Article citationsMore>>
Mahmudov, K.T., Hasanov, X.I., Maharramov, A.M., Azizova, A.N., Ragimov, K.Q., Askerov, R.K., Kopylovich, M.N., Ma, Z. and Pombeiro, A.J.L. (2013) A Hexanuclear Metallacrown Palladium(II) Cluster Derived from 2-Mercaptoethanol. Inorganic Chemistry Communications, 29, 37-39.
http://dx.doi.org/10.1016/j.inoche.2012.12.012
has been cited by the following article:
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TITLE:
Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by β-Mercaptoethylamine
AUTHORS:
Asmat N. Azizova, Dilqam B. Tagiyev, Shmid G. Gasimov, Khudayar I. Gasanov
KEYWORDS:
Mercaptoamine, Ligands, Platinum, Six-Nuclear Complexes, Synthesis
JOURNAL NAME:
Advances in Chemical Engineering and Science,
Vol.6 No.1,
January
12,
2016
ABSTRACT: Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β-mercaptoethylamine with composition [Pt6(H2NCH2CH2S)8]Cl4·5H2O had been syntesized for the first time. Structure of the complex had been installed together with IKS- and XRD analysis. It has been established that each atom of platinum is surrounded by two atoms of sulfur and nitrogen due to bidentate coordination of a ligand. Only two of the six platinum atoms are on the same plane; other four atoms are in the different crossing planes. Four platinum atoms form adurable metal chelate cycles, which collapse over temperature 260℃. The results of IR spectroscopy confirmed with the RS-analysis.