Keller, T.M., Laskoski, M., Saab, A.P., Qadri, S.B. and Kolel, M. (2014) In Situ Formation of Nanoparticle Titanium Carbide/Nitride Shaped Ceramics from Meltable Precursor Composition. Journal of Physics Chemistry, 118, 30153-30161.
https://doi.org/10.1021/jp5082388

has been cited by the following article:

• TITLE: Structural Analysis of TiC and TiC-C Core-Shell Nanostructures Produced by Pulsed-Laser Ablation

  AUTHORS: Luis Enrique Iniesta Piña, Miguel Ángel Camacho López, Rafael Vilchis Néstor, Víctor Hugo Castrejón Sánchez, Delfino Reyes Contreras

  KEYWORDS: Laser Ablation, TiC, Nanoparticles, Core-Shell Nanoparticles, Pulsed Laser

  JOURNAL NAME: Journal of Materials Science and Chemical Engineering, Vol.11 No.7, July 14, 2023

  ABSTRACT: This paper reports on the ablation process of a pure Ti solid target immersed in a C-enriched acetone solution, leading to the production of titanium carbide (TiC) and Ti-C core-shell nanostructures. The used route of synthesis is generally called pulsed laser ablation in liquid (PLAL). The presence of carbon structures in the solution contributed to the carbon content in the produced Ti-based nanomaterials. The atomic composition of the produced nanostructures was analyzed using SEM-EDS, while TEM micrographs revealed the formation of spherical TiC and core-shell nanostructures ranging from 40 to 100 nm. The identification of atomic planes by HRTEM confirmed a 10 nm diameter C-shell with a graphite structure surrounding the Ti-core. Raman spectroscopy allowed for the identification of D and G peaks for graphite and a Raman signal at 380 and 600 cm−1, assigned to TiC. The results contribute to the state-of-the-art production of TiC and Ti-C core-shell nanostructures using the PLAL route.