Electrochemical Corrosion Behavior of Aluminum in Perchloric Acid


The effects of acetate, citrate, benzoate, tetra-ethylammonium iodide (TEA) and 1,4,8,11 tetra-azacyclo-tetradecane (cyclam) on the corrosion behavior of aluminum in 1 M HClO4 at 40°C were studied by potentiodynamic polarization technique. Acetate, citrate, and benzoate inhibited the corrosion of aluminum and shifted the breakdown potential to positive direction. Cyclam was investigated as a macrocyclic organic inhibitor to the acid corrosion of aluminum. The addition of cyclam to the corroding medium showed a pronounced effect on the anodic but not on the cathodic part of the polarization curve. The addition of TEA to the medium enhanced the corrosion rate and shifted the breakdown potential to more negative value as the concentration increased. The results were discussed on the basis of the adsorption mechanism and the nature of the adsorbed species.

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F. Mahgoub, "Electrochemical Corrosion Behavior of Aluminum in Perchloric Acid," Open Journal of Physical Chemistry, Vol. 3 No. 4, 2013, pp. 177-188. doi: 10.4236/ojpc.2013.34022.

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The authors declare no conflicts of interest.


[1] F. M. Al-Kharafi and W. A. Badawy, “Corrosion and Passivation of Al and Al-Si Alloys in Nitric Acid Solutions II—Effect of Chloride Ions,” Electrochimica Acta, Vol. 40, No. 12, 1995, pp. 1811-1817. http://dx.doi.org/10.1016/0013-4686(95)00091-R
[2] O. Benali, L. Larabi and Y. J. Harek, “Adsorption and Inhibitive Corrosion Properties of Thiourea Derivatives on Cold Rolled Steel in 1M HClO4 Solutions,” Applied Electrochemistry, Vol. 39, 2009, p. 769.
[3] R. Vidal and A. C. West, “Aluminum and Aluminum Alloy Dissolution in Concentrated Phosphoric Acid,” Journal of The Electrochemical Society, Vol. 145, No. 12, 1998, pp. 4067-4073. http://dx.doi.org/ 10.1149/1.1838916
[4] L. Garrigues, N. Pebere and F. Dabosi, “An Investigation of the Corrosion Inhibition of Pure Aluminum in Neutral and Acidic Chloride Solutions,” Electrochimica Acta, Vol. 41, No. 7-8, 1996, pp. 1209-1215. http://dx.doi.org/10.1016/0013-4686(95)00472-6
[5] E. Stupnisek, K. Berkovic-Salajster and J. Vorkapic-Furac, “An Investigation of the Efficiency of Several Organic Descaling Inhibitors,” Corrosion Science, Vol. 28, No. 12, 1988, p. 1189. http://dx.doi.org/ 10.1016/0010-938X(88)90128-X
[6] G. Lyberatos and L. Kobotiatis, “Inhibition of Aluminum 7075 Alloy Corrosion by the Concerted Action of Nitrate and Oxalate Salts,” Corrosion, Vol. 47, No. 11, 1991, pp. 820-824. http://dx.doi.org/ 10.5006/1.3585856
[7] T. H. Ngugen and R. T. Foley, “The Chemical Nature of Aluminum Corrosion,” Journal of the Electrochemical Society, Vol. 127, No. 12, 1980, pp. 2563-2566. http://dx.doi.org/10.1149/1.2129520
[8] R. T. Foley and T. H. Ngugen, “The Chemical Nature of Aluminum Corrosion,” Journal of the Electrochemical Society, Vol. 129, No. 3, 1982, pp. 464-467. http://dx.doi.org/10.1149/1.2123881
[9] A. A. El-Awady, B. A. Abd-El-Nabey and S. G. Aziz, “Thermodynamic and Kinetic Factors in Chloride Ion Pitting and Nitrogen Donor Ligands Inhibition of Aluminium Metal Corrosion in Aggressive Acid Media,” Journal of the Chemical Society, Faraday Transactions, Vol. 89, 1993, pp. 795-802.
[10] S. G. Aziz, A. A. El-Awady and B. A. Abd-El-Nabey, “Studies on the Kinetics of Aluminium Metal Dissolution in Aggressive Acid Media Containing Inorganic Anions,” JKAU, Vol. 9, 1997, p. 101. http://dx.doi.org/10.4197/Sci.9-1.10
[11] G. A. El-Mahdy and S. S. Mahmoud, “Inhibition of Acid Corrosion of Pure Aluminum with 5-Benzylidine-1-methythiolmidazole-4-one,” Corrosion, Vol. 51, No. 6, 1995, pp. 436-440. http://dx.doi.org/ 10.5006/1.3293609
[12] E. Kamis and M. Alea, “Inhibition of Acid Corrosion of Aluminum by Triazoline Derivatives,” Corrosion, Vol. 50, No. 2, 1994, pp. 106-152. http://dx.doi.org/10.5006/1.3293498
[13] M. Metikos, Z. Grubac and E. Stupnisek, “Organic Corrosion Inhibitors for Aluminum in Perchloric Acid,” Corrosion, Vol. 50, No. 2, 1994, pp. 146-151. http://dx.doi.org/10.5006/1.3293503
[14] N. Khalil, F. Mahgoub, B. A. Abd-El-Nabey and A. Abd-El-Aziz, “Corrosion of Aluminum in Perchloric Acid in Presence of Various Inorganic Additives,” Corrosion Engineering, Science and Technology, Vol. 38, No. 3, 2003, pp. 205-210.
[15] ASTM, “Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements,” Annual Book of ASTM Standards, Vol. 3, No. 2, 1995, in press.
[16] ASTM, “Standard Practice for Preparing, Cleaning and Evaluating Corrosion Test Specimens,” Annual Book of ASTM Standards, Vol. 3, No. 2, 2001, in press.
[17] J. C. Scully and W. J. Rudd, “The Role of Corrosion Product in the Inhibition of Pitting Corrosion on Aluminum,” Corrosion, NACE, Huston, 1979.
[18] P. N. S. Yadav, A. K. Sgn and R. Wadhwani, “Roll of Hydroxyl Group in the Inhibition Action of Benzoic Acid toward Corrosion of Aluminum in Nitric Acid,” Corrosion, Vol. 55, No. 10, 1999, pp. 937-941. http://dx.doi.org/10.5006/1.3283929
[19] L. Kobotiatis, C. Tsikrikas and P. G. Koutsoukos, “Enhanced Pitting Corrosion Resistance of Aluminum Alloy 7075 in the Presence of Oxalate Anions,” Corrosion, Vol. 51, No. 1, 1995, pp. 19-29.
[20] B. Al-Anadoul, F. Eltaib, F, Elnizami and B. Ateva, “Extended Abstract of the Electrochemical Society Fall Meting,” The Electrochemical Society, Chicago, 1988, p. 188.
[21] I. Langmuir, “The Constitution and Fundamental Properties of Solids and Liquids. Part I. Solids, ” Journal of the American Chemical Society, Vol. 38, No. 11, 1916, pp. 2221-2295. http://dx.doi.org/ 10.1021/ja02268a002
[22] B. A. Abd El-Naby, E. Khamis, M. Ramadan and A. El Gandy, “Application of the Kinetic Thermodynamic Model for Inhibition of Acid Corrosion of Steel by Inhibitors Containing Sulphur and Nitrogen,” Corrosion, Vol. 52, No. 9, 1996, pp. 671-679. http://dx.doi.org/10.5006/1.3292157
[23] A. A. El-Awady, B. A. Abd El-Naby and G. Aziz, “Kinetic Thermodynamic and Adsorption Isotherm Analysis for the Inhibition of Acid Corrosion of Steel by Cyclic and Open Chain Amines,” Journal of the Electrochemical Society, Vol. 139, No. 8, 1992, pp. 2149-2154. http://dx.doi.org/10.1149/1.2221193
[24] P. J. Florry, “Thermodynamics of High Polymer Solutions,” The Journal of Chemical Physics, Vol. 10, No. 1, 1942, p. 51. http://dx.doi.org/10.1063/1.1723621
[25] A. M. Abdel-Gaber, B. A. Abd-El Nabey, I. M. Sid Ahmed, A. M. El-Zayady and M. Saadawy, “Kinetics and Thermodynamics of Aluminum Dissolution in 1.0 M Sulphuric Acid Containing Chloride Ions,” Materials Chemistry and Physics, Vol. 98, No. 2-3, 2006, pp. 291-297. http://dx.doi.org/10.1016/j. matchemphys.2005.09.023

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