Structural and Optical Characterization Studies on 2, 4- dinitrophenylhydrazine Single Crystal

DOI: 10.4236/jmmce.2010.94023   PDF   HTML     6,100 Downloads   7,699 Views   Citations

Abstract

Single crystal of an organic nonlinear optical (NLO) material, 2,4-Dnitrophenylhydrazine (DNPH), was grown by slow cooling method. Powder X-ray diffraction (PXRD), Fourier transform infrared (FT-IR) FT-Raman and NMR studies have confirmed respectively the crystal structure and functional groups of the grown crystal. Crystalline perfection of single crystals was evaluated by high resolution X-ray diffractometry (HRXRD) using a multicrystal X–ray diffractometer and found that the grown crystals are nearly perfect. UV-Visible-NIR spectral analysis was used to determine the optical constants and band gap of DNPH. Fluorescence spectrum of DNPH was recorded.

Share and Cite:

T. Devi, N. Lawrence, R. Babu, K. Ramamurthi and G. Bhagavannarayana, "Structural and Optical Characterization Studies on 2, 4- dinitrophenylhydrazine Single Crystal," Journal of Minerals and Materials Characterization and Engineering, Vol. 9 No. 4, 2010, pp. 321-330. doi: 10.4236/jmmce.2010.94023.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] H. Vidrio, G. Fernandez, M. Medina, E. Alvarez, F. Orallo, Vascul Pharmacol. 40 (2003) 13.
[2] S. Patil, A. Kanase, P.H. Kulkarni, Indian J. Exp. Biol. 38 (2000) 253.
[3] I. Kosalec, M. Bakmaz, S. Pepeljnjak, S. Vladimir-Knezevic, Acta Pharm. 54 (2004) 65.
[4] S. Gupta, R.C. Husser, R.S. Geske, S.E. Welty, C.Smith, Toxicol. Sci. 54 (2000) 203.
[5] N. Okabe, T. Nakamura, H. Pukuda, Acta Crystallogr. C49 (1993) 1678.
[6] J.L. Wardell, J.N. Low, C. Glidewell, Acta Cryst. C62 (2006) o318.
[7] V. Chis, S. Filip, V.Miclaus, A. Pirnau, C. Tanaselia, V.Almasan, M. Vasilescu, J.mol.struct. 744 (2005) 363.
[8] N. Sundaraganesan, S. Ayyappan, H. Umamaheswari, B. D. Joshua, Spectrochim. Acta A 66 (2007) 17.
[9] R. Ramesh Babu, S. Kumaresan, N. Vijayan, M. Gunasekaran, R.Gopalakrishnan, P. Kannan, P. Ramasamy J.Cryst. Growth 256 (2003) 387.
[10] S. A. deVries, P. Goedtkindt, W. J. Huisman, M. J. Zwanenburg, R.Feidenhans’l, S. L. Bennett, D. M. Smilgies, A. Stierle, J. J. De Yoreo, W. J. P. van Enckevort, P. Bennema, E. Vlieg, J. Cryst. Growth 205 (1999) 202.
[11] K. Udaya Lakshmi, K. Ramamurthi, Cryst. Res. Technol. 40, 1167 (2005).
[12] K. Lal, G. Bhagavannarayana, J. Appl. Cryst. 22, 209 (1989).
[13] G. Bhagavannarayana, R.V. Ananthamurthy, G.C. Budakoti, B. Kumar, K.S.Bartwal, J. Appl.Cryst. 38, 768 (2005).
[14] G. Socrates, Infrared Characteristic Group frequencies; Wiley-Interscience: Chichester, U.K., 1980.
[15] Hobart H. Willard, Lynne L. Merritt jr., John A. Dean, Frank A.Settle jr., Instrumental Methods of Analysis,Sixth Edition, Wadsworth Publishing Company. USA, 1986 pp.609.
[16] N. J. Turro, Molecular Photochemistry, W. A. Benjamin, Inc. Publishers, Massachusetts, 1965.

  
comments powered by Disqus

Copyright © 2020 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.