Thermodynamic Aspects of the Graphene/Graphane/Hydrogen Systems: Relevance to the Hydrogen On-Board Storage Problem - Advances in Materials Physics and Chemistry

AMPC > Vol.3 No.5, September 2013

Thermodynamic Aspects of the Graphene/Graphane/Hydrogen Systems: Relevance to the Hydrogen On-Board Storage Problem ()

HTML

Download as PDF (Size: 11930KB) PP. 255-280

DOI: 10.4236/ampc.2013.35037 5,529 Downloads 9,972 Views Citations

Author(s)

Yury S. Nechaev, T. Nejat Veziroglu

Affiliation(s)

Bardin Institute for Ferrous Metallurgy, Kurdjumov Institute of Metals Science and Physics, Vtoraya Baumanskaya St., Moscow, Russia.
International Association for Hydrogen Energy, Miami, USA.

ABSTRACT

The present analytical review is devoted to the current problem of thermodynamic stability and related thermodynamic characteristics of the following graphene layers systems: 1) double-side hydrogenated graphene of composition CH (theoretical graphane) (Sofo et al. 2007) and experimental graphane (Elias et al. 2009); 2) theoretical single-side hydrogenated graphene of composition CH; 3) theoretical single-side hydrogenated graphene of composition C2H (graphone); 4) experimental hydrogenated epitaxial graphene, bilayer graphene and a few layers of graphene on SiO2 or other substrates; 5) experimental and theoretical single-external side hydrogenated single-walled carbon nanotubes, and experimental hydrofullerene C60H36; 6) experimental single-internal side hydrogenated (up to C2H or CH composition) graphene nanoblisters with intercalated high pressure H2 gas inside them, formed on a surface of highly oriented pyrolytic graphite or epitaxial graphene under the atomic hydrogen treatment; and 7) experimental hydrogenated graphite nanofibers-multigraphene with intercalated solid H2 nano-regions of high density inside them, relevant to solving the problem of hydrogen on-board storage (Nechaev 2011-2012).

KEYWORDS

Hydrogenated Graphene Layers; Graphanes; Thermodynamic Stability; Solid Hydrogen Intercalated into Hydrogenated Graphite Nanofibers; Hydrogen On-Board Storage

Share and Cite:

Y. Nechaev and T. Veziroglu, "Thermodynamic Aspects of the Graphene/Graphane/Hydrogen Systems: Relevance to the Hydrogen On-Board Storage Problem," Advances in Materials Physics and Chemistry, Vol. 3 No. 5, 2013, pp. 255-280. doi: 10.4236/ampc.2013.35037.

Journals Menu

Follow SCIRP

	+1 323-425-8868
	customer@scirp.org
	+86 18163351462(WhatsApp)
	1655362766

	Paper Publishing WeChat

Journals Menu

Home

About SCIRP

Service

Policies