Optical Characterization of Erbium Doped KY3F10 Fluoride Single Crystals

Abstract

Preparation and optical characterisation of Erbium doped KY3F10 single crystals are reported. The crystals were grown using the Czochralski pulling technique. The single phase was controlled by X-ray diffraction analysis. Room temperature optical spectra were recorded between 200 and 1600 nm. They were used to fit the three phenomenological Judd-Ofelt (JO) parameters Ωt (t = 2, 4, 6). The emission transition probabilities, branching ratios and radiative lifetimes are then deduced. The possibility to use such material for laser emissions is discussed.

Share and Cite:

S. Khiari, F. Bendjedaa and M. Diaf, "Optical Characterization of Erbium Doped KY3F10 Fluoride Single Crystals," Optics and Photonics Journal, Vol. 3 No. 1, 2013, pp. 13-17. doi: 10.4236/opj.2013.31003.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] K. Heyde, K. Binnemans and C. G?rller-Walrand, “Spectoscopic Properties of KY3F10:Er3+,” Journal of the Chemical Society, Faraday Transactions, Vol. 94, No. 12, 1998, pp. 1671-1674. doi:10.1039/a800610e
[2] J. P. R. Wells, A. Sugiyama, T. P. J. Han and H. G. Gallagher, “Laser Site Selective Excitation of KY3F10 Doped with Samarium,” Journal of Luminescence, Vol. 85, No. 1-3, 1999, pp. 91-102. doi:10.1016/S0022-2313(99)00150-7
[3] C. Borel and B. Viana, “Laser Hosts Emitting in the Range 1.5 2 μm,” Annales de Chimie Fran?aises, Vol. 20, 1995, pp. 227-232.
[4] M. Diaf, A. Braud, C. Labbé, J. L. Doualan, S. Girard, J. Margerie, R. Moncorgé and M. Thuau, “Synthesis and Spectroscopic Studies of Tm3+-doped KY3F10 Single Crystals,” Canadian Journal of Physics, Vol. 77, No. 9, 1999, pp. 693-697. doi:10.1139/cjp-77-9-693
[5] C. Wyss, W. Lüthy, H. P. Weber, P. Rogin and J. Hulliger, “Emission Properties of an Optimised 2.8 μm Er3+:YLF Laser,” Optics Communications, Vol. 139, No. 4-6, 1997, pp. 215-218. doi:10.1016/S0030-4018(97)00130-2
[6] M. Mujaji and J. P. R. Wells, “Spectroscopy and Crystal-Field Analysis of KY3F10:Ho3+,” Journal of Physics: Condensed Matter, Vol. 21, No. 25, 2009, pp. 255402-255408 doi:10.1088/0953-8984/21/25/255402
[7] A. Braud, S. Girard, J. L. Doualan, M. Thuau and R. Moncorgé, “Energy Transfer Processes in Yb:Tm-Doped KY3F10, LiYF4 and BaY2F8 Single Crystals for Laser Operation at 1.5 and 2.3 μm,” Physical Review B, Vol. 61, No. 8, 2000, pp. 5280-5292. doi:10.1103/PhysRevB.61.5280
[8] A. Grzechnik, W. A. Crichton and J. Y. Gesland, “Sheelite CaWO4 at High Pressures,” Solid State Sciences, Vol. 5, No. 5, 2003, pp. 757-764. doi:10.1016/S1293-2558(03)00094-3
[9] B. Chai, J. Lefaucher, A. Pham, G. Lutts and J. Nichols, “Growth of High Quality Single Crystals of KYF4 by TSSG Method,” SPIE Proceedings, Vol. 131, 1993, p. 1863.
[10] M. Mortier, J. Y. Gesland, M. Rousseau, M. A. Pimenta, L. O. Laderia, J. C. Machado, D. Silva and G. A. Barbosa, “Raman Scattering Investigations of KY3F10,” Journal of Raman Spectroscopy, Vol. 22, No. 7, 1991, pp. 393-396. doi:10.1002/jrs.1250220706
[11] A. P. Ayala, M. A. S. Olivera, J. Y. Gesland and R. L. Moreira, “Electrical and Dielectric Investigations of the Conductions Processes in Crystals,” Journal of Physics: Condensed Matter, Vol. 10, No. 23, 1998, p. 5161. doi:10.1088/0953-8984/10/23/016
[12] J. W. Pierce and H. Y. P. Hong, “Laser Focus,” Proceedings of the Tenth Rare Earth Research Conference, Vol. 1, 1976, p. 527.
[13] R. Y. Abdulsabirov, M. A. Dubiniski, N. M. Kazakov, N. I. Silkin and S. I. Yagudin, “ New Fluoride Laser Host,” Soviet Physics-Crystallography, Vol. 32, No. 4, 1987, p. 559.
[14] B. R. Judd, “Optical Absorption Intensities of Rare-Earth Ions,” Physical Review, Vol. 127, No. 3, 1962, pp. 750-761. doi:10.1103/PhysRev.127.750
[15] G. S. Ofelt, “Intensities of Crystal Spectra of Rare-Earth Ions,” Journal of Chemical Physics, Vol. 37, No. 3, 1962, pp. 511-520. doi:10.1063/1.1701366
[16] W. T. Carnall, P. R. Fields and K. Rajnak, “Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions, Pr, Nd, Sm, Dy, Ho, Er and Tm,” Journal of Chemical Physics, Vol. 49, No. 10, 1968, pp. 4412-4423. doi:10.1063/1.1669892
[17] A. A. Kaminskii, “Laser Crystals: Their Physics and Properties,” 2nd Edition, Springer-Verlag, Berlin, 1989.
[18] M. J. Weber, “Probabilities of Radiative and Non Radiaive Decay of Er3+ in LaF3,” Physical Review, Vol. 157, No. 2, 1967, pp. 262-272. doi:10.1103/PhysRev.157.262
[19] W. F. Krupke, “Radiative Transition Probabilities within the 4f3 Ground Configuration of Nd:YAG,” IEEE Journal of Quantum Electronics, Vol. 7, No. 4, 1971, pp. 153-159. doi:10.1109/JQE.1971.1076623
[20] W. F. Krupke, “Induced Emission Cross Sections in Neodymium Laser Glasses,” IEEE Journal of Quantum Electronics, Vol. 10, No. 4, 1974, pp. 450-457. doi:10.1109/JQE.1974.1068162
[21] M. J. Weber and T. E. Varitimos, “Optical Spectra and Intensities of Nd3+ in YAlO3,” Journal of Applied Physics, Vol. 42, No. 12, 1971, pp. 4996-5005. doi:10.1063/1.1659885
[22] R. Beach, M. D. Shinn, L. Davis, R. W. Solarz and W. F. Krupke, “Optical Absorption and Stimulated Emission of Neodymium in Yttrium Orthosilicate,” IEEE Journal of Quantum Electronics, Vol. 26, No. 8, 1990, pp. 1405-1412. doi:10.1109/3.59689
[23] D. K. Sardar, R. C. Velarde-Montecinos, and S. Vizcarra, “Spectroscopic Properties of Nd3+ in CaF2,” Phys. Stat. Solidi A, Vol. 136, 1993, pp. 555-560. doi:10.1002/pssa.2211360228
[24] K. Labbaci and M. Diaf, “Crystal Growth and Spectroscopic Investigations of Tm3+ Ions doped 5Na-9YF3 Fluoride Single Crystals,” Physica Scripta, Vol. 75, No. 3, 2007, pp. 27-330. doi:10.1088/0031-8949/75/3/018
[25] X. Li, Z. Lin, L. Zhang and G. Wang, “Growth and Spectroscopic Characterization of Er3+:NaY (MoO4)2 Crystal,” Journal of Crystal Growth, Vol. 293, No. 1, 2006, pp. 157-161. doi:10.1016/j.jcrysgro.2006.04.100
[26] A. M. Tkachuk, S. I. Klokishner, A. V. Poletimova and L. M. Petrove, “Probabilities of Intracenter Transitions and Self-Quenching of Luminescence in BaEr2F8 and BaHo2F8 Crystals,” Optics and Spectroscopy, Vol. 60, No. 6, 1986, pp. 745-751.
[27] D. K. Sardar, J. B. Gruber, B. Zandi, J. A. Hutchinson and C. W. Trussel, “Judd-Ofelt Analysis of Er3+ (4f11) Absorption Intensities in Phosphate Glass: Er3+, Yb3+,” Journal of Applied Physics, Vol. 93, No 4, 2003, pp. 2041-2046. doi:10.1063/1.1536738
[28] S. Hubert, D. Meichenin, B. W. Zhou and F. Auzel, “Emission Properties, Oscillator Strengths and Laser Pa rameters of Er3+ in LiYF4 at 2.7 μm,” Journal of Luminescence, Vol. 50, No. 1, 1991, pp. 7-15. doi:10.1016/0022-2313(91)90004-F

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.