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has been cited by the following article:

• TITLE: Study on the Mechanism of Heterogeneous Catalysis (1) —The Measurement of Equilibrium Pressure of Reaction BaCO3 + C = BaO + 2CO, the Chemical States of Fe in Reaction Tank, and Chemical Reaction Model Catalytic Cycle Mechanism (CRMM)

  AUTHORS: Jiamin Jin, Weifan Bao

  KEYWORDS: Heterogeneous-Catalysis, Mechanism, Carburizing, BaCO3

  JOURNAL NAME: Journal of Materials Science and Chemical Engineering, Vol.5 No.7, July 27, 2017

  ABSTRACT: The results on the equilibrium pressure measurement of BaCO3 + C = BaO + 2CO reaction and the demonstration of chemical state of iron proved that decomposition-generation cycle of BaCO3 and oxidation-reduction cycle of Fe in that reaction condition case were impossible to occur. The Chemical Reaction Model Catalytic Cycle Mechanism-CRMM does not exist at all for BaCO3, Fe, Noble metal catalysts. To call CRMM as a “principle” was obviously inappropriate. The TOF (Turnover Frequency—TOF: unit: s-1) was used to measure the activity size and life of catalyst, and it is clearly out of nothing.