Author(s)

Drissa Ouattara Kra¹, Grah Patrick Atheba^1,2*, N’da Arsène Kouadio³, Patrick Drogui², Albert Trokourey¹

¹Laboratoire de Chimie Physique, Université Félix Houphouët Boigny de Cocody-Abidjan, Abidjan, Côte d’Ivoire.
²Institut National de la Recherche Scientifique (INRS-ETE), Université du Québec, Quebec City, Canada.
³Laboratoire de Bioénergie, Centre National de Recherche Agronomique (CNRA), Abidjan, Côte d’Ivoire.

The objective of this study is to develop carbon, that of Acacia auriculeaformis through its activation in order to eliminate lead in an aqueous medium. A series of activated carbon has been prepared by chemical activation with phosphoric acid, sodium hydroxide and sodium chloride. The determination of the physico-chemical properties of the prepared carbon guided the choice of phosphoric acid activated carbon as the best adsorbent for the elimination of lead(II) in an aqueous solution. Pb²⁺ adsorption tests in batch mode have shown that the adsorption capacity is influenced by various parameters such as mass, pH, concentration of Pb²⁺ ions and contact time linked to the medium and the adsorbent. Adsorption isotherms, kinetic models and thermodynamics have been used to describe the adsorption process. The equilibrium data for activated charcoal correspond well to the model of Freundlich, Langmuir, Temkin and Kiselev. The kinetic adsorption data proved to be better described by the pseudo-second order model with external and intraparticle diffusion which are two decisive steps in the adsorption process of Pb²⁺ ions. Thermodynamics and adsorption isotherms predict a spontaneous exothermic surface reaction, of the chemisorption type, with ion retention in orderly monolayers on the heterogeneous surface of the adsorbent. Tests carried out with this adsorbent material have contributed to the elimination of the Pb²⁺ ions contained in an industrial effluent with a reduction rate reaching 42.52% against 85.90% in a synthetic solution.

Acacia auriculeaformis, Activated Carbon, Lead(II) Ion, Adsorption Isotherms, Kinetics

Kra, D. , Atheba, G. , Kouadio, N. , Drogui, P. and Trokourey, A. (2021) Activated Carbon Based on Acacia Wood (Auriculeaformis, Côte d’Ivoire) and Application to the Environment through the Elimination of Pb²⁺ Ions in Industrial Effluents. Journal of Encapsulation and Adsorption Sciences, 11, 18-43. doi: 10.4236/jeas.2021.111002.