Effect of Talus Deposit Excavations on Hydrogeochemical Characteristics of Kuvars Spring Water, Maltepe, Istanbul, Turkey

Abstract

Spring waters consumed for drinking purposes should be clean and quality. These waters with balanced mineral distribution, which do not contain organic substances, whose physical and chemical caharacteristics comply with certain quality parameters and which do not negatively affect human health are identified as healthy water. Kuvars water is a spring water which is pumped out from the draw well at the Camurluk stream basin of Maltepe province of Istanbul and filled into bottles. The Camurluk stream basin is approximately 4.5 km2. The Camurluk stream basin is sedimentary rocks and talus deposit outcrops. Reaching of trace elements, which is found more in the talus deposit samples than outcropping quartzarenite at the basin, to underground aquifer as ions under effect of rains, water rock interaction, leakage and filtration, is prevented by illite type clay levels existing within the talus deposit stack, which have upto 20 cm thickness. However, negative effects of the excavation that were made at the talus deposit reflect on the hydrologic cycle and chemical compositions of well waters. This effect was at first negatively affected the physical characteristics of the well waters. During the rainy periods, the water in the excavated area which was enriched with respect to the suspended sediments was percolated into the groundwaters from the joints and cracks of the quartzarenite. The turbidity value measured in the well waters of K2 and K3 were determined as 40.3 NTU and 34.2 NTU respectively. Although at the basin, the aquifer of underground water and the well waters being managed are quartzarenite, the fact that water types belonging to well waters differ (they are not same) according to the Piper diagram and when the heavy metal content of the water of well numbered KS1 is taken as basis, that some heavy metals such as Al3+, Fe2+, Ni2+, Mn2+ and Cu2+ be enriched 3 to 40 times in KS2 and KS3 well waters, are caused by talus deposit—water interaction at the excavation area. After a rainfall, in the water that became turbid with the water-talus deposit interaction at the excavation area, the water-mineral interaction has caused the limit value for drinking water suggested by World Health Organization (WHO) to be exceeded with the Al3+ concentration of 189 ppb detected in KS2 well water and Fe2+ concentration of 185 ppb has caused to approach the drinking water limit value of 200 ppb permitted by World Health Organization (WHO), United States Environmental Protection Agency (EPA), European Union (EU) and Turkish Standards (TS). Therefore, at the water basins where bottled spring waters consumed for drinking purposes are produced, technical undertakings that shall disturb the stability of geological units should not be permitted.

Share and Cite:

R. Pehlivan, H. Emre and D. Key, "Effect of Talus Deposit Excavations on Hydrogeochemical Characteristics of Kuvars Spring Water, Maltepe, Istanbul, Turkey," Journal of Water Resource and Protection, Vol. 4 No. 5, 2012, pp. 294-306. doi: 10.4236/jwarp.2012.45032.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] C. Lee and F. C. Loughnan, “Chemical Weathering of the Silicate Minerals,” Elsevier, London, 1969, pp. 1-154.
[2] R. J. Gibbs, “Mechanismis Controlling World Water Chemistry”, Science, Vol. 170, No. 3962, 1970, pp. 1088-1090. doi:10.1126/science.170.3962.1088
[3] J. Gaillardet, B. Dupre and C. J. Allegre, “Geochemistry of Large River Suspended Sediments: Silicate Weathering or Recycling Tracer?”, Geochimica et Cosmochimica Acta, Vol. 63, No. 23/24, 1999, pp. 4037-4051. doi:10.1016/S0016-7037(99)00307-5
[4] W. Chesworth, J. Dejou and P. Larroque, “The Weathering of Basalts and Relative Mobilities of the Major Elements at Belbex France,” Geochimica et Cosmochimica Acta, Vol. 45, No. 7, 1991, pp. 1235-1243. doi:10.1016/0016-7037(81)90147-2
[5] R. F. Stallard, “Weathering and Erosion in the Humid Tropics,” In: A. Lerman and M. Meybeck, Eds., Physical and Chemical Weathering in Geochemical Cycles, Kluwer Academic Publishers, Dordrecht, 1998, pp. 225-246.
[6] I. D. L. Foster and S. M. Charlesworth, “Heavy Metals in the Hydrological Cycle: Trends and Explanation,” Hydrological Processes, Vol. 10, No. 2, 1996, pp. 227-261. doi:10.1002/(SICI)1099-1085(199602)10:2<227::AID-HYP357>3.0.CO;2-X
[7] N. A. Nkono and O. I. Asubiojo, “Trace Elments in Bottled and Soft Drinks in Nigeria: A Preliminary Study,” The Science of the Total Environment, Vol. 208, No. 3, pp. 161-163. doi:10.1016/S0048-9697(97)00289-1
[8] C. Reimann, K. Bjorvatn, B. Frengstad, Z. Melaku , R. T. Haimanot and U. Siewers, “Drinking Water Quality in the Ethiopian Section of the East African Rift Valley I-Data and Health Aspects,” The Science of the Total Environment, Vol. 311, No. 1-3, 2003, pp. 65-80. doi:10.1016/S0048-9697(03)00137-2
[9] S. Li and Q. Zhang, “Geochemistry of the Upper Han River Basin China. 1: Spatial Distribution of Major ?on Compositions and Their Controlling Factors,” Applied Geochemistry, Vol. 23, No. 12, 2008, pp. 3535-3544. doi:10.1016/j.apgeochem.2008.08.012
[10] G. Papastergios, J. L. Fernandez-Turiel, A. Georgakopoulos and D. Gimeno, “Natural and Anthropogenic Effects on the Sediment Geochemistry of Nestos River Northern Greece,” Environmental Geology, Vol. 58, No. 6, 2009, pp. 1361-1370. doi:10.1007/s00254-008-1639-8
[11] R. Pehlivan and O. Yilmaz, “Marmara Bolgesi Termomineral Kaynaklarinin ?cilebilirligi ve ?nsan Sagligina Etkisi,” Jeoloji Muhendisligi Dergisi, Vol. 47, 1995, pp. 21-27.
[12] R. Pehlivan, “The Effects on Human Health and Hydrogeochemical Characteristics of the Kirkgecit and Ozancik Hot Springs Canakkale, Turkey,” Environmental Geochemistry and Health, Vol. 25, No. 2, 2003, pp. 205-217. doi:10.1023/A:1023205900038
[13] R. Pehlivan “Quality of Bottled Waters in Turkey,” Journal of Nepal Geological Society, Vol 35, 2007, pp. 37-42.
[14] C. Guler, M. Alpaslan and C. Akbulut, “Istanbul ve Civarinda Satisa Sunulan Sise Sularinin Kalitesi,” Istanbul’un Su Politikasi Sempozyumu Bildiriler Kitabi, 2008, p. 408.
[15] R. Pehlivan, “The Effect of Weathering in the Buyukmelen River Basin on the Geochemistry of Suspended and Bed Sediments and the Hyrogeochemical Characteristics of River Water Duzce, Turkey,” Journal of Asian Earth Sciences, Vol. 39, No. 1-2, 2010, pp. 62-75. doi:10.1016/j.jseaes.2010.02.011
[16] A. F. McClymont, M. Hayashi, L. R. Bentley, D. Muir and E. Ernst, “Groundwater Flow and Storage within an Alpine Meadow-Talus Complex,” Hydrology and Earth System Sciences, Vol. 14, No. 6, 2010, pp. 859-872. doi:10.5194/hess-14-859-2010
[17] Regulation, “Insani Tuketim Amacli Sular Hakkinda Yonetmelik,” Saglik Bakanligi, RG 25730, 2005, p. 27.
[18] C. W. Thornthwaite, “An Approach toward a Rational Classification of Climate,” Geographic Review, Vol. 38, No. 1, 1948, pp. 55-94. doi:10.2307/210739
[19] DMI, “2009-2010 Yili Kumulatif Yagis Raporu. Devlet Meteoroloji Isleri Genel Mudurlugu,” 2010. http://www.dmi.gov.tr/veridegerlendirme/yagis-raporu.aspx?y=k
[20] M. Onalan, “Istanbul Ordovisiyen ve Siluriyen Istifinin Cokelme Ortamlari,” IU Yerbilimleri Dergisi, Vol. 2, No. 3-4, 1981, pp. 161-177.
[21] R. Pehlivan and O Yilmaz, “Hidrojeokimya,” IU Muhendislik Fakultesi Yayin, No 112, ISBN No: 975-404-750-2, 2005, p. 160.
[22] WHO, “Guidelines for Drinking-Water Quality, Recommendations,” World Health Organization First Addendum to Th?rd Edition Geneva, Vol. 1, 2006, p. 595.
[23] United States Environmental Protection Agency, “National Primary Drinking Water Ragulations,” 2009. http://www.epa.gov/safewater/contaminants/index.html
[24] J. Qin, Y. Huh, J. M. Edmond, G. Du and J. Ran, “Chemical and Physical Weathering in the Min Jiang, a Headwater Tributary of the Yangtze River,” Chemical Geology, Vol. 227, No. 1-2, 2006, pp. 53-69. doi:10.1016/j.chemgeo.2005.09.011
[25] H. Schoeller, “Les Eaux Souterraines,” Masson et Cie, Paris, Vol. 1, 1962, p. 642.
[26] A. M. Piper, “A Graphic Procedure in the Geochemical Interpretation of Water Analyses,” US Geological Survey Groundwater, Washington DC, Note 12, 1953, p. 63.
[27] European Union, “Council Directive 98/83/EC of 3 Nowember 1998 on the Quality of Water ?ntended for Human Consumption,” Offical Journal, L330, 1998, pp. 32-54.
[28] Turkish Standard, “Sular-Insani Tuketim Amacli Sular,” TS 266, 2005, p. 10.
[29] SKKY, “Su Kirliligi Kontrolu Yonetmeligi,” Cevre ve Orman Bakanligi, RG 25687, 2004, p. 51.
[30] P. W. Birkeland, “Soils and Geomorphology,” Oxford University Press, New York, 1999.
[31] C. J. Bowser and B. F. Jones, “Mineralogic Controls on the Composition of Natural Waters Dom?nated by Silicate Hydrolysis,” American Journal of Science, Vol. 302, No. 7, pp. 582-662. doi:10.2475/ajs.302.7.582

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.