This paper studies radiation from circumferential slots on cylindrical waveguide by Poynting’s vector method. It can help us to find mutual admittance between two circumferential slots in an antenna array. The main advantage of Poynting’s vector method is its accurate convergence to compute mutual admittance between two circumferential slots. The importance of this matter will be more salient while we want to compare it with other mutual admittances and also use it to optimize an antenna array.