Preparation and Performance Research of CuInSe2 Materials Applied in Solar Cell

Abstract

At present, CuInSe2 (referred to as CIS) semiconductor has become one of the hot points in solar cell field at home and abroad for its excellent performances, such as direct bandgap, high light absorption coefficient, high photoelectric conversion efficiency and long-term stability. In this paper, the CIS bulk materials are prepared by the horizontal Bridgman method with double-heat sources, the crystal structure, microstructure morphology and composition of the samples are analyzed in X-ray diffraction instrument (XRD) and scanning electronic microscope (SEM) with Energy Dispersive X-ray Spectrum (EDX), and surface electrical state and electrical properties of the samples are characterized in X-ray photoelectron spectroscopy (XPS) and four point resistivity test system. The results show that the CIS crystal was grown, and that the conductive performance of the samples is good which display the characteristics of p-type semiconductor. Furthermore, a thin film CIS sample was obtained by argon ion-beam scanning bombardment, and it has high solar energy absorptivity and the bandgap of 0.99 eV analyzed in Ultraviolet-visible Spectrum that is suitable for solar cell. Keywords: Solar

Share and Cite:

X. Wang, Y. Zhang, Z. Deng, Y. Wang, Z. Wang and I. Shih, "Preparation and Performance Research of CuInSe2 Materials Applied in Solar Cell," Journal of Crystallization Process and Technology, Vol. 2 No. 4, 2012, pp. 142-145. doi: 10.4236/jcpt.2012.24020.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] M. A. Green, K. Emery, Y. Hishikawa and W. Warta, “Solar Cell Efficiency Tables (version 37),” Progress in Photovoltaics: Research and Applications, Vol. 19, No. 1, 2011, pp. 84-92. doi:10.1002/pip.1088
[2] N. B. Chaure, J. Young and A. P. Samantilleke, “Electrodeposition of p-i-n Type CuInSe2 Multilayers for Photovoltaic Applications,” Solar Energy Materials & Solar Cells, Vol. 81, No. 1, 2004, pp. 125-133. doi:10.1016/j.solmat.2003.10.001
[3] J. M. Sun, Y. X. Zhu, X. F. Xu, L. F. Lan, L. J. Zhang, P. Cai, J. W. Chen, J. B. Peng and Y. Cao, “High Efficiency and High Voc Inverted Polymer Solar Cells Based on a Low-Lying HOMO Polycarbazole Donor and a Hydrophilic Polycarbazole Interlayer on ITO Cathode,” The Journal of Physical Chemistry C, Vol. 116, No. 27, 2012, pp. 14188-14198. doi:10.1021/jp3009546
[4] G. Adolf and H. Christopher, “Photovoltaic Materials, Past, Present, Future,” Solar Energy Materials and Solar Cells, Vol. 62, No. 1, 2000, p. 1-19. doi:10.1016/S0927-0248(99)00131-2
[5] G. P. Vassilev, P. Docheva and N. Nancheva, “Technology and Properties of Magnetron Sputtered CuInSe2 Layers,” Materials Chemistry and Physics, Vol. 82, No. 3, 2003, pp. 905-910. doi:10.1016/j.matchemphys.2003.08.005
[6] G. F. Zheng and H. X. Yang, “A Novel Semiconductor CIGS Photovoltaic Material and Thin Film ED Technology,” Chinese Semiconductors, Vol. 22, No. 11, 2001, pp. 1357-1363.
[7] R. Caballero and C. Guillen, “CuInSe2 Formation by Selenization of Sequentially Evaporated Metallic Layers,” Solar Energy Materials & Solar Cells, Vol. 86, No. 1, 2005, pp. 1-10. doi:10.1016/j.solmat.2004.05.019
[8] A. Ashour, A. A. S. Akla and A. A. Ramadan, “Study of Polycrystalline CuInSe2 Thin Film Formation,” Thin Solid Films, Vol. 467, No. 1, 2004, pp. 300-307. doi:10.1016/j.tsf.2004.04.046
[9] K. Subbaramaiah, “Structural and Optical Properties of Spray Deposited CIS Thin Films,” Solar Energy Materials and Solar Cells, Vol. 32, No. 1, 1994, pp. 1-6. doi:10.1016/0927-0248(94)90250-X
[10] A. H. Moharram, M. M. Hafiz and A. Salem, “Electrical Properties and Structural Changes of Thermally Co-Evaporated CuInSe2 Films,” Applied Surface Science, Vol. 172, 2001, pp. 61-67. doi:10.1016/S0169-4332(00)00836-9
[11] M. V. Yakushev, A. V. Mudryi and V. F. Gremenok, “Influence of Growth Conditions on the Structural Quality of Cu(In-Ga)Se2 and CuInSe2 Thin Films,” Thin Solid Films, Vol. 452, 2004, p. 133. doi:10.1016/j.tsf.2003.11.003
[12] A. Zegadi, M. V. Yakushev and E. Ahmed, “Effect of Se Content on Defect Levels in CuInSe2 Single Crystals Detected by Photoacoustic Spectrometry,” IEEE Photovoltaic Specialists Conference, Waikoloa, 5-9 December 1994.
[13] Z. F. Hou, A. Y. Li, Z. Z. Zhu and M. C. Huang, “Ab initio Calculation of the Electronic Structures of Copper Pyrites CuS2, CuSe2 and CuTe2,” Journal of Materials Science & Technology, Vol. 29, No. 4, 2004, pp. 429-431.

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.