Share This Article:

The Theory of Coherent Synchronized Reactions: Chemical Interference Logics

Abstract Full-Text HTML XML Download Download as PDF (Size:2335KB) PP. 152-170
DOI: 10.4236/msa.2015.62019    3,218 Downloads   3,561 Views   Citations
Author(s)    Leave a comment

ABSTRACT

Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced; the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered. Therefore macrokinetic theory of coherent synchronized reactions is offered.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Nagiev, T. (2015) The Theory of Coherent Synchronized Reactions: Chemical Interference Logics. Materials Sciences and Applications, 6, 152-170. doi: 10.4236/msa.2015.62019.

References

[1] Nagiev, T.M. (2007) Coherent Synchronized Oxidation by Hydrogen Peroxide. Elsevier, Amsterdam, 325.
[2] Nagiev, T.M. (1994) Interrelated Reactions and Chemical Interference. Journal of Physics and Chemistry, 68, 456-460.
[3] Nagiev, T.M. (2000) Conjugated Chemical Reactions. Journal of Physics and Chemistry, 74, 2034-2040.
[4] Buchachenko, A.L. (1999) Chemistry on the Border of Two Centuries—Achievements and Prospects. Russian Chemical Reviews, 68, 85-102. http://dx.doi.org/10.1070/RC1999v068n02ABEH000487
[5] Boreskov, G.K. (1971) Catalysis, Pt. 1/2. Nauka, Novosibirsk, 267.
[6] Nagiev, T.M. (1983) Conjugated Reactions of Oxidation by Hydrogen Peroxide. Zhurnal Fizicheskoi Khimii, 6, 823- 832.
[7] Nonhibel, D. and Walton, J. (1977) Chemistry of Free Radicals. Mir, Moscow, 606.
[8] Nulman, B. and Pulman, A. (1965) Quantum Biochemistry. Mir, Moscow, 654.
[9] Benson, S. (1971) Thermochemical Kinetics. Mir, Moscow, 308.
[10] Nagiev, T.M., Mamed’yurov, G.M., Nagieva, Z.M. and Agaeva, S.I. (1981) Study of Conjugated Oxidation Reactions by Hydrogen Peroxide. XII Mendeleev Council on General and Applied Chemistry, Nauka, Moscow, No. 4, 268.
[11] Nagiev, T.M. and Abbasova, M.T. (1997) Oxidation of Methane to Methanol by Hydrogen Peroxide on a Supported Hematin Catalyst. Journal of Physical Chemistry, 71, 1213-1217.
[12] Nagiev, T.M., Gasanova, L.M., Zulfugarova, S.Z. and Mustafaeva, Ch.A. (1996) Oxidation-and-Heating-Stable Fe(III) Perfluoroetraphenylporphyrin Catalyst Immobilized on Alumunia. Journal of Physical Chemistry, 70, 2063-2068.
[13] Mamedov, E.M., Farajev, E.G. and Nagiev, T.M. (1997) High Selectivity Process of Conjugation Oxidation Methane by Hydrogen Peroxide to Methanol under Pressure. Azerbaidzhanskii Khimicheskii Zhurnal, 45-48.
[14] Nagiev, T.M., Farajev, E.G. and Mamedov, E.M. (2001) Oxidation Methane by Hydrogen Peroxide to Methanol under Pressure. Journal of Physical Chemistry, 75, 50-56.
[15] Ashmore, P.A. (1966) Catalysis and Inhibition of Chemical Reactions. Mir, Moscow, 386.
[16] Dolgoplosk, B.A. and Tinyakova, E.I. (1982) Generation of Free Radicals and Their Reactions. Nauka, Moscow, 253.
[17] Dolgoplosk, B.A. and Tinyakova, E.I. (1972) Redox System as the Source of Free Radicals. Nauka, Moscow, 237.
[18] Emanuel, N.M. and Knorre D.G. (1984) The Course of Chemical Kinetics. Vysshaya Shkola, Moscow, 237.

  
comments powered by Disqus

Copyright © 2018 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.