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Measuring Conditions for the Determination of Lead in Iron-Matrix Samples Using Graphite Atomizers with/without a Platform in Graphite Furnace Atomic Absorption Spectrometry

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DOI: 10.4236/ajac.2011.26081    4,426 Downloads   7,597 Views   Citations


In graphite furnace atomic absorption spectrometry (GF-AAS), the atomization process of lead occurring in graphite atomizers with/without a platform plate was investigated when palladium was added to an iron-matrix sample solution containing trace amounts of lead. Absorption profiles of a lead line were meas- ured at various compositions of iron and palladium. Variations in the gas temperature were also estimated with the progress of atomization, by using a two-line method under the assumption of a Boltzmann distribu- tion. Each addition of iron and palladium increased the lead absorbance in both the atomizers, indicating that iron or palladium became an effective matrix modifier for the determination of lead. Especially, palladium played a significant role for controlling chemical species of lead at the charring stage in the platform-type atomizer, to change several chemical species to a single species and eventually to yield a dominant peak of the lead absorbance at the atomizing stage. Furthermore, the addition of palladium delayed the peak after the gas atmosphere in the atomizer was heated to a higher temperature. These phenomena would be because the temperature of the platform at the charring stage was elevated more slowly compared to that of the furnace wall, and also because a thermally-stable compound, such as a palladium-lead solid solution, was produced by their metallurgical reaction during heating of the charring stage. A platform-type atomizer with palladium as the matrix modifier is recommended for the determination of lead in GF-AAS. The optimum condition for this was obtained in a coexistence of 1.0 × 10–2 g/dm3 palladium, when the charring at 973 K and then the atomizing at 3073 K were conducted.

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S. Morimoto, T. Ashino and K. Wagatsuma, "Measuring Conditions for the Determination of Lead in Iron-Matrix Samples Using Graphite Atomizers with/without a Platform in Graphite Furnace Atomic Absorption Spectrometry," American Journal of Analytical Chemistry, Vol. 2 No. 6, 2011, pp. 710-717. doi: 10.4236/ajac.2011.26081.


[1] L. Savov, E. Volkova and D. Janke, “Copper and Tin in Steel Scrap Recycling,” Materials Geoenvironment, Vol. 50, No. 3, 2003, pp. 627-640.
[2] K. Kunishige and M. Hatano, “Surface Hot-Shortness of Steels Induced by a Small Amount of Copper and Tin from Scrap Steels and Its Suppression Methods,” Mate- rial Science Forum, Vol. 539-543, 2007, pp. 4113-4118. doi:10.4028/0-87849-428-6.4113
[3] J. A. Broekaert, “Analytical Atomic Spectrometry with Flames and Plasmas,” Wiley-VCH Verlag, Weinheim, 2002, pp. 146-171.
[4] F. Betts and A. Yau, “Graphite-Furnace Atomic-Absorp- tion Spectrometric Determination of Chromium, Nickel, Cobalt, Molybdenum, and Manganese in Tissues Con- taining Particles of a Cobalt Chrome Alloy,” Analytical Chemistry, Vol. 61, No. 11, 1989, pp. 1235-1238. doi:10.1021/ac00186a012
[5] T. Ashino, K. Takada and K. Hirokawa, “Determination of Trace Amounts of Selenium and Tellurium in High-Purity Iron by Electrothermal Atomic-Absorption Spectrometry after Reductive Coprecipitation with Pal- ladium Using Ascorbic-Acid,” Analytical Chimica Acta, Vol. 297, No. 3, 1994, pp. 443-451. doi:10.1016/0003-2670(94)00226-6
[6] T. Itagaki, T. Ashino and K. Takada, “Determination of Trace Amounts of Gold and Silver in High-Purity Iron and Steel by Electrothermal Atomic Absorption Spec- trometry after Reductive Coprecipitation,” Fresenius Journal of Analytical Chemistry, Vol. 368, No. 4, 2000, pp. 344-349. doi:10.1007/s002160000455
[7] K. Kobayashi, S. Hasegawa, S. Itoh, K. Ide, H. Yamagu- chi and Y. Yamada, “Analysis of Iron and Steels for Tramp Elements by Graphite Furnace AAS,” Tetsu-To- Hagané, Vol. 90, No. 2, 2004, pp. 86-91.
[8] T. W. May and W. G. Brumbaugh, “Matrix Modifier and Lvov Platform for Elimination of Matrix Interferences in the Analysis of Fish-Tissues for Lead by Graphite-Fur- nace Atomic-Absorption Spectrometry,” Analytical Chemi- stry, Vol. 54, No. 7, 1982, pp. 1032-1037. doi:10.1021/ac00244a005
[9] M. Taga, H. Yoshida and O. Sakurada, “Determination of Tin by Graphite-Furnace AAS with Matrix Modifier,” Bunseki Kagaku, Vol. 36, No. 10, 1987, pp. 597-600. doi:10.2116/bunsekikagaku.36.10_597
[10] K. Matsumoto, “Palladium as a Matrix Modifier in Gra-phite-Furnace Atomic-Absorption Spectrometry of Group IIIb-VIb Elements,” Analytical Sciences, Vol. 9, No. 11, 1993, pp. 447-453. doi:10.2116/analsci.9.447
[11] Y. Morishige, K. Hirokawa and K. Yasuda, “The Role of Metallic Matrix Modifiers in Graphite-Furnace Atomic- absorption Spectrometry,” Fresenius Journal of Analyti- cal Chemistry, Vol. 350, No. 6, 1994, pp. 410-412. doi:10.1007/BF00325614
[12] K. Hirokawa, K. Yasuda and K. Takada, “Graphite-Fur- nace Atomic-Absorption Spectrometry and Phase-Dia- grams of Alloys,” Analytical Sciences, Vol. 8, No. 3, 1992, pp. 411-417. doi:10.2116/analsci.8.411
[13] S. Morimoto, T. Ashino and K. Wagatsuma, “Role of a Binary Metallic Modifier in the Determination of Cad- mium in Graphite Furnace Atomic Absorption Spec- trometry,” Analytical Sciences, Vol. 26, No. 7, 2010, pp. 809-813. doi:10.2116/analsci.26.809
[14] B. V. L’Vov, “Electrothermal Atomization—Way to- ward Absolute Methods of Atomic-Absorption Analysis,” Spectrochimica Acta, Vol. 33B, No. 5, 1978, pp. 153-193.
[15] M. L. Cervera, A. Nevarro, R. Montoro, M. Gerardia and A. Salvador, “Platform in Furnace Zeeman-Effect Atomic- absorption Spectrometric Determination of Arsenic in Beer by Atomization of Slurries of Sample Ash,” Journal of Analytical Atomic Spectrometry, Vol. 6, No. 6, 1991, pp. 477-481. doi:10.1039/ja9910600477
[16] H. D. Narrce, C. M. Ohl and M. Stoppler, “Metal Analy- sis in Difficult Materials with Platform Furnace Zeeman- Atomic Absorption Spectrometry: I. Direct Determina- tion of Cadmium in Crude Oil and Oil Products,” Inter- national Journal of Environmental Analytical Chemistry, Vol. 18, No. 4, 1984, pp. 267-279. doi:10.1080/03067318408077008
[17] D. Ma, Y. Okamoto, T. Kumamaru and E. Iwamoto, “Determination of Gallium by Graphite Furnace Atomic Absorption Spectrometry with Combined Use of a Tung- sten-Coated L’Vov Platform Tube and a Chemical Mod-ification Technique,” Analytica Chimica Acta, Vol. 390, No. 1-3, 1999, pp. 201-206. doi:10.1016/S0003-2670(99)00144-0
[18] F. Fagioli, C. Locatelli, R. Vecchiett and G. Torsi, “Sur- vey of the Diffusion Process in Atomic-Absorption Spec- trometry with the Platform-in-Furnace Technique,” Jour- nal of Analytical Atomic Spectrometry, Vol. 3, No. 1, 1988, pp. 159-162. doi:10.1039/ja9880300159
[19] T. M. Mahmood and K. W. Jackson, “Wall-to-Platform Migration in Electrothermal Atomic Absorption Spectro-metry .1. Investigation of the Mechanism of Chloride In-terference on Thallium,” Spectrochimica Acta, Vol. 51B, No. 9-10, 1996, pp. 1155-1162.
[20] H. Shimabukuro, T. Ashino and K. Wagatsuma, “Tem- poral Variations in Gas Temperature in an Atomization Stage of Cadmium and Tellurium Evaluated by Using the Two-Line Method in Graphite Furnace Atomic Absor- ption Spectrometry,” Analytical Sciences, Vol. 24, No. 9, 2008, pp. 1165-1170. doi:10.2116/analsci.24.1165
[21] P. W. J. M. Boumans, “Theory of Spectrochemical Exci- tation,” Prenum Press, New York, 1966.
[22] T. Ashino, S. Morimoto and K. Wagatsuma, “Role of a Binary Metallic Modifier in the Determination of Cad- mium in Graphite Furnace Atomic Absorption Spectro- metry,” Analytical Sciences, Vol. 26, No. 7, 2010, pp. 809-813. doi:10.2116/analsci.26.809
[23] J. R. Fuhr, G. A. Martin and W. L. Wiese, “Atomic Tran- sition Probabilities, Iron through Nickel,” Journal Physi- cal and Chemical Reference Data, Vol. 17, Supplement No. 4, 1988, pp. 25-26.
[24] M. Hansen, “Constitution of Binary Alloys,” McGraw Hill, New York, 1958, pp. 695, 1094-1095.

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