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Synthesis, Characterization and Application of Mg/Al Layered Double Hydroxide for the Degradation of Congo Red in Aqueous Solution

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DOI: 10.4236/ojpc.2015.53007    3,769 Downloads   4,792 Views   Citations

ABSTRACT

The adsorption properties of layered double hydroxide (Mg/Al-CO3) for the removal of Congo Red (CR) dye from aqueous solution were studied. The layered double hydroxide was synthesized by co-precipitation method and characterized by X-ray diffraction (XRD), Fourier Transform Infrared spectroscopic (FTIR) and Energy-Dispersive X-ray Spectroscopic (EDX). The effects of various experimental parameters such as contact time, dye concentrations and temperature variation were investigated. The results show that the amount of Congo Red adsorbed increases with increase in temperature but decreases with increase in initial dye concentration and contact time. The data were also fitted to several kinetic models: zero-order kinetic model, first-order kinetic model, second-order kinetic model, pseudo-second-order kinetic model and third-order kinetic model respectively. The adsorption process was best defined by zero-order-kinetic model (R2 = 1). Langmuir, Freundich, Temkin and Dubinin-kaganer-Radushkevich (DPK) adsorption isotherm models were applied to analyze adsorption data with Temkin isotherm being the most applicable to the adsorption process. Thermodynamic parameters e.g. △Go, So, Ho and Hx of the adsorption process were found to be endothermic, spontaneous and feasible.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Ayawei, N. , Angaye, S. , Wankasi, D. and Dikio, E. (2015) Synthesis, Characterization and Application of Mg/Al Layered Double Hydroxide for the Degradation of Congo Red in Aqueous Solution. Open Journal of Physical Chemistry, 5, 56-70. doi: 10.4236/ojpc.2015.53007.

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