Effects of Alkaline Additives on the Thermal Behavior and Properties of Cameroonian Poorly Fluxing Clay Ceramics ()
1. Introduction
In nature, clayey material is commonly composed of one or more clay minerals associated to non-clay minerals such as quartz, goethite, calcite, feldspars, organic matter, etc. On firing, clayey material undergoes many physico-chemical transformations which lead to common ceramics such as bricks, floor and roofing tiles, etc. Depending on both the chemical and mineralogical composition of clayey material, temperatures necessary to mature ceramic products whose characteristics must correspond to recommended norms can be more or less high [1] . For clayey material rich both in alkaline and iron oxides, the microstructure is highly modified at moderate temperature and ceramics with good characteristics can be obtained because vitrification generally appears between 900˚C and 1100˚C [2] [3] . On the contrary, the maturing temperature of ceramics of clayey material rich in iron oxides and poor in alkaline oxides is high [4] - [6] . In order to remedy the latter, an alternative can consist of making mixtures of both clayey material and additives rich in alkaline oxides [7] - [9] . Though the ceramic formation often involves solid-solid diffusion, the role of fluxes is to promote the formation of an amorphous phase that will act as a phase formation promoter, a binder and a glass. Its residual liquid fraction is converted into a vitreous compound when cooled. Among fluxes commonly used, sodium and potassium feldspars are of better choice [10] . Syenite is a flux that is generally used in the composition of many ceramic products such as sanitary, table and electric porcelains [11] . Nepheline syenite whose content in K2O + Na2O is generally higher than 14% and does not contain quartz has a melting point lower than that of potassium feldspar. These two latter fluxes are abundantly present on the Cameroonian territory [12] [13] .
Cameroon possesses an important potential of raw materials that can be used for the production of ceramics [14] . However, their value is still homemade and the products manufactured are essentially bricks, roofing tiles and pottery products [14] . The main company that produced ceramics in Cameroon (Céramiques Industrielles du Cameroun), mostly producing floor and wall tiles and certain type of plates existed only from 1976 to 1983. Several factors were responsible for this and among them a poor mastery of the clay-based raw material (Bomkoul clays). Today, business ventures contracted between Cameroonian, Chinese and Italian business men are being revised so as to solidify this activity.
In many localities of Sub-Saharan Africa and elsewhere around the world, chemical analysis of kaolinite clays indicates presence of high percentage of iron oxides and low percentage of alkaline oxides [6] [15] - [17] . During the making of common ceramics such as bricks, floor or roofing tiles from such clays, certain researchers elaborate mixtures whose compositions contain low waste materials as additive [18] - [20] .
The large clay deposit of Bomkoul is composed of two types of materials: red clay referenced as B1 and grey clay labeled as B2. B1 is rich in iron oxides but poor in alkaline oxides [21] . Up to 1982’s, a local industrial company in Cameroon used the Bomkoul clays for manufacturing ceramics. An anonymous document reports that the B1 clay was particularly used to produce floor and wall tiles. However, in spite of experimented mixtures that were done between B1 and additives to make satisfactory products, the quality of resulting ceramics was poor. A former study carried out on the properties of fired products of these clayey materials showed that ceramics from B1 are red but maturity temperature of its products is relatively high compared to those from B2 [3] . The aim of the present work is to set up conditions to lower maturity temperature of kaolinite clays which contain high amount of iron oxides and low amount of alkaline oxides. For this purpose, mixtures were made up using B1 clayey material and additives, respectively ball clay (B2 from the Bomkoul clay deposit), syenite and nepheline syenite. The thermal behavior of different mixtures was followed up via Young modulus versus temperature (20˚C to 1300˚C) while characteristics such as linear shrinkage, water absorption, bulk density, flexural strength, microstructure and crystalline phases of fired products were determined as a function of percentage of additive and temperature (1000˚C - 1200˚C).
2. Materials and Geological Settings
The Bomkoul clay deposit is located in the east of the sub-basin of Douala between longitudes 4˚05' and 4˚06' North and latitudes 9˚47' and 9˚50' East [21] . It is part of the Matanda formation since the Eocene-Paleocene era and is made up predominantly of deltaic deposits (Figure 1). This clay deposit extends over an area of 12 km2 and consists in two clay layers: one of which is red (1.5 to 3 m average depth) and the other gray (3 to 12 m average depth) [22] . The red clay referenced as B1 is plastic and its maturity temperature intended to terra cotta is around 1200˚C [3] . The gray clay referenced as B2 is a ball clay and the maturity temperature of its fired products is lower than 1150˚C [3] . Table 1 and Figure 2 give the chemical and the mineralogical compositions of
Figure 1. Geological sketch of the areas and locations where the samples were collected [22] -[24] .
Table 1. Chemical composition of the clays and the fluxes expressed as wt% oxides. (N.D. = Not Detected).
Figure 2. XRD patters of the clays (B1 and B2) and the fluxes (SL and SK).
these clayey materials. The Eboundja syenite massive occurs in the form of lens (Figure 1) which extends over a distance of close to 40 km. This massive is partially covered up and its visible part which contains nepheline syenite (denoted as SK) occupies an area of less than 20 km2 [23] . The Koupé massif includes the Lala village and is located between latitudes 4˚43' and 4˚52' North and longitudes 9˚40' and 9˚47' East. The massif has an elliptical shape with a maximum length of 11 km by a breadth of 8.5 km (Figure 1). This massif is made up of syenite rock, gabbroic rocks and basalt. The syenite rock denoted as SL covers a surface area close to 32 km2 [24] . Table 1 and Figure 2 show the chemical and the mineralogical compositions of SL and SK.
3. Experimental Methods
Elaborated mixtures were of three types: red clay B1-grey clay B2 (B1-B2), red clay B1-syenite SL (B1-SL) and red clay B1-nepheline syenite SK (B1-SK). The weight compositions of B1-B2, B1-SL and B1-SK are given respectively in Table 2. Powders of the materials were sieved through sieves of 125 µm (clays) and 80 µm (fluxes) , well mixed in a mixer (M & O, model N50-G) for 15 min in accordance with the percentages of Table 2 and moistened with distilled water (5% - 7% of weight of dried material). The humidified materials were well mixed again for 10 min and later uniaxially pressed in a mold (SPECAC model) at 15 MPa. Test samples were made in accordance with the following characteristics: cylindrical form (height 6 mm; radius 10 mm) to examine densification parameters (linear shrinkage, water absorption, bulk density) and microstructure; parallelepiped form (80 mm × 40 mm × 7 mm ) to measure flexural strength and to determine crystalline phases. Samples used to follow up Young modulus as a function of temperature were parallelepiped ( 15 mm × 15 mm × 150 mm ). Before thermal treatment, all the samples were first dried at ambient temperature in the laboratory (20˚C - 26˚C) and later in an oven at 105˚C, respectively for 48 and 24 hours. Firing of the samples consisted of heating them between 1000˚C and 1200˚C for two hours, by increments of 50°C with a firing speed of 5˚C/min. After firing, the samples were allowed to cool in ambient temperature of the furnace (Nabertherm, Mod. LH 60/14). In order to ensure good handling, samples used to follow up Young modulus as a function of temperature were preheated at 900˚C for two hours with a firing ramp of 5˚C/min in the electric temperature-programmed furnace. Young modulus as a function of temperature was examined using the ultrasonic technique known as “Long bare mode” [25] . Physical characteristics of the ceramics (linear shrinkage, water absorption, bulk density) were determined according to the NF-P 18-554 standard [26] whereas flexural strength was measured in accordance with the EN- 100 standard [27] . Microstructure of the ceramics was determined via Scanning Electron Microscope by using a Hitachi S-2500. Crystalline phases which appeared within ceramics were determined by X-ray powder diffraction using a Philips PW 1710 diffractometer equipped with an automatic slit window operating by reflexion of kα1 radiation under the following conditions: 30 kV/50 mA, 400 cps sensitivity, angular sweep range 6˚ < 2θ < 70˚ Quantitative comparison of amount of quartz, mullite and cristobalite contained in the products as a function of temperature and percentage of additive was achieved. For each of the preceding crystalline phases, variations of relative intensity (expressed as percentage) of selected peak were followed up via diffractograms. The selected peaks were as follow: 2θ = 20.84˚ (dhhl = 4.26 Å) for quartz; 2θ = 16.46˚ (dhkl = 5.38 Å) for mullite; 2θ = 21.92˚ (dhkl = 4.07 Å) for cristobalite.
4. Results and Discussion
4.1. Mineralogical Composition of the Ceramics
The X-ray diffraction analyses were focused on the mixtures treated at 1000˚C, 1100˚C and 1200˚C for: G10 and G50 (B1-B2); SL5, SL15 and SL25 (B1-SL); SK5, SK15 and SK25 (B1-SK). Quantitative comparison of amount of quartz, mullite and cristobalite contained in the mixtures as a function of temperature and percentage of additive was achieved and the results are shown in Figure 6. An examination of the X-ray diffractograms (Figures 3-5) revealed:
For B1-B2 ceramics, crystalline phases are shown in Figure 3. The amount of quartz in the products does not vary appreciably (Figure 6(a)) and kaolinite is transformed into mullite and cristobalite. These neo-crystalline phases are present from 1100˚C in G50 to 1200˚C in G10 (Figure 6(b) and Figure 6(c)). Since the previous re-
Table 2. Weight composition of the mixtures of B1-B2, B1-SL and B1-SK expressed as wt%.
Figure 3. XRD patters of the fired mixtures of B1-B2 (Q: quartz; H: hematite; A: anatase; Fe: pseudorutile; M: mullite; C: cristobalite.
sults indicate that the ceramics of B1 fired up to 1100˚C contain neither mullite nor cristobalite [3] , it appears that mixing together B1 and B2 promotes the formation of these minerals in amounts which increase along with amount of additive (B2) (Figure 6(b) and Figure 6(c)). Hematite originates from the thermal decomposition of goethite (Figure 2 and Figure 3) while pseudorutile could results from chemical reaction between anatase and hematite [28] .
Figure 4. XRD patterns of the fired mixtures of B1-SL (H: hematite; Q: quartz; Fe: pseudorutile; A: anatase; Mi: microcline; Al; albite; M: mullite; C: cristobalite).
Figure 5. XRD patterns of the fired mixtures of B1-SK. (H: hematite; Q: quartz; Fe: pseudorutile; A: anatase; Al: albite; M: mullite; C: cristobalite).
Figure 6. Quantitative comparison of the amount of quartz, mullite and cristobalite contained in the mixtures as a function of temperature and percentage of additive.
Figure 4 shows crystalline phases of the ceramics of B1-SL. From 1100˚C, albite and microcline are not more present which indicates their transformation into vitreous phase. This is clearly expressed at 1200˚C (diffractograms of SL15 and SL25) by the appearance of a hump at 2θ between 17˚ and 28˚. There is a weak decrease of amount of quartz at 1200˚C (Figure 6(a)) while mullite and cristobalite are observed from 1100˚C in SL15 and SL25. However, increase of temperature leads to increase the amount of mullite and decrease the amount of cristobalite (Figure 6(b) and Figure 6(c)). At a same firing temperature, the amount of cristobalite is higher in SL15 than in SL25 (Figure 6(b)). It is well known that the presence of an abundant vitreous phase in aluminosilicate ceramics provokes the dissolution of cristobalite [29] which is in accordance with Figure 6(b). Hematite originates from the thermal decomposition of goethite while pseudorutile could result from the thermal reaction between anatase and hematite [28] .
In the ceramics of B1-SK, the crystalline phases observed are shown in Figure 5. Albite is not more present from 1100˚C which indicates its transformation into vitreous phase (hump at 2θ between 17˚ and 28˚ in the diffractograms of SK5-SK25). There is light decrease of the amount of quartz at 1200˚C (Figure 6(a)) probably because it has reacted with vitreous phase [7] . Mullite is observed from 1100˚C in the products of SK15-25 and its amount increases along with firing temperature (Figure 6(b)) while cristobalite is present at 1100˚C in SK15 and at 1100˚C and 1200˚C in SK5 (Figure 5 and Figure 6(c)). The absence of cristobalite in certain mixtures of B1- SK is expressed as its dissolution in an abundant vitreous phase [7] . Hematite originates from the thermal decomposition of goethite (Figure 2 and Figure 5) while pseudorutile may result from the reaction between anatase and hematite [28] .
4.2. Thermal Behavior of the Mixtures
The variation of Young modulus (YM) versus temperature is sensitive to phase and microstructure changes within materials [30] . Figure 7 shows data of YM as a function of temperature of the mixtures preheated at 900˚C. For the samples G10 and G50 of B1-B2, three domains are observed (Figure 7(a)). Above 334˚C, YM does
Figure 7. Data of Young modulus as a function of temperature for certain mixtures. ((a): B1-B2; (b): B1-SL; (c): B1-SK).
not vary appreciably since the microstructure of the products is governed by phases such as quartz, metakaolinite and hematite previously present in the mixtures (pre-sintering temperature), except at 575˚C where the polymorphism of quartz α into quartz β leads to a weak increase of YM. Between 1052˚C and 1200˚C there is a considerable increase of YM (+11.4 GPa) which is in accordance with the rearrangement of the network of metakaolinite followed by a significant sintering of the products [31] . In fact metakaolinite is transformed into spinel phase and amorphous silica [32] . Between 1184˚C and 1235˚C YM of G10 increases uniformly while that of G50 deflects first at 1184˚C and increases slightly later on. This difference is assigned to the mineralogical composition of their ceramics. In fact, Figure 3 indicates the presence of mullite and cristobalite as from 1100˚C in G50 against 1200˚C in G10. In the samples SL5 and SL15 of B1-SL, three domains are also observed (Figure 7(b)). Up to 1066˚C, YM does not vary appreciably as result of intrinsic properties of the phases such as quartz and metakaolinite and hematite previously present in the mixtures. However there is slight increase of YM at 575˚C as a result of the polymorphism of quartz α into quartz β. From 1066˚C to 1170˚C, YM undergoes considerable increase which indicates both rearrangement of the network of metakaolinite and the beginning of sintering [29] . Elsewhere, albite and microcline melt from 1100˚C (Figure 4) and bring about vitreous phase in the products. Thus YM increases since it is sensitive to the newly formed phases (spinel, amorphous silica and vitreous phase). However this increase begins at 1106˚C (sample SL5) against 1066˚C (sample SL15). This difference is assigned to the presence of more abundant amorphous phase in SL15 than in SL5. In fact before firing, the amount of flux (syenite SL) is greater in SL15 than in SL5. Consequently when SL melts down the amount of vitreous phase brought about is greater in the products of SL15 than in those of SL5. As result, the sintering temperature of SL15 is lower than that of SL5. Between 1177˚C and 1237˚C, there is a deflection on the curve of YM of SL15 at 1177˚C against 1237˚C on that of SL5 (Figure 7(b)). This difference is attributed to the mineralogical composition of their ceramics. In fact, the products of SL15 contain mullite and cristobalite from 1100˚C against 1200˚C in those of SL5 (Figure 4 and Figure 6(b) and Figure 6(c)). The curves of YM of the samples SK5, SK15 and SK25 show three domains each (Figure 7(c)). Up to 1038˚C C, YM is almost constant except at 575˚C (polymorphism of quartz α into quartz β). Between 1038˚C and 1129˚C, YM undergoes strong increase as result of concomitant effects of rearrangement of the network of metakaolinite and sintering of the products [29] . However the temperatures which correspond to the increase of YM are as follow: 1101˚C (SK5), 1058˚C (SK15) and 1038˚C (SK25), (Figure 7(c)). This behavior is the result of the presence of amorphous phase [29] within the ceramics and the more the amorphous phase is produced, the lower is the temperature at which the sintering begins. In fact the amount of flux in the mixtures increases from the sample SK5 to the sample SK25. Consequently, when the flux melts down, there is an increase of the amount of vitreous phase from the product of SK5 to that of SK25. From 1129˚C to 1250˚C, YM increases and in each curve, there is a deflection whose temperature decreases along with the amount of additive: 1231˚C (SK5), 1177˚C (SK15) and 1166˚C (SK25). On the other hand, mullite is observed from 1100˚C in all the products (Figure 5) and its amount increases from the product of SK5 to that of SK25 (Figure 6(b)). Hence the presence of deflection in the YM curves depends on the amount of mullite: the greater the amount of mullite the lower the temperature of appearance of deflection.
4.3. Microstructure of the Ceramics
The microstructure of fired products is presented by the SEM micrographs of Figure 8. In general, the mixtures fired at 1000˚C contain large blocks (fired clay aggregates) surrounded by granules (fired clay particles and non- transformed additive particles) of variable dimensions and the ceramics apparently manifest weak cohesion (Figure 8: micrographs a, b, e, f, i, j). In the samples of B1-B2 fired at 1000˚C, the higher the amount of additive (B2), the lower the particles surrounding fired clay aggregates (Figure 8: micrographs a and b). In fact B2 is ball clay [3] and the mixtures that contain it in great amount are more plastic which leads to low individual particle products. On the contrary, the samples of B1-B2 fired at 1200˚C are compact enough as result of good sintering but there are some cracks through some parts of the products (Figure 8: micrographs c and d) because of tensions due to the difference in thermal expansion coefficients between the amorphous phase (produced by minerals such as illite) and the crystalline phases (Figure 6(b): namely cristobalite and mullite). For the products of B1-SL and B1-SK fired at 1000˚C, mixtures with great amount of additive contain more granules (fired clay particles and non-transformed additive particles) than fired clay aggregates (Figure 8: micrographs f and j in comparison with micrographs e and i) because the fluxes (SL and SK) have not yet melt down. The mixtures fired at 1200˚C are compact enough as a result of great amount of amorphous phase which fills pores and connects particles. However, the ceramics of B1-SL (Figure 8: micrographs g and h) exhibit more cracks and pores than
Figure 8. Micrographs of the fired mixtures of B1-B2; B1-SL and B1-SK.((a): G10: 1000˚C; (b): G50: 1000˚C; (c): G10: 1200˚C; (d): G50: 1200˚C; (e): SL5: 1000˚C; (f): SL25: 1000˚C; (g): SL5: 1200˚C; (h): SL25: 1200˚C; (i): SK5: 1000˚C; (j): SK25: 1000˚C; (k): SK5: 1200˚C; (l): SK25: 1200˚C).
those of B1-SK (Figure 8: micrographs k and l) which presumably results from the fact that the amorphous phase produced by SK (nepheline syenite) is more wetting than the one produced by SL (syenite) [30] . This allows amorphous phase produced by SK to connect better the particles. On the contrary, the amorphous phase produced by SL is more viscous and generates cracks during the cooling. This results from the difference between the thermal expansion coefficients of the rigid amorphous phase and the crystalline particles (quartz, mullite and cristobalite).
4.4. Physical and Mechanical Properties of the Ceramics
Data of physical and mechanical characteristics of the ceramics as a function of the amount of additive and temperature are shown in Figures 9-11. In the ceramics of B1-B2, linear shrinkage increases along with temperature and amount of additive (B2), except for G10 respectively at 1150˚C and 1200˚C and for G40 and G50 at 1200˚C (Figure 9(a)). This increase indicates of the level of physico-chemical transformations that take place in the materials [31] . However at 1150˚C and 1200˚C, the values of linear shrinkage of G10 are slightly lower than those of G0 since the mineralogical composition of their mixtures differs notably (G0 contains no additive). By contrast, the mixtures of G10-30 have the same mineralogical composition and their linear shrinkage increase slightly along with additive (B2) until the amount of cristobalite reaches a high level (Figure 6(c)). The presence of high amount of cristobalite in aluminosilicate ceramics generally generates the bloating of products [4] [25] . Thus the presence of great amount of cristobalite in the products of G40-50 explains the decrease of linear shrinkage at 1200˚C (Figure 6(c) and Figure 9(a)). Increasing the temperature leads to decrease the water absorption and increase the bulk density (Figure 9(b) and Figure 9(c)). This is a result of sintering which is promoted
Figure 9. Physical and flexural strength of ceramics of the mixtures of B1-B2 as a function of amount of additive (B2) and temperature. ((a): linear shrinkage; (b): water absorption; (c): bulk density; (e): flexural strength).
Figure 10. Physical and flexural strength of ceramics of the mixtures of B1-SL as a function of amount of additive (SL) and temperature. ((a): linear shrinkage; (b): water absorption; (c): bulk density; (d): flexural strength).
Figure 11. Physical and flexural strength of ceramics of the mixtures B1-SK as a function of amount of additive (SK) and of temperature. ((a): linear shrinkage; (b): water absorption; (c): bulk density; (d): flexural strength).
within the products of B1-B2 by the amorphous phase brought about by minerals such as illite (Figure 2) [32] . However the disruption observed in G40 and G50 at 1200˚C (Figure 9(c)) is a result of bloating within their ceramics via the presence of a high amount of cristobalite (Figure 6(c)). The overall physical characteristics (linear shrinkage, water absorption, bulk density) and increase of amount of mullite and cristobalite within the ceramics of B1-B2 (Figure 6(b) and Figure 6(c)) are in accordance with the increase of flexural strength (Figure 9(d)). In fact, increasing the sintering and amounts of mullite and cristobalite in aluminosilicate ceramics lead to the increase of mechanical strength [33] . However, it is interesting to mention the positive effect brought about by the mixtures obtained with 20% B2 and 80% B1 and firing between 1100˚C and 1150˚C to get ceramics whose flexural strengths is of class 20 to 35 in the NC-2 Standard of the Cameroonian Norm [34] . Such products are comparable with those obtained with the clays of Bakong which are rich both in iron oxides and alkaline oxides [35] . Nonetheless the values of flexural strength of B1-B2 products do not attain 18 MPa because of cracks resulting from the difference in thermal expansion coefficients between amorphous phase (produced by minerals such as illite) and neo-crystalline phases that go through many parts of their microstructures (Figure 8: micrographs c and d). With respect to the ceramics of B1-SL and B1-SK, linear shrinkage increases along with temperature and amount of additive (Figure 10(a) and Figure 11(a)) except in the mixtures of SL5-15 and SK5 and SK20-25 respectively at 1100˚C, 1150˚C and 1200˚C. There is a disruption between the value of linear shrinkage of SL0 and SK0 in comparison with those of SL5-25 and SK5-25 which is a result of their mineralogical compositions (Figure 2 and Figure 3). As for the decrease of linear shrinkage in the products of SK20-25 (Figure 11(a)), it is well known that nepheline syenite does not contain quartz, hence firing the preceding samples at 1150 or 1200˚C leads to the production of an abundant fluid amorphous phase which promotes bloating of the products [36] . The decrease of water absorption (Figure 10(b) and Figure 11(b)) and the increase of bulk density (Figure 10(c) and Figure 11(c)) along with the percentage of additive (SL or SK) and temperature are in agreement with the production of an increasing amount of amorphous phase. On the other hand, the amorphous phase produced by SK (nepheline syenite) is less viscous than that one produced by SL (syenite).Therefore, fluid amorphous phase allows for better diffusion through the network of the materials which leads to more compact products. Hence between 1100˚C and 1200˚C, the ceramics of B1-SK exhibit lower water absorption values than those of B1-SL (Figure 10(c) and Figure 11(c)). The decrease of bulk density in the products of SK20-25 at 1200˚C (Figure 11(c)) is in accordance with the presence of a fluid amorphous phase that promotes bloating of the products. Flexural strength as a function of additive (Figure 10(d) and Figure 11(d)) increases along with firing temperature and amount of additive. This is a result of appearance of both mullite and cristobalite (Figure 4 and Figure 5) and the formation of an increasing amount of amorphous phase which promotes good sintering of the products. On the other hand, there is a gap between the values of flexural strength obtained at 1150˚C - 1200˚C and those obtained at 1000˚C - 1100˚C. This is as a result of better sintering of the ceramics produced between 1150˚C and 1200˚C. In fact, around 1150˚C much amorphous phase resulting from the melting down of additives (SL and SK) is produced [10] [11] . However, when using the same amount of additive and firing at the same temperature, the ceramics of B1-SK exhibit higher flexural strengths than those of B1-SL (Figure 10(d) and Figure 11(d)) which is attributed to the fact that the amorphous phase produced by SK is less viscous than that the one produced by SL.
5. Conclusions
The thermal behavior and certain characteristics of ceramics produced from mixtures of red clay (rich in iron oxides but poor in fluxing oxides) and additives (ball clay, nepheline syenite and syenite) show that:
In the ceramics of mixtures of red clay-ball clay, the amount of mullite or cristobalite increases along with temperature and amount of additive. Additionally, Young modulus variation indicates that the temperature at which an important densification of the products begins, reduces slightly with the increasing amount of additive. The mixtures made up of 20% B2 and 80% B1 and fired between 1100˚C and 1150˚C give ceramics with flexural strength of class between 20 and 35 in the NC-2 Standard of the Cameroonian Norm.
In the mixtures of red clay-alkaline additive, contrary to mullite, the amount of cristobalite decreases along with the amount of additive and fired temperature. Also, Young modulus variations show that the temperature at which there is an important sintering of the mixtures drops with increasing amount of additive. The ceramics whose mixtures contain up to 15% alkaline feldspar could be destined to terra cotta when fired between 1050˚C and 1100˚C. In the mixtures where the amount of alkaline additive goes up to 25%, the products obtained around 1200˚C can be destined to low water absorption ceramics (0.70% to 0.25%). When using the same amount of alkaline additive and firing at the same temperature, the products which result from nepheline syenite are denser than those from syenite. That results from the fact that the amorphous phase produced by nepheline syenite is more wetting than that the one produced by syenite. Ball clay or alkaline feldspars produce an efficient fluxing effect when mixed with kaolinite clay containing great amount of iron oxides and low fluxing oxides.
Acknowledgements
The authors wish to acknowledge the Director of Ecole Nationale Supérieure de Céramique Industrielle (Limoges, France) for the laboratory facilities and the authorities of the University of Yaoundé I for the financial support of this research work.
NOTES
*Corresponding author.