Study on the Mechanism of Heterogeneous Catalysis (1) —The Measurement of Equilibrium Pressure of Reaction BaCO3 + C = BaO + 2CO, the Chemical States of Fe in Reaction Tank, and Chemical Reaction Model Catalytic Cycle Mechanism (CRMM) ()
ABSTRACT
The results on the equilibrium pressure measurement of BaCO3 + C = BaO + 2CO reaction and the demonstration of chemical state of iron proved that decomposition-generation cycle of BaCO3 and oxidation-reduction cycle of Fe in that reaction condition case were impossible to occur. The Chemical Reaction Model Catalytic Cycle Mechanism-CRMM does not exist at all for BaCO3, Fe, Noble metal catalysts. To call CRMM as a “principle” was obviously inappropriate. The TOF (Turnover Frequency—TOF: unit: s-1) was used to measure the activity size and life of catalyst, and it is clearly out of nothing.
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Jin, J. and Bao, W. (2017) Study on the Mechanism of Heterogeneous Catalysis (1) —The Measurement of Equilibrium Pressure of Reaction BaCO
3 + C = BaO + 2CO, the Chemical States of Fe in Reaction Tank, and Chemical Reaction Model Catalytic Cycle Mechanism (CRMM).
Journal of Materials Science and Chemical Engineering,
5, 90-100. doi:
10.4236/msce.2017.57010.