Geochemistry , Mineral Chemistry and Thermobarometry of Boneh-Shorou Amphibolites in Gelmandeh Massive ( Saghand-Central Iran )

The Gelmandeh Massive is located in the Central part of Iranian Microcontinent. Amphibolitic rocks occupy the main portion of Gelmandeh complex, which consists of hornblendite, garnet amphibolites, and gneiss. Geochemical investigations indicate that the ratio of Eu/Eu* separates samples into two categories: first category with ratio of Eu/Eu* > 1 and the second with ratio of Eu/Eu* < 1, which the former indicates an enriched mantle origin while the latter points to crustal contamination. Generally, amphibolites can be differentiated into two separate series. First series is characterized with calc-alkaline to alkaline composition with enriched mantle origin, and the second one has calc-alkaline to tholeiitic nature and it is of continental type that underwent crustal contamination within subduction zone. The microprobe electron analysis shows that the amphiboles were a member of the calcic group and hastingsite-tschermakite series. Geo-barometric studied and mineral paragenesis show that the metamorphism is of Barovian type with PT condition upto 7 K bar and 580 ̊C. Corresponding author. A. Gourabjeiri-Pour et al.


Introduction
The studied area is located within Yazd Province, and can be seen in some geological quadrangles such as Ardakan 1:250,000 [1], Saghand 1:100,000 [2], Chah-miyoonteh 1:25,000 (Block 70 of Ardakan quadrangle), numbered as 7055II NE.Its geographic coordinates limited within 55, 22, 30 to 55, 30, 00 eastern longitudes, and 32, 45, 00 to 32, 37, 30 northern latitudes, all located in geographic zone 40.Based on geological-structural classification of Iran, this area is considered as part of Central Iran zone and Kalmard-Posht-e-Badam block.Geomorphologically, this area can be divided into two parts, and Posht-e-Badam fault is the departing line trending NE-SW that divides the area into two eastern and western parts.This fault changes direction near the city of Saghand as its trend shifts toward NW-SE.The eastern part mainly consists of low mounds which crop out through a series of desert flats whereas the western part of the fault includes wide short "KALUTs".The western part consists of geologic complexes namely Posht-e-Badam, Chatak, Chapedony and Naybaz featuring ages ranging from Late Paleozoic to Eocene and present (Figure 1).
The eastern part of the fault is older than the western part, and it is indeed a part of Iran's basement.This part consists of geologic complexes such as Zamanabad, Boneh Shorou and Tashk.The oldest rock units of this part include a series of slate, micaschist, quartzite, metagraywacke, volcaniclastics, and mafic lavas, which has been known and introduced as Tashk Formation.This formation contains clastic zircons with age of 627 million years.This rock unit is covered with volcano-clastic complex with age of Cambrian [3].Thereafter, a shallow marine carbonate rock unit with age of Permian-Triassic sits atop Cambrian rock unit with an angular unconformity, and furthermore, an Orbitolina-bearing clastic carbonate rock unit with age of Cretaceous (Albian-Aptian) covers the older rock units, yet again with an angular unconformity.Boneh-shorou Complex consists of a series of micaschist, gneiss, amphibolites, marble and quartzite, in which amphibolites containing large garnet grains are abundant within this complex.Metamorphosis age of these amphibolites was dated as old as 547 ± 2 million years [4], which intercalated with micaschist and were cut through by granitic intrusive bodies (now as gneiss) with age of 533 years old [4].

Gelmandeh Massive
This massive is in form of an oval upheaval trending NW-SE that sits between Allahabad desert and eastern part of Posht-e-Badam fault.It is part of Boneh-shorou complex, and is of great importance to be studies as Iran's basement.Figure 2 shows a three-dimensional (3D) view of Gelmandeh massive, which is an assemblage of IRS and Aster satellite images with scale of 1;25,000.These satellite images have been used as base for compilation of geological map of Gelmandeh mound with scale of 1:25,000.Figure 3 shows the geological map of Gelmandeh massive.

Methodology and Procedure
Conducting and performing a geological research project considering its experimental nature as well as the research concepts include specific methods that can be divided in three major parts as it follows: 1) Field visits and introductory sampling, 2) Lab studies, 3) Office works to prepare and compile the results and findings from previous.
Two steps during the course of this project, which are described below: a) Field studies and sampling, b) Date gathering, preparation and processing of Aster satellite images with resolution of 15 meters in assemblage with IRS satellite images with resolution of 5 meters in order to compile geological map of the studied area, c) Field studies and sampling from rock units both in form of normal and positional approaches, and structural measurements, d) Lab studies including thin sections, total rock analysis, and electron-microprobe studies, e) Analysis and compilation of data.

Lab Studies
Based on the results from thin section studies, several samples were selected out of total samples taken from the studied area to be sent to lab for the purpose of total rock analysis both for geochemical analysis and electron microprobe mineralogy point analysis.Total rock analysis for 43 elements was performed using ICP method by ALS lab in Canada.The analysis method for 10 major oxide elements was chosen to be ME-ICP06, and ME-MS81 for rare elements.
After sample preparation, mineralogical analysis using electron micro probe analyses method performed by SX100 machine in Maximillian University in Hamburg, Germany.

Petrography and Mineral Distribution
Amphibolitic rock unit occupies the main portion of Gelmandeh massive, which consists of three parts of hornblendite (large amphibolites), garnet-amphibolites, and gray mafic gneiss.The distinctive features of this unit are its dark color (dark green to black) and large garnet grains that in some cases their size reaches to 2.5 cm.

Hornblendite
Hornblendites are identified with high content of large-grained and multi-colored hornblendes (green-blue) in such way that hornblendes often form 90% of the rock volume, and their size reaches to 8 mm in some areas.This rock unit contains low amount of plagioclase and quartz along with secondary minerals such as sphene and apatite.Amphiboles are usually fully-shaped to amorphous with no distinct foliation, however amphibole needles show orientation.Amphiboles in hornblendite thin sections are less conspicuous and fewer multi-coloreds as compared to those in gneiss and amphibolites (Figure 4

Garnet-Amphibolites
Garnet-amphibolites are characterized with granular to nematoblastic texture and large pink garnet grains, but without a distinguishable banded structure.Among other characteristics of this unit, it can be referred to existence of intact green-blue amphiboles with good prominence (Figure 5(a), Figure 5(b)), and plagioclases with albitic macle and somehow sericitized.Biotite, epidote and sphene are among the secondary minerals of this rock unit.Garnets are mostly of almandine-grossular composition, and lack zoning (Figure 6(a), Figure 6(b)).They are altered along the fractures and transformed to chlorite and quartz.Amphiboles are generally seen as semi-shaped to amorphous, but mostly in form of short to long columns or wide rods to somewhat columnar.They are rarely seen as automorphous, but seen in form of hexagonal in cross sections.Bluish green color is one of their characteristics.Based on Figures 7(a)-(c) they fall in calcic amphiboles group, green hornblende family and hastingsite-tschermakite series.

Amphibolitic Gneiss
Amphibolitic gneisses or gray mafic gneisses are characterized with large porphyroclastic plagioclases and biotites, which show signs of mylonitization and foliation due to mylonitization.This rock unit often contains pink garnets that are seen as amorphous and rounded with many fractures in the thin sections.Plagioclases are usually heavily altered in the central parts, which show accumulations rich in epidote and calcium.Among other characteristics of this rock unit it can be referred to existence of amphiboles with good prominence and strong blue-green multi-coloration that are mainly seen along the edges of these garnets (Figure 8(a), Figure 8(b)).
Transformation of mafic gneisses to amphibolites sub-unit is characterized by increase of hornblende content and garnet size, and also evidence of mylonitization.

Geochemistry
Total rock geochemical study of amphibolites in Gelmandeh massive is based on analysis results from 11 samples that were studied and analyzed for 43 elements in ALS lab in Canada.Table 1 shows the results from analysis of main elements oxides as well as the results from related calculations in details.
This complex in Gelmandeh massive is remarkably widespread, and based on the field evidences, its origin can be associated with a dark-colored gabbro-basaltic body.Signs and evidences of penetration of this intrusive     body are frequently seen in older parts.
According to Table 1 the content of SiO 2 varies from 45 to 57 with an average of 51.3%, and Al 2 O 3 content ranges from 10 -1 with average of 14.4.The variation range of other major elements oxides such as Fe 2 O 3 varies between 6.77 and 15.5, CaO between 5.02 and 12.3, Na 2 O between 1.26 and 7.23, K 2 O between 0.26 and 2.81, TiO 2 between 0.63 and 3.65, MnO between 0.09 and 0.36, and P 2 O 5 between 0.14 and 0.88.Accordingly, the variation of degree of saturation of Aluminum (A/CNK) ranges between 0.87 and 1.06, the ratio of Mg# varies from 0.44 to 0.52, and A' index changes between 1.76 and 1.86.Such variations match the average/median of continental basalts.R1-R2 [5] diagram have been used in order to name and identify the source rock of these amphibolites and to support petrographic studies (Figure 9(a)).In this diagram the nature of samples varies from gabbro to gabbro-diorite, monzo-gabbro and diorite.
In addition, other diagrams such as Zr/Ti-Nb/Y [6] and Co-Th [7] differentiate these rocks as two complexes     15) and normalization of data based on chondrite content yield interesting evidences in this section.The ratio of Eu/Eu* separates samples in two categories; one category with ratio of Eu/Eu* > 1 and the other with ratio of Eu/Eu* < 1, which the former one indicates to an enriched mantle origin while the latter one points to crustal contamination.
The ratio of (La/Sm) > 1 also confirms the enriched mantle origin for formation of amphibolites.Figure 13 shows all samples in a chondrite-based normalized spider diagram [9].This diagram clearly presents different origins for these types of rocks.Based on this fact the samples were divided apart and spider diagram was drawn for each part again.Samples GL1S3, GL9S38, GL11S53, GL18S71 and GL21S76 were allocated to one part and the rest of the samples to the other part.Figure 14 shows enrichment for Th, Nb, Ta and Ti elements and impoverishment for Rb, K and Sr elements, which implies to enriched mantle origin of alkaline-basalt type within oceanic or crustal plates.
Figure 15 shows variation of samples GL25S86, GL23S81, GL47S64, GL45S60, GL10S42 and GL6S22 in spider diagram.The samples show impoverishment for P, Ti, Ta, Nb and Th elements whereas enrichment for Rb, K and Nd elements.Impoverishment of Nb and Ti is specific to magmas that undergo crustal contamination process within a tectonic setting associated with subduction.
According to Wood [10] diagram (Figure 16), it assigns the first series of samples to continental alkaline-basalt territory and the second series of samples to continental tholeiitic-basalt territory.
Taking all data and findings into account, two geneses are confirmed for the origin of amphibolites although petrographic studies do not show significant difference between these two geneses.Accordingly, amphibolites can be differentiated into two separate series.First series is characterized with calc-alkaline to alkaline composi-tion with enriched mantle origin of continental type, and the second one has calc-alkaline to tholeiitic composition and it is of continental type that underwent crustal contamination within subduction zone, which is probably younger than the first series.

Thermo-Barometry
The best method to determine the temperature and pressure condition affecting the studied area at the time is to     [10].Samples in the first series fall in a territory between continental alkali-basalt and tholeiits, while the samples in the second series fall in magmatic arc basalt territory.
precisely study the association of minerals with one another as well as the reactions took place among them [12].The mineralogical association and minerals assemblage have been described in detail in petrography section.Here it is attempted to reconstruct the reactions between minerals and determine the metamorphism conditions based on mineralogical association.At the final stage, the results gained from determination of metamorphic facies based on mineralogical association along with the results from electron microprobe analyses were studied and analyzed using THERMOCALC (Version 2.3) software and temperature and pressure condition for formation of each mineral was determined.
Garnet-amphibolite consists of hornblendes belonged to HANSTINGZIT-CHERMAKIT series (Figure 17(a)), and oligoclase-andesine plagioclase minerals are primary components of this rock unit, wherein amorphous garnet without zoning along (Figure 17(b), Figure 18) with small amount of biotite and quartz are found.
2) Transformation of amphibole composition from actinolite to hornblende.In this situation and due to structural change, amphiboles acquire more dense composition and leads to formation of hornblendes belonged to CHERMAKIT to PARAGARNET series.

Conclusions
Based on the facts and findings, it can be concluded that Gelmandeh complex is the result of metamorphosis of rocks within a shallow basin, which is accompanied by magmatic rocks as they all place atop an ultrabasic to basic basement.Gelmandeh complex was originally a complex of arenite-quartz sandstones with intercalations of shallow basin limestones.Geochemical studies imply that the basement of the basin is of gabbro or basalt with calc-alkaline to alkaline nature, which originated from an enriched mantle origin.These studies show their formation environment was of continental type, which probably might be the sign for a hotspot deep in the mantle.
This complex along with mafic intrusive and extrusive rocks at its lower part was probably metamorphosed 547 million years ago (metamorphic age of amphibolites in Gelmandeh) that was concurrent with the penetration of basic to intermediate complexes with composition of gabbro-diorite.Total rock geochemical studies on samples of amphibolites confirm the aforementioned assumption to some extent.Such studies point to two separable origins for amphibolites, and divide them into two complexes; one is of calc-alkaline to alkaline nature with enriched mantle origin (Eu/Eu* > 1) and the other is of calc-alkaline to tholeiitic or crustal contaminated nature (Eu/Eu* < 1).Both complexes formed in a continental tectonic setting.Such results make one think of two different origins or one origin in two different times originated from a hotspot, which indicate the former was directly originated from the mantle and is older, and the latter is younger but underwent crustal contamination.
During the course of this metamorphism, quartzites turned to mica schist, limestones to marbles, and the basement and basic intrusive to amphibolites.The results from mineral assemblage in petrographic studies and the results from microprobe electron analysis point to metamorphism as high as amphibolite facies.
The presence of hornblende bands with CHERMAKIT and HASTINGZIT composition along with high content of epidote in amphibolites indicates to epidote-amphibolite facies, and presence of large garnets with almandine composition implies to facies transition to the higher grade.Barometric studies on samples taken from the studied area point to metamorphism of BAROVIAN type and epidote-amphibolite metamorphic facies with precedence of maximum pressure peak over maximum temperature peak.The calculation yields an average temperature of 580˚C and pressure of 7 kilo bar.

Figure 1 .
Figure 1.A general view of the studied area and the location of identified geologic complexes on both sides of Posht-e-Badam fault.

Figure 2 .
Figure 2. Three-dimensional (3D) view of Gelmandeh massive, which is an assemblage of IRS and Aster.

Figure 11 .
Figure 11.Variation of major element oxide in relation to MgO [11].

Figure 12 .
Figure 12.Variation of rare elements oxide in relation to MgO [11]. of Ni and Cr in rare elements is remarkable, and Y, Ce, Ba, Zr, Rb and alkaniteh show descending trend too.Crystalline liquid distribution coefficient data shows that during partial melting Ni, Ca and Cr separate away from olivine crystalline differentiation process.Therefore, distribution and abundance of such elements is a useful indication for petrogenetic processes.So far, the study of major and rate elements in Harker diagram not only confirms and verifies the magmatic origin for amphibolites but also indicates that formation of amphiboles associates with two different origins or happened during two different time spans.Study of rare elements in spider diagrams (Figures13-15) and normalization of data based on chondrite content yield interesting evidences in this section.The ratio of Eu/Eu* separates samples in two categories; one category with ratio of Eu/Eu* > 1 and the other with ratio of Eu/Eu* < 1, which the former one indicates to an enriched mantle origin while the latter one points to crustal contamination.The ratio of (La/Sm) > 1 also confirms the enriched mantle origin for formation of amphibolites.Figure13shows all samples in a chondrite-based normalized spider diagram[9].This diagram clearly presents different origins for these types of rocks.Based on this fact the samples were divided apart and spider diagram was drawn for each part again.Samples GL1S3, GL9S38, GL11S53, GL18S71 and GL21S76 were allocated to one part and the rest of the samples to the other part.Figure14shows enrichment for Th, Nb, Ta and Ti elements and impoverishment for Rb, K and Sr elements, which implies to enriched mantle origin of alkaline-basalt type within oceanic or crustal plates.Figure15shows variation of samples GL25S86, GL23S81, GL47S64, GL45S60, GL10S42 and GL6S22 in spider diagram.The samples show impoverishment for P, Ti, Ta, Nb and Th elements whereas enrichment for Rb, K and Nd elements.Impoverishment of Nb and Ti is specific to magmas that undergo crustal contamination process within a tectonic setting associated with subduction.According to Wood[10] diagram (Figure16), it assigns the first series of samples to continental alkaline-basalt territory and the second series of samples to continental tholeiitic-basalt territory.Taking all data and findings into account, two geneses are confirmed for the origin of amphibolites although petrographic studies do not show significant difference between these two geneses.Accordingly, amphibolites can be differentiated into two separate series.First series is characterized with calc-alkaline to alkaline composi-

Figure 16 .
Figure 16.Diagram distinguishing basalts based on Th-Hf-Ta[10].Samples in the first series fall in a territory between continental alkali-basalt and tholeiits, while the samples in the second series fall in magmatic arc basalt territory.

Figure 18 .
Figure 18.Variation of 20-point composition across garnet mineral, composition homogeneous composition of garnets, and lack of zoning are shown in this diagram.

Figure 20 .
Figure 20.Diagram showing main metamorphic facies, tri-points of Al 2 O 3 , and thermo barometric study of samples [14].calculation using garnet, plagioclase and amphibole minerals points to temperature of 580˚C and pressure of 7 kilo bar for metamorphic condition of garnet-amphibolites (Figure 20).

Table 1 .
The results of major elements total rock analysis, in Gelmandeh-Saghand area.

Table 2 .
Results from electron microprobe analysis of minerals in sample GL21S76.