Growth and Characterization of a New Semi-Organic Nonlinear Optical Crystal: Thiosemicarbazide Cadmium Acetate

Abstract

A new semi-organic nonlinear optical thiosemicarbazide cadmium acetate (TSCA) material has been synthesized. TSCA single crystals were grown from aqueous solution by slow evaporation method. The solubility of TSCA has been determined for various temperatures. The grown crystals were characterized by single crystal X-ray diffraction (XRD), FTIR, UV-Vis., thermal and second harmonic generation (SHG) analysis. Single crystal XRD study has been carried out to identify the lattice parameters. FTIR studies confirm the functional groups present in the grown crystal. Optical transmission studies have confirmed that the grown crystal is highly transparent. Thermogravimetric and differential thermal analyses reveal the good thermal stability of the material. The SHG conversion efficiency of TSCA was determined using Kurtz powder technique and found two times that of potassium dihydrogen orthophosphate (KDP).

Share and Cite:

K. Selvaraju, K. Kirubavathi and S. Kumararaman, "Growth and Characterization of a New Semi-Organic Nonlinear Optical Crystal: Thiosemicarbazide Cadmium Acetate," Journal of Minerals and Materials Characterization and Engineering, Vol. 11 No. 3, 2012, pp. 303-310. doi: 10.4236/jmmce.2012.113022.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] P.N. Prasad, D.J. Williams, Introduction to Nonlinear optical effects in organic molecules and polymers, Wiley, New York, 1991.
[2] S.R. Marder, J.E. Sohn, G.D. Stucky, ACS Symp. Proc. 455, Washington, 1991.
[3] D.S. Chemla, J. Zyss, Nonlinear optical properties of organic molecules and crystals, Academic Press, New York, 1987.
[4] H.S. Nalwa, S. Miyata, Nonlinear optical properties of organic molecules and polymers, CRC Press, Boca Raton, FL, 1996.
[5] H.O. Mercy, L.F. Warren, M.S. Webb, C.A. Ebbers, S.P. Velsko, G.C. Kennedy, G.C. Catella, Appl. Opt. 31 (1992) 5051-5060.
[6] U. Ramabadran, D.E. Zelmon, G.C. Kennedy, Appl. Phys. Lett. 60 (1992) 2589-2592.
[7] P.M. Ushasree, R. Muralidharan, R. Jayavel, P. Ramasamy, J. Crystal Growth 218 (2000) 365-371.
[8] V. Kannan, N.P. Rajesh, R. Bairava Ganesh, P. Ramasamy, J. Crystal Growth 269 (2004) 565-569.
[9] R. Sankar, C.M. Raghavan, R. Jayavel, Cryst. Growth & Desi. 7 (2007) 501-505.
[10] W.S. Wang, K. Sutter, Ch. Bosshard, Z.Pan, H. Arend, P. Gunter, G. Chapuis, F. Nicolo, Jpn.J. Appl. Phy. 27 (1988) 1138-1141.
[11] R. Sankar, C.M. Raghavan, . Mohan Kumar, R. Jayavel, J. Crystal Growth 305 (2007) 156-161.
[12] M. Mashima, Bull. Chem. Soc. Japan 37 (1964) 974-977.
[13] G. Keresztury, M.P. Marzocchi, Chem. Phys. 6 (1974) 117-123.
[14] S.K. Kurtz, T.T. Perry, J. Appl. Phys. 39 (1968) 3798-3813.

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.