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Study on Complex Formation of Fluorescein-p-Sulfonatocalix[4]arene by Spectroscopic Methods

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DOI: 10.4236/opj.2014.49024    2,072 Downloads   2,588 Views   Citations

ABSTRACT

The aqueous solution of p-Sulfonatocalix[4]arene-fluorescein complex has been studied based on fluorescence and 1H NMR spectroscopic results. It has been found that the fluorescence intensity quenches regularly upon addition of p-SCX4. The proposed interaction mechanism between p-SCX4 and FL indicates that FL partially goes into the cavity of p-SCX4 with the help of strong electrostatic and π-π* interaction. The quenching constants and stability constants are determined by p-SCX4-FL systems. The proposed inclusion complex is discussed on 1H NMR results. Results are consistent with experimental data obtained from NMR spectroscopy.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Gawhale, S. , Thakare, Y. , Malkhede, D. and Chaudhari, G. (2014) Study on Complex Formation of Fluorescein-p-Sulfonatocalix[4]arene by Spectroscopic Methods. Optics and Photonics Journal, 4, 237-245. doi: 10.4236/opj.2014.49024.

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