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The Origin of the Giant Hall Effect in Metal-Insulator Composites

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DOI: 10.4236/ojcm.2016.63008    1,620 Downloads   2,195 Views   Citations
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ABSTRACT

Near the metal-insulator transition, the Hall coefficient R of metal-insulator composites (M-I composite) can be up to 104 times larger than that in the pure metal called Giant Hall effect. Applying the physical model for alloys with phase separation developed in [1] [2], we conclude that the Giant Hall effect is caused by an electron transfer away from the metallic phase to the insulating phase occupying surface states. These surface states are the reason for the granular structure typical for M-I composites. This electron transfer can be described by [1] [2], provided that long-range diffusion does not happen during film production (n is the electron density in the phase A. uand uB are the volume fractions of the phase A (metallic phase) and phase B (insulator phase). β is a measure for the average potential difference between the phases A and B). A formula for calculation of R of composites is derived and applied to experimental data of granular Cu1-y(SiO2)y and Ni1-y(SiO2)y films.

Received 7 April 2016; accepted 28 June 2016; published 1 July 2016

1. Introduction

Nanocomposites play a growing role in both scientific research and practical applications because of the possibility of combination of special properties which cannot be reached in classical materials [3] - [5] . A prominent example for both scientific challenge and practical application is the Giant Hall effect (GHE) in metal-insulator composites (M-I composites): Near the metal-insulator transition (M-I transition), the Hall coefficient can be up to 104 times larger than that in the pure metal [6] - [16] .

Applications of the GHE we find in magnetic field sensing elements, in read heads of magnetic recording devices and magnetic switching devices. Other examples for practical applications of nanocomposites are biomedical ones, materials with improved corrosion resistance, and thermoelectric materials with higher efficiency for energy harvesting, environmentally friendly refrigeration, direct energy transformation from heat into electricity, and temperature sensors.

As reasons for the GHE, quantum size effects and quantum interference effects on the mesoscopic scale have been discussed [8] [11] - [14] [17] . To our knowledge, until now, there is no explanatory model which can interpret the phenomenon of GHE. In the present paper, we present a discussion of the reasons for the GHE applying the electron transfer model [1] [2] developed for metal-metalloid alloys. This model can be summarized by three points1:

For large ranges of concentration there is

(1) Phase separation between two phases called phase A and phase B, where each phase has its “own” short-range order (SRO),

(2) The phase separation leads to band separation in the conduction band (CB) and valence band (VB) connected with the phases A and B, respectively, and the electrons are freely propagating and the corresponding wave functions are extended over connected regions of one phase as long as the phase forms an infinite (macroscopic) cluster through the alloy.

(3) Between the two coexisting phases there is electron redistribution (electron transfer) which can be described by

(1)

where is the quotient of the volume or atomic fractions2 of the two coexisting phases. is the electron density in the phase A with. is a constant for a given alloy, which is determined by the average potential difference between the two phases.

The points (1) and (2) imply the fact that each phase can be characterized by its own transport coefficients which can be calculated, in principle, by classical transport theory as done in [2] (conductivity) and [18] [19] (Seebeck coefficient).

Since M-I composites also consist of two separate phases with phase grains at the nanoscale, it is obvious to ask whether Equation (1) is reflected in the concentration dependence of the Hall coefficient R of M-I composites as well. Indeed, we have found that in the metallic regime of Cu1-y(SiO2)y and Ni1-y (SiO2)y thin films, the concentration dependence of R can be approximated by linear relations

(2)

with constant slope. For Cu1-y(SiO2)y and Ni1-y(SiO2)y it follows from Figure 1(a) and Figure 1(b), and with the coefficient of determination and, respectively., where y is the volume fraction of SiO2. This finding is illustrated in Figure 1(a) and Figure 1(b), where the absolute R values measured by Zhang et al. [12] , Saviddes et al. [20] and Pakhomov et al. [10] are drawn versus. The signs of the R values are negative. For Ni1-y(SiO2)y, Figure 1(b), the extraordinary R values (taken from Fig. 3 in [10] ) are drawn.

Figure 1(a) and Figure 1(b) reflect immediately Equation (1) provided that (nearly free electrons - NFE). For a more precise discussion, we have to separate the contribution of the metallic phase to R, which can be done applying effective medium theory (EMT, [2] , Sec. IVA therein).

The known EMT-formula for the Hall coefficient derived by Cohen and Jortner [21] is

(3)

Figure 1. Experimental Hall coefficient data at 5 K versus for Cu1-y(SiO2)y, (a), (c), and Ni1-y(SiO2)y, (b), (d), taken from [12] (circles), [20] (triangles) and [10] (diamonds). (c), (d): calculated by according to Equation (16), where is set.

where and R are the electrical conductivity and Hall coefficient of a composite, respectively. and are the corresponding transport parameters of the phase i.3 is the volume fraction of the phase i (i stands for the phase A or B).

As will be argued in Sec. 3.1, Equation (3) seems to be a good approximation for two-phase composites if, but not if, as typical for M-I composites. Therefore, in Sec. 2 a R formula will be derived which holds for as well. In Sec. 3.1 this R formula and Equation (3) will be compared and its applicability to M-I composites will be checked. In Sec. 3.2 it will be applied to a quantitative discussion of the GHE in M-I composites. In Sec. 3.3 the effect of the grain size on the GHE will be discussed. In Sec. 4 the results will be summarized.

2. Derivation of the R Formula

Let us consider a non-magnetic two-phase composite, where the phase grains are spherical without preferred orientations and arranged in a symmetrical fashion and each phase i can be characterized by a set of transport coefficients. The local electric current density in a single grain of the phase i (i = A or B) can be written as

(4)

where and are the electric field and the magnetoconductivity tensor [22] in this grain. For the electric current density outside of this grain we write analogously

(5)

where and are the electric field and the magnetoconductivity tensor outside of this grain (effective medium). For the determination of the coefficients in we start with the equation for under the influence of an electrical and magnetic field, [23] - [25]

(6)

are the transport integrals, and for electrons and holes, respectively. is the elementary charge. The third summand in Equation (6) disappears only if (or) is always perpendicular to. In a composite, however, and (or), are generally not perpendicular to each other because of the spherical boundary between a phase grain and its surroundings. Without loss of generality, the external fields applied to the sample, and, have the directions of the X and Z axes, respectively. Then Equation (6) and Equation (4) lead to

(7)

where. Analogously we write for,

(8)

with. and, where and are the angle between and, respectively between and. and are the Hall mobility in the composite and phase i, respectively.

At the interface between a single phase grain and its surroundings continuity of the normal components of the current density and the tangential components of the potential gradient are to be fulfilled. For the limiting case, this demand is fulfilled by

(9)

following from the EMT-formula for, [27] [28]

(10)

For the case, the tensor properties of and, Equation (7) and Equation (8), are to be taken into account. Equation (9) expressed in tensor form reads

(11)

where the identities and have been used. Equation (11) determines the coefficients of Equation (8) as a function of the coefficients of Equation (7). Inserting Equation (7) and Equation (8) into Equation (11) and comparing coefficients for the tensor elements, we get

(12)

following from the tensor elements or, where quadratic and higher powers of, are neglected, i.e., Equation (12) and the following Equations (13), (14) are low-field approximations. Within this approximation the parameters and do not have an influence on the result. From the tensor elements, , or, Equation (10) follows.

Substituting and in Equation (12) by R and and considering Equation (9) we get the R formula for two-phase composites:

(13)

The same formalism can also be applied to composites with more than two phases leading to relatively complex formulae for R. A self-contained and more manageable description of these R formulae is given by

(14)

with

(15)

3. Discussion

3.1. Comparison between Equation (3) and Equation (13)

For three examples of two-phase composites, in Figure 2(b), Figure 2(d), and Figure 2(f), the concentration dependence of R related to its values at is shown, calculated by Equation (13), and compared with Equation (3), denoted as “C & J”. In Figure 2(a), Figure 2(c), and Figure 2(e), the corresponding concentration dependence of the Hall mobility () is shown, where is calculated by Equation (9). There are two essential differences between the two solutions Equation (3) and Equation (13):

(1) The most striking difference appears in Figure 2(a) and Figure 2(c): The “C & J” curves decrease dramatically with increasing and pass through a pronounced minimum at, although and, respectively. In contrast, the curves calculated by Equation (13) agree with the expectation: Figure 2(a): agrees with for all; Figure 2(c) and Figure 2(e): increases and decreases with increasing, respectively.

A possible interpretation for such dramatic decrease of at (“C & J” curves) could be additional scattering centres in the added phase boundaries. Such an effect by the phase boundaries is expected to be the more pronounced the smaller the sizes of the phase grains,. However, the C & J formula [21] [26] does not contain.

The differences between Equation (13) and the curves “C & J” are the larger the larger the difference between and. On the other hand, for the limiting case, , Equation (3) and Equation (13) agree.

(2) Another striking difference between Equation (13) and Equation (3) is represented by the boundary case “and”, for which one obtains

(16)

and

(17)

Figure 2. and versus calculated by Equation (3) (“C & J”) and by Equation (13). The “C & J”-curves in Figure 2(a) and Figure 2(c) agree with the curves “5” and “7” shown in Fig. 1(b), Fig. 1 (c) of [21] and Fig. 13, Fig. 14 of [26] , where the same examples are chosen.

respectively, and for, Equation (9) gives

(18)

Starting at, with decreasing both and decrease continuously until they vanish at

. This result corresponds to the fact that for there is no longer a connected metal cluster through the composite (in correspondence with the assumption made earlier that the phase grains are spherical without preferred orientations and arranged in a symmetrical fashion). This result is, however, not reflected by Equation (17) which gives even for, where all the metallic granules are separated by adjacent insulating phase regions, that is, electron transport through the sample does not happen, if additional tunneling is excluded.

These two differences, (1) and (2), suggest the fact that Equation (16) represents the physical situation better than Equation (17). Therefore, in the following, Equation (13), respectively Equation (16), will be applied in a discussion of the Hall coefficient in M-I composites.

3.2. The Giant Hall Effect in M-I Composites

For calculated by Equation (16) applied to the R data of Figure 1(a), Figure 1(b), we find that they can be approximated by a relation similar to Equation (2),

(19)

where is a constant for a given M-I composite: For Cu1-y(SiO2)y and Ni1-y(SiO2)y it follows from Figure 1(c) and Figure 1(d), and with the coefficient of determination and, respectively.4 This finding suggests that the colossal increase of is caused by one (!) effect acting in the complete metallic regime. Inserting (NFE approximation) in Equation (19) leads to Equation (1), or in differential form,

(20)

where. n is the electron density in the metallic phase and. and are the volume fractions of the insulator phase (B) and metallic phase (A), respectively. and are identical with y and, respectively, if the insulating phase consists only of SiO2 and the metallic phase only of Cu or Ni. In this case,. If, however, a certain portion of the metalloid atoms is dissolved in the metallic phase and/or a certain portion of the metal atoms is solved in the insulating phase, then is only an approximation for. Equations (1) and (20) agree with the equations (15a) and (15b) in [1] , respectively, which describe electron transfer between the phases in amorphous transition-metal―metalloid alloys.5 There the parameter was interpreted to be a constant for a given composite, which is determined by the average potential difference between the phases,.6 Phase B is the phase with the deeper potential. Because of this analogy, Equation (19) suggests the following interpretation of the GHE: The colossal increase of with decreasing metal content is essentially caused by a decrease of n due to electron transfer to the insulator phase (SiO2) which can be described by Equation (1), respectively Equation (20).

Because the Fermi level lies in the energy gap between the valence band and conduction band of the insulator SiO2 phase, the transferred electrons occupy surface states on the SiO2 phase. This is the reason for the granular structure: spherical metal grains are embedded in the amorphous SiO2 phase (see, e.g., [29] , Figs. 13-16 therein). A minimum energy is realized if, firstly, the transferred (pinned) electrons are arranged on spherical surfaces and, secondly, the insulating phase forms very thin layers around the metal grains providing the largest possible surface to accommodate the large number of transferred electrons. This electron transfer from the metallic phase to the phase boundaries provides the logical explanation for the granular structure in M-I composites. Such a granular structure has been found in many M-I films [7] [13] [15] [29] . This proposal applies to magnetic M-I composites as well. For nonmagnetic M-I composites the parameter C in

(21)

(NFE approximation) is of the order of one, depending slightly on the magnetic field. [23] [24] and are the conductivity and Hall mobility, respectively, of the phase A. is the elementary charge. For magnetic M-I composites Equation (21) holds approximately if “=” is replaced by “” considering the effect of the additional internal magnetic field due to the magnetization: An electron sees the effective magnet field, where. H is the external field applied to the specimen and is the internal field produced by the quantum mechanical exchange forces ( [30] , p. 341). An electron does not distinguish between H and. It moves according to the Lorentz force determined by and the electrical field E. One can assume that is nearly proportional to H as long as is nearly proportional to the magnetization produced by H.

This assumption is supported by the experimental finding by Xiong et al. [31] that (for not too small fields H), in the granular Co-Ag system, the Hall resistivity is linearly proportional to H. If so, the measured R values differ from the calculated R values, Equation (21), only by a factor which is nearly constant. Therefore, we assume that the EMT-formula for R, Equation (13), can be applied to magnetic composites as well.

If the metallic phase of a M-I composite is a noble metal, the NFE approximation is a good one for the metallic phase, above all as the Fermi surface moves away from the Brillouin zone boundary as n decreases. For the metallic phase in Ni-SiO2 the NFE approximation is surely also a good one, because Ni has only 0.55 4s valence electrons per Ni atom ( [30] , p. 271).

If the metallic phase of a M-I composite is a transition-metal, the electron transfer is expected to be composed of both the d and s electrons. As the d density of states at the Fermi level is essentially larger than the s density of states, the principal share of electrons transferred to the insulating phase, is made up of d electrons, that is, the s electron density in the metallic phase remains relatively large. Because the electronic transport is determined by the s valence electrons in the A phase, the effect of the electron transfer on the electronic transport in the metallic phase is expected to be relatively small, and the increase of due to electron transfer should be essentially smaller as in M-I composites containing a noble metal as metallic phase. For instance, in Mo1-y(SnO2)y ( [7] , Fig. 2 therein), we do not find an exponential change of with increasing: for (i.e.), the experimental R values [7] of Mo-SnO2 fluctuate slightly where the average of calculated by Equation (16) remains nearly independent of y. Only approaching the M-I transition (),increases drastically.7

Now the question arizes: why do we find an exponential dependence of in Ni1-y(SiO2)y although Ni is a transition-metal? X-ray emission spectra of amorphous and crystalline Ni1-ySiy and Pd1-ySiy alloys by Tanaka et al. [32] have shown that there are strong bonds between d orbitals (of Ni and Pd) and Si p orbitals leading to a stronger splitting of the d band into a bonding and antibonding fraction, where the former is lifted, whereas the latter lies below the Fermi level. Analogously, for Ni1-y(SiO2)y one can also expect strong bonds between Ni d orbitals and Si (and O) p orbitals which leads to a strong reduction or disappearance of the d density of states at the Fermi level. Therefore, we find an experimental increase of (Figure 1(d)). Moreover, there is strong evidence for the assumption that the metallic phase does not consist of Ni alone, but that there is a certain fraction of Si (and O atoms) dissolved in the metallic phase.

In summary, for M-I composites containing a noble metal, we expect an exponential dependence because the electron transfer is made up entirely of the s electron density. For M-I composites containing a transition-metal, an exponential dependence can be expected if the d density of states at the Fermi level is strongly reduced, for instance caused by a hybridization of the d states with the p states of the metalloid.

Comparing granular M-I composites with amorphous transition-metal―metalloid alloys ( [1] ), we state that the exponential increase of R and the exponential decrease of with y (respectively) is essentially caused by the same phenomenon: decrease of the electron density in the metallic phase due to electron transfer to the metalloid or insulator phase. The essential difference between these two material classes is the fact that in the metalloid phase of the amorphous transition-metal―metalloid alloys an incompletely occupied sp band can exist ( [2] , Sec. IIA therein) for accepting the transferred electrons. In contrast, in the insulator phase of M-I composites only localized states on the surface of it are available for acceptance of the transferred electrons. This difference is also the reason for the different microscopic structures of M-I composites and amorphous transition-metal―metalloid alloys. Another, rather quantitative difference is the fact that the decrease of n is essentially larger than in amorphous transition-metal―metalloid alloys, as the average potential difference between the phases, , is essentially larger.

Our electron transfer model is compatible with a series of other experimental findings:

1) The GHE occurs both in magnetic M-I composites and non-magnetic ones suggesting a mechanism independent from magnetism [13] .

2) In M-I composites, and decrease exponentially with decreasing metal content in correspondence with the exponential increase of R. For some M-I composites, in Figure 3, and are drawn versus. In the NFE approximation the connection between and n is given by

Figure 3. (a) versus for Ni1-y(SiO2)y, Au1-y(Al2O3)y, W1-y(Al2O3)y and annealed W1-y(Al2O3)y (at 1200˚C in H2) taken from Abeles et al. ( [29] , Fig. 19 therein) and Ag1-y(SiO2)y, Priestley et al. [33] . (b) versus, calculated by Equation (18) and. Inlets in (a) and (b): Cu1-y(SiO2)y and Ni1-y(SiO2)y, taken from Liu et al. [14] and Pakhomov et al. [10] , respectively.

(22)

where is the mobiliy of the carriers which is assumed to be equal to the Hall mobility introduced in Sec. 2. h is Plancks constant. L is the (elastic) mean free path of the electronic carriers in the (metallic) phase A. Because of Equation (22) the exponential concentration dependence of n, Equation (1), is also reflected by the concentration dependence of in Figure 3 if the concentration dependences of L or can either be neglected or change exponentially with as well. For W1-y(Al2O3)y we assume that there are strong bonds between W d orbitals and Si (and O) p orbitals, comparable with the situation in Ni1-y(SiO2)y descussed earlier.

The only exception in Figure 3, where such an exponential concentration dependence of, respectively, does not occur, is represented by the annealed W1-y(Al2O3)y samples. This phenomenon will be discussed in Sec. 3.3.

3) With increasing y the temperature coefficient of resistivity, TCR, decreases and changes sign from positive to negative. [6] [11] [12] [14] [15] [34] The reason is an activation of localized electrons to the conduction band of the metallic phase. This conductivity contribution by activation is in competition with the positive contribution to the TCR due to scattering. The activation contribution is the larger the larger the amount of transferred electrons, i.e., the larger y, in correspondence to Equation (1).

In earlier papers it was suggested “that the GHE is a result of the drastic reduction of both the effective electron density and (in case of EHE) the effective carrier mobility”8 (Pakhomov et al. [11] ) or a drastic reduction of carrier density (Jing et al. [35] ). These two suggestions [11] [35] correspond to our physical model summarized in Sec. I. We emphasise, however, that it is not any effective electron density or carrier density (electrons or holes), but it is the real electron density which is reduced in the M-I composites.

3.3. The Effect of the Grain Size on the GHE

Approaching the M-I transition, the charging energy arising from the positively charged metal ions grows more and more and one could assume that such ‘metal’ phase cannot exist, because the electrostatic contribution by the positive ions increases more and more as n decreases. However, the growth of the electrostatic energy is not unbounded; decrease of n is accompanied with a decrease of the sizes of the metal grains. For granular Al1-yGey films, with increasing y the sizes of the metal grains decrease from 10 - 20 nm (on the metallic-rich side) to sizes <2 nm beyond the MIT (Rosenbaum et al. [36] [37] ). This decrease of with decreasing metal content even continues in the dielectric regime, as found for Ni1-y(SiO2)y, Pt1-y(SiO2)y and Au1-y(Al2O3)y thin films ( [29] , Fig. 17 therein), where decreases from 4 nm at to 1 nm at. For co-sputtered granular Ni1-y(SiO2)y films, Abeles et al. found that the average particel size, , decreases with Ni content: = 14 nm, 9.4 nm, 5.7 nm, and 3.7 nm for 87, 67, 56 and 37 vol % Ni, respectively ( [29] , Fig. 11 therein).

We suppose that the electron transfer described by Equation (1), respectively Equation (20), holds also beyond the M-I transition. This assumption correlates with the concentration dependence of, which decreases continuously through the M-I transition as cited.

As mentioned earlier ( [18] , Sec. IVA therein), Equation (1), is part and result of a complex energy balance realized during solidification of the alloy, where the sizes of the phase grains are part of this balance. Equation (1) holds for situations, where atomic diffusion does practically not play a role because of the high cooling rate during the film deposition process. Because of this suppression of the long-range diffusion, the EMT provides a more realistic description of the electrical properties of disordered alloys with phase separation than any percolation description. This is justified in [2] (Sec. IVA therein).

On the other hand, at sufficiently high temperatures, appreciable diffusion can take place leading to additional growth of. With increasing, for instance due to annealing, the electron transfer to the phase boundaries can no longer be expected to follow Equation (1). Otherwise, the growth of the electrostatic energy could be shoreless.

Therefore, the GHE decreases or disappears by annealing at sufficiently high temperatures [14] . This phenomenon is also reflected by the concentration dependences of and which can be essentially smaller than before annealing. One typical example is W1-y(Al2O3)y, [29] , Figure 3: Before annealing, is approximately linear in, but after annealing at 1200˚C it is not. Reason is the fact that after annealing the metallic phase grains are essentially larger than before, for instance for (Abeles et al. [38] , Fig. 2 therein), whereas for the unannealed samples (Abeles et al. [38] , Fig. 1 therein). Because of the large phase grains in the annealed W1-y(Al2O3)y samples [38] , the electron transfer (related to) is essentially smaller than in the unannealed samples. Elsewise, the electrostatic energy would be too large.

This can also explain the experimental finding [14] that the maximum of the enhancement of R in Zn1-y(SiO2)y is about 60, but 700 in Cu1-y(SiO2)y: the size of the granules in Zn1-y(SiO2)y is much larger (, [14] , p.608) than in Cu1-y(SiO2)y, for which is given as the minimum value ( [14] , p. 606). Apparently, in Zn1-y(SiO2)y a certain measure of atomic diffusion has been happen during film deposition, so that this balance was shifted to smaller electron transfer, i.e., Equation (1) does no longer apply.

4. Conclusions

A formula is derived for the Hall coefficient R of composites and applied to a discussion of the concentration dependence of R in M-I composites. From the empirical relation with found for experimental R data of Cu1-y(SiO2)y and Ni1-y(SiO2)y thin films, it is concluded that both the GHE and the granular structure typical for M-I composites are caused by electron transfer from the metallic phase to the

insulating phase which obeys. This equation holds for nanocomposites, where long-range

atomic diffusion does practically not play a role during the film deposition process. It is part and result of a complex energy balance realized during solidification of the alloy, where the sizes of the phase grains are part of this balance.

In M-I composites, the decrease of electron density n in the metallic phase occurs as interface charges occupying surface states on the insulating phase which is responsible for the granular structure.

Acknowledgements

The author is appreciative to MEAS Deutschland GmbH a TE Connectivity LTD company for supporting this work. He also would like to thank Professor Stolze from the University of Dortmund for a critical reading of the manuscript and Stefan Lange for technical support.

NOTES

*PACS numbers: 71.23.-k 71.55.Jv 72.10.Bg 72.15.-v.

#Corresponding author.

1The points (1) and (2) are now confirmed experimentally or supported by independent authors [39] - [50] (details in [2] , Sec. I therein). Support for point (3) comes from the fact that it is successfully applied for a quantitative description of the concentration dependence of both conductivity and Seebeck coefficient in [18] [19] and of the M-I transition and structural features of metal-metalloid alloys and M-I composites in [2] .

2In [1] , the available experimental data were not sufficient to decide this question. This question was discussed in [2] with the result that is to be interpreted as volume quotient.

3Equation (3) is a comprehensive formulation of the Equations (16)-(20) of [21] .

4RA calculated by Equation (17) can also be approximated by Equation (19) with the slopes β′ = 7.5 and β′ = 9.9 and r2 = 0.92 and r2 = 0.96, for Cu1−y(SiO2)y and Ni1−y(SiO2)y, respectively.

5For large ranges of composition, amorphous transition-metal―metalloid alloys are composed of different amorphous phases [39] - [43] with Di ~ 1 - 2 nm [42] [43] .

6The potential difference ∆V is identical with the difference of the electrochemical potentials of the phases, as long as they are not in contact to each other. Only, when a contact is realized, a common electrochemical potential is realized by electron transfer between the phases.

7In Mo1−y(SnO2)y the carriers are holes [7] ; electron transfer away from the metallic phase can lead to an increase of the hole density p, but also to a decrease of it depending on the position of the Fermi surface in relation to the Brillouin zones.

8EHE is applied in [11] for the extraordinary Hall effect in magnetic M-I composites.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Sonntag, J. (2016) The Origin of the Giant Hall Effect in Metal-Insulator Composites. Open Journal of Composite Materials, 6, 78-90. doi: 10.4236/ojcm.2016.63008.

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