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https://doi.org/10.1021/ja01641a067

has been cited by the following article:

• TITLE: A New Strategy for the Synthesis of Monomethylhydrazine Using the Raschig Process

  AUTHORS: Duc Minh Le, Anne-Julie Bougrine, Olivier Duclos, Véronique Pasquet, Henri Delalu

  KEYWORDS: Synthesis, Raschig, Monomethylhydrazine, Kinetic Model

  JOURNAL NAME: Advances in Chemical Engineering and Science, Vol.11 No.3, June 21, 2021

  ABSTRACT: A new strategy for the development of monomethylhydrazine (MMH) using the Raschig process is discussed in this publication. The determination of optimal conditions for the synthesis of MMH required the development of a kinetic model. In order to validate the results of the calculation, a device for synthesis under pressure (13 bar) by direct injection of the stoichiometric monochloramine, synthesized using microreactor technology, into monomethylamine (MMA) was developed. The experimental data, in accordance with the theoretical results of the kinetic model, make it possible to establish a new process for the synthesis of monomethylhydrazine.