TITLE:
Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide
AUTHORS:
Rupali Rastogi, Sanjay Kumar Srivastava, Shikha Asolia, Raymond J. Butcher
KEYWORDS:
Phthalimide; Selenium; Monoclinic; Phenylseleno; Sodium Borohydride
JOURNAL NAME:
Journal of Crystallization Process and Technology,
Vol.3 No.1,
January
28,
2013
ABSTRACT: PhSe-Na+ generated in situ by reduction of PhSeSePh, with sodium borohydride on reaction with N-(2-bromoethyl) phthalimide in N2 atmosphere results in the formation of N-[2-(phenylseleno)ethyl]phthalimide (L1). The title compound has been characterized by elemental analysis, FT-IR, 1H and 13C NMR techniques. The crystal structure of L1 has been solved by direct methods and refined by full-matrix least squares. The ligand L1 crystallize in the monoclinic space group. Selenium forms two Se-C linkages, one is due to Se-Calkyl and the other one to Se-Caryl. Further, the ligation reaction of L1 with complex 1 is also explored whose identities are characterized by spectroscopic techniques.