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Universal 2D Soft Nano-Scale Mosaic Structure Theory for Polymers and Colloids

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DOI: 10.4236/snl.2011.13016    4,357 Downloads   7,222 Views   Citations
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ABSTRACT

A basic concept in chain-particle cluster-motion, from frozen glassy state to melt state, is the 2D soft nano-scale mosaic structure formed by 8 orders of 2D interface excitation (IE) loop-flows, from small to large in inverse cascade and rearrangement structure in cascade along local one direction. IE has additional repulsive energy and extra vacancy volume. IE results from that the instantaneous synchronal polarized electron charge coupling pair is able to parallel transport on the interface between two neighboring chain-particles with antiparallel delocalization. This structure accords with de Gennes’ mosaic structure picture, from which we can directly deduce glass transition temperature, melt temperature, free volume fraction, critical entangled chain length, and activation energy to break solid lattice. This is also the inherency maximum order-potential structure in random systems.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

J. Wu, "Universal 2D Soft Nano-Scale Mosaic Structure Theory for Polymers and Colloids," Soft Nanoscience Letters, Vol. 1 No. 3, 2011, pp. 86-95. doi: 10.4236/snl.2011.13016.

References

[1] R. Zallen, “The Physics of Amorphous Solids,” Wiley Interscience, New York, 1983. doi:10.1002/3527602798
[2] C. Alba-Simionesco, J.-L., Barrat, L. Berthier, G. Biroli, J.-P. Bouchaud, L. Cipelletti, F. Corberi, L. Cugloandolo, et al., “Dynamical Heterogeneities in Glasses, Colloids and Granular Materials,” In: L. Berthier, G. Biroli, J.-P. Bouchaud, L. Cipelletti and W. van Saarloos, Eds., Oxford University Press, Oxford, 2011, Chapter 1-12. http://www.physics.emory.edu/~weeks/ lab/pubs.html
[3] P. G. de Genne, “A Simple Picture for Structural Glasses,” Comptes Rendus Physique, Vol. 3, No. 9, 2002, pp. 1263-1268. doi:10.1016/S1631-0705(02)01387-7
[4] J.-l. WU, D. Guan and B. Quian, “The Characteristic Behaviour of the Stretch-Orientation Zone during High- Speed PET Spinning,” International Polymer Processing, Vol. 1, No. 1, 1986, pp. 25-31.
[5] M. V. Berry, “Foreword to ‘Global Properties of Simple Quantum Systems—Berry’s Phase and Others’,” In: H. Z. Li, Ed., Shanghai Scientific and Technical, Shanghai, 1998. http://www.phy.bris.ac.uk/peple/berry_mv/the_papers/berry 347.pdf
[6] Physics Survey Committal, “Physics through the 1990s, Condensed-Matter Physics,” National Academy, Washington, 1986, p. 56.
[7] V. Lubchenko and P. G. Wolynes, “Origin of the Boson Peak and Thermal Conductivity Plateau in Low Temperature Glasses,” P N AN (USA), Vol. 100, No. 4, 2003, pp. 1515-1518. doi:10.1016/S1631-0705(02)01387-7
[8] G. N. Greaves, F. Meneau, O. Majérus, D. G. Jones and J. Taylor, “Identifying Vibrations That Destabilize Crystals and Characterize the Glassy State,” Science, Vol. 308, No. 5726, 2005, pp. 1299-1302. doi:10.1126/science.1109411
[9] G. Tarjus, “An Overview of the Theories of the Glass Transition,” Oxford University Press, Oxford, 2010.
[10] V. Lubchenko and P. G. Wolynes, “Barrier Softening Near the Onset of Nonactivated Transport in Supercooled Liquids: Implications for Establishing Detailed Connection between Thermodynamic and Kinetic Anomalies in Supercooled Liquids,” Journal of Chemical Physics, Vol. 119, No. 17, 2003, pp. 9088-9105. doi:10.1063/1.1614180
[11] J. Jackle, “Models of the Glass Transition,” Reports on Progress in Physics, Vol. 49, No. 2, 1986, pp. 171-231. doi:10.1088/0034-4885/49/2/002
[12] K. J. Falconer, “Fractal Geometry-Mathematical Foundations and Applications,” 2nd Edition, John Wiley and Sons, New York, 2003. doi:10.1002/0470013850
[13] V. Lubchenko and P. G. Wolynes, “The Intrinsic Quantum Excitations of Low Temperature Glasses,” Physical Review Letters, Vol. 87, No. 19, 2001, p. 195901. doi:10.1103/PhysRevLett.87.195901
[14] S. Pahl, G. Fleischer, F. Fujara and B. Geil, “Anomalous Segment Diffusion in Polydimethylsiloxane Melts,” Macromolecules, Vol. 30, 1997, No. 5, pp. 1414-1418.

  
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