisms in Aqueous Medium: Influence of Chemical Compounds in UV/Vis Absorption Spectra. Advances in Nanoparticles, 2, 217-222. doi: 10.4236/anp.2013.23030.


[1] K. L. Kelly, Z. E. Coronado, L. L. Zhao and G. C. Schatz, “The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment,” The Journal of Physical Chemistry B, Vol. 107, No. 3, 2003, pp. 668-677. doi:10.1021/jp026731y
[2] M. Grzelczak, J. Pérez-Juste, P. Mulvaney and L. M. Liz-Marzan, “Shape Control in Gold Nanoparticle Syn thesis,” Chemical Society Reviews, Vol. 37, No. 9, 2008, pp. 1783-1791.
[3] Y. Xia, Y. Xiong, B. Lim and S. Skrabalak, “Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemi stry Meets Complex Physics?” Angewandte Chemie In ternational Edition, Vol. 48, No. 1, 2009, pp. 60-103. doi:10.1002/anie.200802248
[4] B. Wiley, T. Herricks, Y. Sun and Y. Xia, “Polyol Synthesis of Silver Nanoparticles: Use of Chloride and Oxygen to Promote the Formation of Single-Crystal, Truncated Cubes and Tetrahedrons,” Nano Letter, Vol. 4, No. 9, 2004, pp. 1733-1739. doi:10.1021/nl048912c
[5] V. Bastys, I. Pastoriza-Santos, B. Rodríguez-González, R. Vaisnoras and L. M. Liz-Marzán, “Formation of Silver Nanoprisms with Surface Plasmons at Communication Wavelengths,” Advanced Functional Materials, Vol. 16, No. 6, 2006, pp. 766-773. doi:10.1002/adfm.200500667
[6] W. Shi and Z. Ma, “Amperometric Glucose Biosensor Based on a Triangular Silver Nanoprisms/Chitosan Com posite Film as Immobilization Matrix,” Biosensors and Bioelectronics, Vol. 26, No. 3, 2010, pp. 1098-1103. doi:10.1016/j.bios.2010.08.072
[7] G. Si, W. Shi, K. Li and Z. Ma, “Synthesis of PSS Capped Triangular Silver Nanoplates with Tunble SPR,” Colloids and Surfaces A: Physicochemical and Enginee ring Aspects, Vol. 380, No. 1-3, 2011, pp. 257-260. doi:10.1016/j.colsurfa.2011.02.023
[8] G. E. P. Box, W. G. Hunter and J. S. Hunter, “Statistics for Experimenters—An Introduction to Design, Data Analysis and Model Building,” Wiley, New York, 1978.
[9] W. Zhang, Y. Yao, N. Sullivan and Y. S. Chen, “Modeling the Primary Size Effects of Citrate-Coated Silver Nanoparticles on Their Ion Release Kinetics,” Environmental Science & Technology, Vol. 45, No. 10, 2011, pp. 4422-4428. doi:10.1021/es104205a
[10] J. Yang, Q. Zhang, J. Y. Lee and H. Too, “Dissolution Recrystallization Mechanism for the Conversion of Silver Nanospheres to Triangular Nanoplates,” Journal of Colloid and Interface Science, Vol. 308, No. 1, 2007, pp. 157-161. doi:10.1016/j.jcis.2006.12.081
[11] J. L. Elechiguerra, L. Larios-Lopez, C. Liu, D. Garcia Gutierrez, A. Camacho-Bragado and M. J. Yacaman, “Corrosion at the Nanoscale: The Case of Silver Nano wires and Nanoparticles,” Chemistry of Materials, Vol. 17, No. 24, 2005, pp. 6042-6052. doi:10.1021/cm051532n
[12] E. Petryayeva and U. J. Krull, “Localized Surface Plasmon Resonance: Nanostructures, Bioassays and Biosensing—A Review,” Analitica Chimica Acta, Vol. 706, No. 1, 2011, pp. 8-24. doi:10.1016/j.aca.2011.08.020
[13] M. Tsuji, S. Gomi, Y. Maeda, M. Matsunaga, S. Hikino, K. Uto, T. Tsuji and H. Kawazumi, “Rapid Transformation from Spherical Nanoparticles, Nanorods, Cubes, or Bipyramids to Triangular Prisms of Silver with PVP, Citrate, and H2O2,” Langmuir, Vol. 28, No. 24, 2012, pp. 8845-8861. doi:10.1021/la3001027
[14] C. Loo, A. Lowery, N. Halas, J. West and R. Drezek, “Immunotargeted Nanoshells for Integrated Cancer Imaging and Therapy,” Nano Letter, Vol. 5, No. 4, 2005, pp. 709-711. doi:10.1021/nl050127s

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