Mathematical Modeling of the Actual Infiltration Process for the Preparation of C/C Composites

Abstract

The mathematical modeling for the preparation of C/C composites from propane by F-CVI (Forced-flow Chemical Vapor Infiltration) was studied. The modeling for the actual processes including overturning the preform in the middle of the deposition process was carried out. Effects of the interval and the number of overturning processes on the time changes of porosity distribution were observed. The actual deposition process could be continued longer by overturning the preform. Furthermore, the total amount of deposition increased twice when several times of overturning were applied. It was confirmed that a low concentration and a slow reaction rate are necessary for a uniform infiltration even when the preform is overturned in the middle of the process.

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G. Chung, D. Hwang and S. Hong, "Mathematical Modeling of the Actual Infiltration Process for the Preparation of C/C Composites," Engineering, Vol. 4 No. 12A, 2012, pp. 921-927. doi: 10.4236/eng.2012.412A117.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] W. Zhang and K. J. Hüttinger, “Simulation Studies on Chemical Vapor Infiltration of Carbon,” Composites Science and Technology, Vol. 62, No. 15, 2002, pp. 19471955. doi:10.1016/S0266-3538(02)00128-8
[2] M. K. Kim and G. Y. Chung, “Computer Simulation of the Preparation of C/SiC Composites in the F-CVI Reactor,” Resources Processing, Vol. 54, 2007, pp. 25-28. doi:10.4144/rpsj.54.25
[3] G. Y. Chung, B. J. McCoy, J. M. Smith and D. E. Cagliostro, “Chemical Vapor Infiltration: Dispersed Graded Depositions for Ceramic Composites,” AIChE Journal, Vol. 39, No. 11, 1993, pp. 1834-1846. doi:10.1002/aic.690391111
[4] M. Frenklach and H. Wang, “Detailed Surface and GasPhase Chemical Kinetics of Diamond Deposition,” Physical Review B, Vol. 43, 1991, pp. 1520-1545. doi:10.1103/PhysRevB.43.1520
[5] M. Okkerse, M. de Croon, C. R. Kleijn, H. van den Akker and G. B. Marin, “A Surface and a Gas-Phase Mechanism for the Description of Growth on the Diamond (100) Surface in an Oxy-Acetylene Torch Reactor,” Journal of Applied Physics, Vol. 84, 1998, pp. 6387-6398. doi:10.1063/1.368965
[6] R. Lacroix, R. Fournet, I. Ziegler-Devin and P. M. Marquaire, “Kinetic Modeling of Surface Reactions Involved in CVI of Pyrocarbon Obtained by Propane Pyrolysis,” Carbon, Vol. 48, 2010, pp. 132-144. doi:10.1016/j.carbon.2009.08.041
[7] I. Ziegler, R. Fournet and P. M. Marquaire, “Influence of Surface on Chemical Kinetic of Pyrocarbon Deposition Obtained by Propane Pyrolysis,” Journal of Analytical and Applied Pyrolysis, Vol. 73, No. 1, 2005, pp. 107-115. doi:10.1016/j.jaap.2004.12.004
[8] I. Ziegler, R. Fournet and P. M. Marquaire, “Pyrolysis of Propane for CVI of Pyrocarbon: Part Ⅲ: Experimental and Modeling Study of the Formation of Pyrocarbon,” Journal of Analytical and Applied Pyrolysis, Vol. 79, 2007, pp. 268-277.
[9] A. Becker and K. J. Huttinger, “Chemistry and Kinetics of Chemical Vapor Deposition of Pyrocarbon-Ⅱ Pyrocarbon Deposition from Ethylene, Acetylene and 1,3-Butadiene in the Low Temperature,” Carbon, Vol. 36, 1998, pp. 177-199.
[10] G. L. Vignoles, C. Gaborieau, S. Delettrez, G. Chollon and F. Langlais, “Reinforced Carbon Foams Prepared by Chemical Vapor Infiltration: A Process Modeling Approach,” Surface and Coatings Technology, Vol. 203, 2008, pp. 510-515. doi:10.1016/j.surfcoat.2008.04.065
[11] A. Li, K. Norinaga, W. Zhang and O. Deutschmann, “Modeling and Simulation of Materials Synthesis: Chemical Vapor Deposition and Infiltration of Pyrolytic Carbon,” Composites Science and Technology, Vol. 68, 2008, pp. 1097-1104. doi:10.1016/j.compscitech.2007.07.007
[12] G. Y. Chung, B. J. McCoy, J. M. Smith and D. E. Cagliostro, “Chemical Vapor Infiltration: Modeling Solid Matrix Deposition for Ceramic Composites Reinforced with Layered Woven Fabrics,” Chemical Engineering Science, Vol. 47, 1992, pp. 311-323. doi:10.1016/0009-2509(92)80022-5
[13] J. Ibrahim and S. Paulucci, “Transient Solution of Chemical Vapor Infiltration/Deposition in a Reactor,” Carbon, Vol. 49, 2011, pp. 915-930. doi:10.1016/j.carbon.2010.11.002
[14] S. Vaidyaraman, W. J. Lackey and P. K. Agrawal, “Carbon/ Carbon Processing by Forced Flow-Thermal Gradient Chemical Vapor Infiltration (FCVI) Using Propane,” Carbon, Vol. 34, 1996, pp. 609-617. doi:10.1016/0008-6223(95)00191-3
[15] D. G. Hwang and G. Y. Chung, “Modeling Studies on the Effects of the Process Parameters in Forced-Flow Chemical Vapor Infiltration Reactor for the Preparation of C/C Composites,” Korean Journal of Chemical Engineering, Vol. 29, 2012, pp. 1266-1271. doi:10.1007/s11814-011-0303-2
[16] D. G. Hwang and G. Y. Chung, “Studies on the Effects of the Concentration in the Preparation of C/C Composites by the CVI Process of Propane,” Industrial & Engineering Chemistry Research, Vol. 18, 2012, pp. 1136-1140. doi:10.1016/j.jiec.2012.01.016

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