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Synthesis, Characterization and Charge-Discharge Properties of Layer-Structure Lithium Zinc Borate, LiZnBO3

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DOI: 10.4236/msa.2013.44030    3,643 Downloads   5,603 Views   Citations


Layer-Structure lithium zinc borate, LiZnBO3, is prepared by a solid state reaction of LiOH·H2O, ZnO, and H3BO3 at 1000°C for 10 h. Highly preferred orientation and a layer-structure are observed in the powder XRD patterns and the SEM images, respectively. The Rietveld analysis indicates a monoclinic unit cell with space group C2/c, and the lattice parameters are refined as a = 8.827 ?, b = 5.078 ?, c = 6.171 ?, and β = 118.86°. LiZnBO3 shows the capacity of 17 mAh/g between 1.3 V and 4.3 V (vs. Li/Li+) larger than ZnO.

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I. Tsuyumoto and A. Kihara, "Synthesis, Characterization and Charge-Discharge Properties of Layer-Structure Lithium Zinc Borate, LiZnBO3," Materials Sciences and Applications, Vol. 4 No. 4, 2013, pp. 246-249. doi: 10.4236/msa.2013.44030.


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