TITLE:
Geochemistry of Cretaceous Mudrocks and Sandstones from Douala Sub-Basin, Kumba Area, South West Cameroon: Constraints on Provenance, Source Rock Weathering, Paleo-Oxidation Conditions and Tectonic Environment
AUTHORS:
Gabriel Ngueutchoua, Leopold Darlus Ngantchu, Martine Youbi, Simon Ngos III, Véronique Kamgang Kabeyene Beyala, Kevin Petsouonko Yifomju, Jean Claude Tchamgoué
KEYWORDS:
Douala Sub-Basin, Provenance, Weathering, Oxic Condition, Tectonic Setting
JOURNAL NAME:
International Journal of Geosciences,
Vol.8 No.4,
April
17,
2017
ABSTRACT: Geochemical data of fifteen Cretaceous sediment samples from Kumba area in the Douala sub-basin are presented to determine the provenance, source rock weathering, tectonic setting and paleo-oxidation conditions of the depositional setting of these rocks. For this purpose, the whole-rocks were analyzed for their major and trace element, including rare earth elements (REEs), contents by ICP-AES and ICP-MS methods respectively. On the basis of their major element composition, the rocks have been classified mainly as Fe-shale, shale, arkose and Fe-sandstone. For the provenance, the plot of Zr vs. TiO2, Y/Ni vs. Cr/V, TiO2 vs. Al2O3 diagrams, high LREE/HREE ratios (5.84 to 20.91) and negative and positive Eu anomalies (Eu/Eu*= 0.87 to 1.62) suggest that the studied rocks were mainly derived from felsic igneous rocks with lesser contribution of mafic components. The higher values of paleo-weathering indices such as Plagioclase Index of Alteration (PIA) and Chemical Index of Weathering (CIW), ranging from 79.63 to 99.90 and 87.57 to 99.92 respectively, suggest that the sediments and their potential source rocks experienced intense weathering. Whereas the variable Chemical Index of Alteration (CIA) values (63.01 to 99.50) coupled with high content of K2O (up to 7.5) in most samples could be indicative of K-addition diagenetic processes. The A-CN-K plot also suggests a possible K-addition. The redox conditions during the sedimentation were suboxic to oxic as evidenced by the Ce anomalies of 0.88 to 1.03. This is also confirmed by the values of Ni/Co (less than 7), U/Th (less than 1.25) and Cu/Zn (mostly less than 1). Tectonic discrimination diagrams (e.g., SiO2-K2O/Na2O and Th-Sc-Zr/10) show that these rocks were deposited mainly in an active continental margin setting, and in various tectonic environments. This reflects probably the recycling effect experienced by the samples studied.