Activated Carbons Containing Dispersed Metal Oxide Particles for Removal of Methyl Mercaptan in Air
Hisashi Tamai, Miki Nakamori, Masayoshi Nishikawa, Takeshi Shiono
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DOI: 10.4236/msa.2011.21007   PDF    HTML     5,889 Downloads   10,879 Views   Citations

Abstract

Activated carbons containing dispersed metal oxide particles were prepared by carbonization of phenol resin containing metal compounds followed by steam activation. Acetylacetonates of Fe, Mn and V, and Cu nitrate were used as the sources of metals. The removal of a small amount of methyl mercaptan (CH3SH) in air with these activated carbons was tested in a flow system. Compared with activated carbons without metal oxides, the carbons exhibited high activity for the removal of CH3SH in air. In particular, activated carbon obtained from Novolac containing 5 wt% Cu showed excellent behavior over a long time.

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H. Tamai, M. Nakamori, M. Nishikawa and T. Shiono, "Activated Carbons Containing Dispersed Metal Oxide Particles for Removal of Methyl Mercaptan in Air," Materials Sciences and Applications, Vol. 2 No. 1, 2011, pp. 49-52. doi: 10.4236/msa.2011.21007.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] T. Sakano, H. Tamon and M. Okazaki, “Selective Removal of Methyl Mercaptan Coffee Aroma Using Oxidized Microporous Carbon,” Journal of Chemical Engineering of Japan, Vol. 32, No. 5, 1999, pp. 701-704. doi:10.1252/jcej.32.701
[2] A. K. Dalai, E. L. Tollefson, A. Yang and E. Sasaoka, “Oxidation of Methyl Mercaptan over an Activated Carbon in a Fixed-Bed Reactor,” Industrial & Engineering Chemistry Research, Vol. 36, No. 11, 1997, pp. 4726-4733. doi:10.1021/ie9701231
[3] S. Bashkova, A. Bagreev and T. J. Bandosz, “Adsorption of Methyl Mercaptan on Activated Carbons,” Environmental Science & Technology, Vol. 36, No. 12, 2002, pp. 2777-2782. doi:10.1021/es011416v
[4] S. Bashkova, A. Bagreev and T. J. Bandosz, “Effect of Surface Characteristics on Adsorption of Methyl Mercaptan on Activated Carbons,” Industrial & Engineering Chemistry Research, Vol. 41, No. 17, 2002, pp. 4346-4352. doi:10.1021/ie020137t
[5] S. Bashkova, A. Bagreev and T. J. Bandosz, “Adsorption/Oxidation of CH3SH on Activated Carbons Containing Nitrogen,” Langmuir, Vol. 19, No. 15, 2003, pp. 6115-6121. doi:10.1021/la0300030
[6] A. Bagreev, J. A. Menendez, I. Dukhno, Y. Tarasenko and T. J. Bandoz, “Oxidative Adsorption of Methyl Mercaptan on Nitrogen-Enriched Bituminous Coal-Based Activated Carbon,” Carbon, Vol. 43, No. 1, 2005, pp. 195 -213. doi:10.1016/j.carbon.2004.09.003
[7] A. H. Miguel, D. F. S. Natusch, R. L. Tanner and J. L. Hudson, “Adsorption and Catalytic Conversion of Thiol Vapors by Activated Carbon and Manganese Dioxide,” Atmospheric Environment, Vol. 10, No. 2, 1976, pp. 145 -150. doi:10.1016/0004-6981(76)90232-8
[8] C. J. Heyes, J. G. Irwin, H. A. Johnson and R. L. Moss, “The Catalytic Oxidation of Organic Air Pollutants. Part 1. Single Metal Oxide Catalysts,” Journal of Chemical Technology & Biotechnology, Vol. 32, No. 12, 1982, pp. 1025-1033. doi:10.1002/jctb.5030320746
[9] C. J. Heyes, J. G. Irwin, H. A. Johnson and R. L. Moss, “The Catalytic Oxidation of Organic Air Pollutants. Part 2. Cobalt Molybdate and Copper Chromite Catalysts,” Journal of Chemical Technology & Biotechnology, Vol. 32, No. 12, 1982, pp. 1034-1041.
[10] M. Nozawa, K. Tanigawa, M. Hosomi, T. Chikusa and E. Kawada, “Removal and Decomposition of Malodorants by Using Titanium Dioxide Photocatalyst Supported on Fiber,” Water Science and Technology, Vol. 44, No. 9, 2001, pp. 127-133.
[11] H. Tamai, T. Kakii, Y. Hirota, T. Kumamoto and H. Yasuda, “Synthesis of Extremely Large Mesoporous Activated Carbon and Its Unique Adsorption for Giant Molecules,” Chemistry of Materials, Vol. 8, No. 2, 1996, pp. 454-462. doi:10.1021/cm950381t

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