Share This Article:

Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups

Full-Text HTML XML Download Download as PDF (Size:421KB) PP. 284-294
DOI: 10.4236/ijoc.2017.73022    766 Downloads   1,329 Views

ABSTRACT

Much interest has been devoted to organometallic NLO materials. We have become interested in exploring the utility of ferrocenyl group as the conjugating bridge. Thus, we synthesized 1-{{[1,3-(5-methylbenzo)dithiol]-2-yli- dene}methyl}-1’-[2-(p-nitrophenyl)-(E)-ethenyl]ferrocene (1). This new ferrocenyl compound has a donor and an acceptor group in 1,1’-positions. Investigations of the solvatochromic property of the compound revealed that it has polarized structure in a polar solvent, such as DMF. SHG efficiency of the compound was estimated by an SHEW (second-harmonic generation with the evanescent wave) method.

Cite this paper

Minato, M. , Sorai, C. , Ito, T. , Kiguchi, M. and Kato, M. (2017) Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups. International Journal of Organic Chemistry, 7, 284-294. doi: 10.4236/ijoc.2017.73022.

Copyright © 2019 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.