TITLE:
Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles
AUTHORS:
Minako Oshima, Minoru Matsuno, Tsutsumi Yuki, Sunaga Nobumitsu, Tomoyuki Haraguchi, Takashiro Akitsu
KEYWORDS:
Chiral Schiff Base Metal Complex, Gold Nanoparticle
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.7 No.2,
June
22,
2017
ABSTRACT: We have prepared supramolecular systems of chiral Schiff base Ni(II), Cu(II), Zn(II) complexes and colloidal gold nanoparticles (AuNP) of 10 nm diameters. They demonstrated that direct adsorption of chiral Schiff base metal complex on the surface of AuNP owing to observation of clear induced CD spectra for the first time. We observed and discussed induced CD bands on AuNP from chiral Schiff base Ni(II), Cu(II), Zn(II) complexes.