Relationship between Helium Degassing of Cattle-Manure-Compost Adsorbents and Copper Ions Removal


This work was aimed to investigate the effect of helium degassing of cattle-manure-compost (CMC) based activated carbons on the adsorptive removal of copper ions from aqueous solution. Degassing temperatures were 500℃, 800℃ and 1000℃. Activated carbons were characterized according to surface chemistry and pore structures. Adsorption of copper ions was carried out using the conventional bottle-point technique to which the equilibrium data were correlated to Langmuir and Freundlich models. Results indicated that the uptake of copper ions could be well characterized by Langmuir model. It was found that the adsorption of copper ions decreased with significant decrease in surface area as a result of helium degassing at higher temperature. The increase of electron density on graphene layers offered higher affinity towards copper ions at lower equilibrium concentration. It was inferred that copper ions favorably adsorbed on mesopores at lower equilibrium concentration and switched to micropores at higher equilibrium concentration.

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M. Zaini, M. Yunus, Y. Aman and M. Machida, "Relationship between Helium Degassing of Cattle-Manure-Compost Adsorbents and Copper Ions Removal," International Journal of Organic Chemistry, Vol. 2 No. 3, 2012, pp. 262-266. doi: 10.4236/ijoc.2012.23035.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] WHO, “Guidelines for Drinking Water Quality,” World Health Organization, Geneva, 2006.
[2] T. A. Kurniawan, G. Y. S. Chan, W.-H. Lo and S. Babel, “Physico-Chemical Treatment Techniques for Wastewater Laden with Heavy Metals,” Chemical Engineering Journal, Vol. 118, No. 1-2, 2006, pp. 83-98. doi:10.1016/j.cej.2006.01.015
[3] R. C. Bansal and M. Goyal, “Activated Carbon Adsorption,” CRC Press, Boca Raton, 2005. doi:10.1201/9781420028812
[4] Roskill, “The Economics of Activated Carbon,” Roskill Information Services Ltd., London, 2008.
[5] J. M. Dias, M. C. M. Alvim-Ferraz, M. F. Almeida, J. Rivera-Utrilla and M. Sánchez-Polo, “Waste Materials for Activated Carbon Preparation and Its Use in Aqueous- Phase Treatment: A Review,” Journal of Environmental Management, Vol. 85, No. 4, 2007, pp. 833-846. doi:10.1016/j.jenvman.2007.07.031
[6] Q. Qian, M. Machida and H. Tatsumoto, “Preparation of Activated Carbons from Cattle-Manure Compost by Zinc Chloride Activation,” Biore-source Technology, Vol. 98, No. 2, 2007, pp. 353-360. doi:10.1016/j.biortech.2005.12.023
[7] Q. Qian, Q. Chen, M. Machida, H. Tatsumoto, K. Mo- chidzuki and A. Sakoda, “Removal of Organic Contaminants from Aqueous Solution by Cattle Manure Compost (CMC) Derived Activated Carbons,” Applied Surface Science, Vol. 255, No. 12, 2009, pp. 6107-6114. doi:10.1016/j.apsusc.2009.01.060
[8] M. A. A. Zaini, R. Okayama and M. Machida, “Adsorption of Aqueous Metal Ions on Cattle-Manure-Compost- Based Activated Carbons,” Journal of Hazardous Materials, Vol. 170, No. 2-3, 2009, pp. 1119-1124. doi:10.1016/j.jhazmat.2009.05.090
[9] H. P. Boehm, “Some Aspects of the surface Chemistry of Carbon Blacks and Other Carbons,” Carbon, Vol. 32, No. 5, 1994, pp. 759-769. doi:10.1016/0008-6223(94)90031-0
[10] I. D. Smiciklas, S. K. Milonjic, P. Pfendt and S. Raicevic, “The Point of Zero Charge and Sorption of Cadmium (II) and Strontium (II) Ions on Synthetic Hydroxyapatite,” Separation and Purification Technology, Vol. 18, No. 3, 2000, pp. 185-194. doi:10.1016/S1383-5866(99)00066-0

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