Optimization of Chromium (Vi) Removal by Donnan Dialysis

I. Marzouk, L. Dammak, L. Chaabane, B. Hamrouni

1UR Traitement et Dessalement des Eaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Manar II, Tunisie.
Institut de Chimie et des Matériaux Paris-Est, Université Paris-Est Créteil, Henri Dunant, Thiais, France.
UR Traitement et Dessalement des Eaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Manar II, Tunisie.

DOI: 10.4236/ajac.2013.46039                

Abstract

The removal of chromium (VI) from aqueous solutions by Donnan dialysis has been investigated in this paper. In this process, two anion-exchange membranes (AEMs) were used: Selemion^? AMV and Neosepta^? AFN. The amount of chromium (VI) removed was determined in terms of the following parameters: initial concentration of chromium (VI), type of anion-exchange membrane, concentration of counter-ion and magnetic stirring rate. A 24 full factorial design analysis was performed to screen the parameters affecting the Cr (VI) removal efficiency. Using the experimental results, a linear mathematical model representing the influence of the different parameters as well as their interactions was obtained. Analysis of the variance (ANOVA), the F-test and the student’s test shows that the type of anion-exchange membrane is the most significant parameter affecting the chromium (VI) removal. The statistical analysis of the experimental data assumes it to be a normal distribution.

Keywords

Donnan Dialysis; Chromium (VI); Anion-Exchange Membrane; Factorial Design; Optimization

Conflicts of Interest

The authors declare no conflicts of interest.

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