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https://doi.org/10.1021/ie3019033

has been cited by the following article:

• TITLE: Evaluation of Reaction Mechanism for Photocatalytic Degradation of Dye with Self-Sensitized TiO2 under Visible Light Irradiation

  AUTHORS: Md. Ashraful Islam Molla, Ikki Tateishi, Mai Furukawa, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco

  KEYWORDS: TiO2, Photocatalytic Degradation, Visible Light, Dye-Sensitization, Reaction Mechanism

  JOURNAL NAME: Open Journal of Inorganic Non-metallic Materials, Vol.7 No.1, January 30, 2017

  ABSTRACT: The dye-sensitized TiO2 method is one of the most promising methods for the visible-light-induced detoxification of pollutants. The reaction mechanism for photocatalytic degradation of orange II (OII) and rhodamine B (RhB) with self-sensitized TiO2 under visible light irradiation (λ > 400 nm) has been evaluated. Radical scavenger studies were carried out to investigate the active species involved in the photodegradation of 5 mg/L of initial concentration of OII and RhB at room temperature. The trapping effects of different scavengers results proved that the oxidation of OII and RhB mainly occurred by the direct oxidization of h+ and ·O2- radicals, while the ·OH radicals played only a relatively minor role in the direct oxidization process.